Methods and configurations for acid gas enrichment

• US 7,635,408 B2
• Filed: 08/18/2004
• Issued: 12/22/2009
• Est. Priority Date: 01/20/2004
• Status: Active Grant

• Current Assignee: Fluor Enterprises Incorporated (Fluor Corporation)
• Original Assignee: Fluor Technologies Corporation (Fluor Corporation)
• Inventors: Chow, Thomas King, Morgan, Oliver, Wong, Vincent Wai, Mak, John, Nielsen, Richard B.
• Primary Examiner(s): LAWRENCE JR, FRANK M
• Application Number:
  US10/585,271
• Publication Number:
  US 20080019899A1
• Time in Patent Office: 1,952 Days
• Field of Search: 962/34, 951/87, 951/88, 95206-209, 952/23, 952/35, 423/220, 423/228, 423/229, 208/208.R
• US Class Current: 95/187
• CPC Class Codes: B01D 2252/20431 Tertiary amines
• CPC Class Codes: B01D 2256/22 Carbon dioxide
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: B01D 53/1468 Removing hydrogen sulfide
• CPC Class Codes: C01B 17/0408 Pretreatment of the hydrogen sulfide containing gases
• CPC Class Codes: C01B 17/167 Separation
• CPC Class Codes: C10L 3/10 Working-up natural gas or synthetic natural gas

Abstract

Hydrogen sulfide is selectively enriched from an acid gas (1) that comprises relatively large quantities of carbon dioxide using a configuration in which a portion of an isolated hydrogen sulfide stream is introduced into an absorber (51) operating as a carbon dioxide rejecter. The resulting concentrated hydrogen sulfide enriched solvent (4) is then further used (directly or indirectly) to absorb hydrogen sulfide from an acid feed gas.

Claims

1. A plant comprising:

a first absorber fluidly coupled to a regenerator, wherein the first absorber is configured to promote absorption of hydrogen sulfide by a hydrogen sulfide-selective solvent, and wherein the regenerator is configured to promote formation of a hydrogen sulfide-rich gas from the hydrogen sulfide-selective solvent;

a second absorber fluidly coupled to the regenerator, wherein a portion of the hydrogen sulfide-rich gas is fed to the second absorber to thereby increase a hydrogen sulfide concentration in the hydrogen sulfide-rich gas;

wherein the first and second absorbers are configured to produce an overhead product that is enriched in carbon dioxide and substantially depleted in hydrogen sulfide;

wherein another portion of the hydrogen sulfide-rich gas is fed to a Claus plant, and further comprising a third absorber that receives a tail gas from the Claus plant, wherein the third absorber is configured to promote absorption of hydrogen sulfide by a hydrogen sulfide-selective solvent; and

wherein the third absorber is configured to produce an overhead product that is enriched in carbon dioxide and substantially depleted in hydrogen sulfide.

2. The plant of claim 1 wherein the first and second absorbers produce a first and second hydrogen sulfide-enriched solvent, and wherein the first and second hydrogen sulfide-enriched solvents are combined.

3. The plant of claim 1 wherein the first and second absorbers produce a first and second hydrogen sulfide-enriched solvent, wherein the first and second hydrogen sulfide-enriched solvents are combined, and wherein the second absorber receives at least a portion of the combined hydrogen sulfide-enriched solvents.

4. The plant of claim 1 wherein the first absorber produces a first hydrogen sulfide-enriched solvent, and wherein the second absorber receives at least a portion of the first hydrogen sulfide-enriched solvent.

5. The plant of claim 1 wherein the third absorber is configured to produce a third hydrogen sulfide-enriched solvent.

6. The plant of claim 5 wherein the third hydrogen sulfide-enriched solvent is fed to at least one of first and second absorbers.

7. A plant comprising:

a first absorber fluidly coupled to a regenerator, wherein the first absorber is configured to promote absorption of hydrogen sulfide by a hydrogen sulfide-selective solvent, and wherein the regenerator is configured to promote formation of a hydrogen sulfide-rich gas from the hydrogen sulfide-selective solvent;

a second absorber fluidly coupled to the regenerator, wherein a portion of the hydrogen sulfide-rich gas is fed to the first absorber to thereby increase a hydrogen sulfide concentration in the hydrogen sulfide-rich gas;

a Claus plant that receives another portion of the hydrogen sulfide-rich gas and produces a tail gas, wherein the second absorber is configured to receive the tail gas; and

wherein the first and second absorbers are configured to produce an overhead product that is enriched in carbon dioxide and substantially depleted in hydrogen sulfide.

8. The plant of claim 7 wherein the second absorber is configured to produce a hydrogen sulfide-enriched solvent, and wherein at least a portion of the hydrogen sulfide-enriched solvent is fed to the first absorber.

9. A method of increasing the concentration of hydrogen sulfide in a gas stream comprising:

separating an acid gas stream in a first absorber to form a first carbon dioxide-rich gas and a first hydrogen sulfide-enriched solvent using a hydrogen sulfide-selective solvent;

separating a first portion of a hydrogen sulfide-rich regenerator overhead product gas in a second absorber to form a second carbon dioxide-rich gas and a second hydrogen sulfide-enriched solvent;

combining the first and second hydrogen sulfide-enriched solvents to form a combined stream that is fed to a regenerator;

removing in the regenerator hydrogen sulfide from the first and second hydrogen sulfide-enriched solvents to thereby form the hydrogen sulfide-rich regenerator overhead product gas, the first portion of which is fed to the second absorber; and

feeding a second portion of the hydrogen sulfide-rich product gas to a Claus plant.

10. The method of claim 9 wherein the step of combining the first and second hydrogen sulfide-enriched solvents comprises mixing of the first and second hydrogen sulfide-enriched solvents.

11. The method of claim 9 wherein the step of combining the first and second hydrogen sulfide-enriched solvents comprises feeding at least part of the first hydrogen sulfide-enriched solvent into the second absorber.

12. The method of claim 11 wherein the Claus plant produces a tail gas, and comprising a step of feeding the tail gas to a third absorber that produces a third overhead product that is enriched in carbon dioxide and substantially depleted in hydrogen sulfide, and a third hydrogen sulfide-enriched solvent.

13. The method of claim 12 wherein the third hydrogen sulfide-enriched solvent is fed to the first absorber.

14. The method of claim 12 wherein the third hydrogen sulfide-enriched solvent is fed to the second absorber.