Apparatus for the liquefaction of a gas and methods relating to same

• US 7,637,122 B2
• Filed: 09/28/2006
• Issued: 12/29/2009
• Est. Priority Date: 05/04/2001
• Status: Active Grant

• Current Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Original Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Inventors: Wilding, Bruce M., Turner, Terry D., McKellar, Michael G.
• Primary Examiner(s): DOERRLER, WILLIAM CHARLES
• Application Number:
  US11/536,477
• Publication Number:
  US 20070017250A1
• Time in Patent Office: 1,188 Days
• Field of Search: 626/11, 626/13, 625/32, 625/37
• US Class Current: 62/611
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0037 of a return stream
• CPC Class Codes: F25J 1/004 by flash gas recovery F25J1/0267 takes precedence
• CPC Class Codes: F25J 1/0045 by vaporising a liquid return stream
• CPC Class Codes: F25J 1/0052 by vaporising a liquid refrigerant stream
• CPC Class Codes: F25J 1/0202 in a quasi-closed internal refrigeration loop F25J1/0208, F25J1/0219, F25J1/0224 take precedence
• CPC Class Codes: F25J 1/0204 as a single flow SCR cycle
• CPC Class Codes: F25J 1/0232 integration within a pressure letdown station of a high pressure pipeline system
• CPC Class Codes: F25J 1/0245 Different modes, i.e. 'runs', of operation; Process control
• CPC Class Codes: F25J 1/0247 start-up of the process
• CPC Class Codes: F25J 1/0251 Intermittent or alternating process, so-called batch process, e.g. "peak-shaving"
• CPC Class Codes: F25J 1/0268 using a dedicated refrigeration means F25J1/0296 takes precedence
• CPC Class Codes: F25J 1/0269 Arrangement of liquefaction units or equipments fulfilling the same process step, e.g. multiple "trains" concept F25J1/0294 takes precedence
• CPC Class Codes: F25J 1/0275 adapted for special use of the liquefaction unit, e.g. portable or transportable devices
• CPC Class Codes: F25J 2205/20 using solidification of components
• CPC Class Codes: F25J 2205/84 using filter
• CPC Class Codes: F25J 2210/06 Splitting of the feed stream, e.g. for treating or cooling in different ways
• CPC Class Codes: F25J 2215/60 Methane
• CPC Class Codes: F25J 2220/62 Separating low boiling components, e.g. He, H2, N2, Air
• CPC Class Codes: F25J 2220/66 Separating acid gases, e.g. CO2, SO2, H2S or RSH
• CPC Class Codes: F25J 2230/30 : Compression of the feed stream
• CPC Class Codes: F25J 2230/32 : Compression of the product stream
• CPC Class Codes: F25J 2230/60 : the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2270/04 : Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/90 : External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
• CPC Class Codes: F25J 2280/02 : Control in general, load changes, different modes ("runs"), measurements
• CPC Class Codes: F25J 2280/10 : Control for or during start-up and cooling down of the installation
• CPC Class Codes: F25J 2280/30 : Control of a discontinuous or intermittent ("batch") process
• CPC Class Codes: F25J 2290/50 : Arrangement of multiple equipments fulfilling the same process step in parallel
• CPC Class Codes: F25J 2290/62 : Details of storing a fluid in a tank
• CPC Class Codes: F25J 3/08 : Separating gaseous impurities from gases or gaseous mixtures or from liquefied gases or liquefied gaseous mixturescold traps B01D8/00

Abstract

Apparatuses and methods are provided for producing liquefied gas, such as liquefied natural gas. In one embodiment, a liquefaction plant may be coupled to a source of unpurified natural gas, such as a natural gas pipeline at a pressure letdown station. A portion of the gas is drawn off and split into a process stream and a cooling stream. The cooling stream may sequentially pass through a compressor and an expander. The process stream may also pass through a compressor. The compressed process stream is cooled, such as by the expanded cooling stream. The cooled, compressed process stream is expanded to liquefy the natural gas. A gas-liquid separator separates the vapor from the liquid natural gas. A portion of the liquid gas may be used for additional cooling. Gas produced within the system may be recompressed for reintroduction into a receiving line.

Claims

1. A method of liquefying a gas, the method comprising:

providing a source of gas and flowing a portion of the gas from the source;

dividing the portion of the gas into at least a process stream and a cooling stream;

flowing the process stream sequentially through a first compressor and a first side of at least one heat exchanger;

flowing the cooling stream sequentially through a second compressor and a second side of the at least one heat exchanger;

expanding at least a portion of the process stream subsequent flowing the process stream through the first side of at least one heat exchanger to produce a liquid;

producing a slurry of liquid natural gas and solid carbon dioxide from the at least a portion of the process stream within a liquid-gas separator; and

transferring at least a portion of the slurry from the liquid-gas separator to at least one transfer tank to maintain adequate transfer pressure of the slurry delivered from the separator.

2. The method according to claim 1, further comprising flowing the cooling stream through an expander subsequent to flowing the cooling stream through a second compressor and prior to flowing the cooling stream through the second side of the at least one heat exchanger.

3. The method according to claim 2, further comprising flowing the cooling stream through at least one other heat exchanger subsequent to flowing the cooling stream through a second compressor and prior to flowing the cooling stream through the expander.

