Warewashing composition for use in automatic dishwashing machines, and methods for manufacturing and using

• US 7,638,473 B2
• Filed: 10/13/2008
• Issued: 12/29/2009
• Est. Priority Date: 07/02/2003
• Status: Expired due to Fees

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Smith, Kim R., Man, Victor F., Olson, Keith E., Lentsch, Steven E., Bartelme, Michael J., Baum, Burton M., Kestell, Howie, Everson, Terence P.
• Primary Examiner(s): Boyer; Charles I
• Application Number:
  US12/250,177
• Publication Number:
  US 20090038649A1
• Time in Patent Office: 442 Days
• Field of Search: 510/220, 510/224, 510/225, 510/227, 510/233, 510/367, 510/379, 510/439, 510/441, 510/445, 510/485, 510/508, 510/514, 510/521
• US Class Current: 510/225
• CPC Class Codes: C11D 17/0052 Cast detergent compositions
• CPC Class Codes: C11D 3/0073 Anticorrosion compositions
• CPC Class Codes: C11D 3/02 Inorganic compounds ; Elemental compounds
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 3/12 Water-insoluble compounds
• CPC Class Codes: C11D 3/2075 Carboxylic acids-salts thereof

Abstract

A warewashing detergent composition is provided according to the invention. The warewashing detergent composition includes a cleaning agent, an alkaline source, and a corrosion inhibitor. The cleaning agent comprises a detersive amount of a surfactant. The alkaline source is provided in an amount effective to provide a use composition having a pH of at least about 8. The corrosion inhibitor includes a source of aluminum ion and a source of zinc ion. The relative amounts of the source of zinc ion and the source of aluminum ion can be controlled to reduce visible filming when the warewashing detergent composition is used in the presence of hard water. Methods for using and manufacturing a warewashing detergent composition are provided.

Claims

1. A method for using a warewashing detergent composition, the method comprising:

(a) diluting a solid warewashing detergent composition with water at a dilution ratio of water to warewashing detergent composition of at least about 20;

1 to form a warewashing detergent use composition, wherein the warewashing detergent use composition comprises;

(i) a cleaning agent comprising a detersive amount of a surfactant;

(ii) an alkaline source in an amount effective to provide the use composition with a pH of at least about 8, wherein the alkaline source comprises at least one of sodium hydroxide, potassium hydroxide, or mixtures thereof; and

(iii) between about 6 ppm and about 300 ppm of a corrosion inhibitor for reducing corrosion of glass, the corrosion inhibitor comprising a source of zinc ion and a source of aluminum ion in amounts sufficient to provide the use composition comprising zinc ion and aluminum ion at a weight ratio of zinc ion to aluminum ion of at least about 2;

1; and

(b) washing ware with the use composition in an automatic dishwashing machine.

2. A method according to claim 1, wherein the water diluting the warewashing detergent composition comprises water having a total dissolved solids content of greater than about 200 ppm.

3. A method according to claim 1, wherein the use composition further comprises a free calcium ion concentration of greater than about 200 ppm.

4. A method according to claim 1, wherein the amount of the source of zinc ion and the amount of the source of aluminum ion is sufficient to provide a weight ratio of zinc ion to aluminum ion of between about 20:

1 and about 3;

1.

5. A method according to claim 1, wherein the amount of the source of zinc ion and the amount of the source of aluminum ion is sufficient to provide a weight ratio of zinc ion to aluminum ion of between about 15:

1 and about 4;

1.

6. A method according to claim 1, wherein the cleaning agent comprises at least one of an anionic surfactant, a nonionic surfactant, a cationic surfactant, and a zwitterionic surfactant.

7. A method according to claim 1, the source of aluminum ion comprises at least one of sodium aluminate, aluminum bromide, aluminum chlorate, aluminum chloride, aluminum iodide, aluminum nitrate, aluminum sulfate, aluminum acetate, aluminum formate, aluminum tartrate, aluminum lactate, aluminum oleate, aluminum bromate, aluminum borate, aluminum potassium sulfate, aluminum zinc sulfate, aluminum phosphate, aluminum oxide, aluminum silicate, and mixtures thereof.

8. A method according to claim 2, wherein the source of aluminum ion comprises a component characterized by the United States Food and Drug Administration as a direct or indirect food additive.

9. A method according to claim 1, wherein the source of aluminum ion comprises particles having an average particle size of less than about 500 nanometers.

10. A method according to claim 1 wherein the source of zinc ion comprises at least one of zinc chloride, zinc sulfate, zinc nitrate, zinc iodide, zinc thiocyanate, zinc fluorosilicate, zinc dichromate, zinc chlorate, sodium zincate, zinc gluconate, zinc acetate, zinc benzoate, zinc citrate, zinc lactate, zinc formate, zinc bromate, zinc bromide, zinc fluoride, zinc fluosilicate, zinc salicylate, zinc oxide, zinc silicate, and mixtures thereof.

11. A method according to claim 1, wherein the source of zinc ion comprises a component characterized by the United States Food and Drug Administration as a direct or indirect food additive.

12. A method according to claim 1, wherein the source of zinc ion comprises particles having an average particle size of less than about 500 nanometers.