4. The method according to claim 1, further comprising flowing at least a portion of the process stream through the second side of the at least one heat exchanger.

5. The method according to claim 1, wherein expanding at least a portion of the process stream includes flowing the at least a portion of the process stream through an expansion device into the gas-liquid separator.

6. The method according to claim 1, wherein expanding at least a portion of the process stream further includes flowing the at least a portion of the process stream through at least one expansion valve.

7. The method according to claim 6, wherein flowing the at least a portion of the process stream through at least one expansion valve includes flowing the at least a portion of the process stream through at least two expansion valves.

8. The method according to claim 7, further comprising arranging the at least two expansion valves in a parallel flow configuration.

9. The method according to claim 8, further comprising configuring a first expansion valve of the at least two expansion valves to exhibit a first flow capacity (Cv) and configuring a second valve of the at least two expansion valves to exhibit a second Cv, different from the first Cv.

10. The method according to claim 8, further comprising flowing approximately 80% of the at least a portion of the process stream through a first expansion valve of the at least two expansion valves.

11. The method according to claim 10, further comprising flowing the remainder of the at least a portion of the process stream through a second expansion valve of the at least two expansion valves.

12. The method according to claim 1, wherein transferring at least a portion of the slurry from the liquid-gas separator to at least one transfer tank further comprises selectively transferring at least a portion of the slurry from the liquid-gas separator to a plurality of transfer tanks.

13. The method according to claim 12, further comprising flowing the at least a portion of the slurry from at least one of the plurality of transfer tanks to at least one hydrocyclone.

14. The method according to claim 13, wherein flowing the at least a portion of the slurry from at least one of the plurality of transfer tanks to at least one hydrocyclone further comprises selectively flowing the at least a portion of slurry from at least one of the plurality of transfer tanks to a plurality of hydrocyclones.

15. The method according to claim 13, further comprising flowing a slush that is rich in solid carbon dioxide though an underflow of the at least one hydrocyclone to a sublimation tank.

16. The method according to claim 15, further comprising subliming the solid carbon dioxide to a gas.

17. The method according to claim 13, further comprising flowing liquid natural gas though an overflow of the at least one hydrocyclone to a diversion tank.

18. The method according to claim 17, further comprising flowing the liquid natural gas though at least one filter prior to flowing the liquid natural gas to the diversion tank.

19. The method according to claim 17, further comprising flowing at least a portion of the liquid natural gas from the diversion tank to a second side of the at least one heat exchanger.

20. The method according to claim 19, further comprising flowing at least a portion of the liquid natural gas to a storage tank.

21. The method according to claim 20, further comprising flowing at least a portion of the cooling stream back into the source of gas.

22. The method according to claim 21, further comprising compressing the at least a portion of the cooling stream prior to flowing it into the source of unpurified natural gas.

23. The method according to claim 1, further comprising compressing the portion of the natural gas flowed from the source prior to dividing the portion of natural gas into at least a process stream and a cooling stream.

24. The method according to claim 1, further comprising flowing the process stream through at least one other heat exchanger subsequent flowing the process stream through a first compressor and prior to flowing the cooling stream through the first side of the at least one heat exchanger.

25. A liquefaction plant comprising:

a first flow path defined and configured for sequential delivery of a first stream of gas through a first compressor and a first side of at least one heat exchanger;

a second flow path defined and configured for sequential delivery of a second stream of gas through a second compressor and a second side of the at least one heat exchanger;

a product flow path defined and configured for delivery of the first stream of gas from the first flow path through at least one expansion device and into a gas liquid separator for producing a slurry of liquid natural gas and solid carbon dioxide from the at least a portion of the process stream within the liquid-gas separator; and

a transfer tank located and configured to receive a solid-liquid slurry from the gas-liquid separator to maintain adequate transfer pressure of the slurry delivered from the separator.

26. The liquefaction plant of claim 25, wherein the second flow path is further defined and configured to deliver the second stream of gas through an expander subsequent the second compressor and prior to the second side of the at least one heat exchanger.

27. The liquefaction plant of claim 26, wherein the second flow path is further defined and configured to deliver the second stream of gas through at least one other heat exchanger subsequent the second compressor and prior to expander.

28. The liquefaction plant of claim 25, wherein the at least one transfer tank includes at least two transfer tanks which are in selective communication with the gas-liquid separator.

29. The liquefaction plant of claim 28, further comprising at least one hydrocyclone in selective communication with the at least one transfer tank.

30. The liquefaction plant of claim 29, further comprising a diversion tank in communication with an overflow of the at least one hydrocyclone.

31. The liquefaction plant of claim 30, further comprising a pump located and configured to convey a mass of liquid from the diversion tank to the second side of the at least one heat exchanger.

32. The liquefaction plant of claim 30, further comprising a storage tank in selective communication with the diversion tank.

33. The liquefaction plant of claim 30, further comprising at least one filter disposed in a flow path extending between the at least one hydrocyclone and the diversion tank.

34. The liquefaction plant of claim 29, further comprising a sublimation tank in communication with an underflow of the at least one hydrocyclone.

35. The liquefaction plant of claim 25, further comprising a recompression compressor configured to receive a flow of gas from the second side of the at least one heat exchanger.

36. The liquefaction plant of claim 35, further comprising another flow path from the recompression compressor to an exit of the plant.