Use of an adsorbent for the removal of liquid, gaseous and/or dissolved constituents from a process stream

• US 7,641,800 B2
• Filed: 06/24/2005
• Issued: 01/05/2010
• Est. Priority Date: 08/18/2000
• Status: Expired due to Fees

• Current Assignee: Veolia Water Solutions & Technologies Support
• Original Assignee: OTV S.A. (Veolia Environnement SA)
• Inventors: van Strien, Cornelis Johannes Govardus, Schomaker, Elwin
• Primary Examiner(s): Savage; Matthew O
• Application Number:
  US11/165,781
• Publication Number:
  US 20060011543A1
• Time in Patent Office: 1,656 Days
• Field of Search: 210/634, 210/635, 210/656, 210/660, 210/671, 210/673, 210/679, 210/680, 210690-694, 95/84, 95/92
• US Class Current: 210/670
• CPC Class Codes: B01J 20/165 Natural alumino-silicates, e.g. zeolites
• CPC Class Codes: B01J 20/20 comprising free carbon; comprising carbon obtained by carbonising processes
• CPC Class Codes: B01J 20/264 derived from different types of monomers, e.g. linear or branched copolymers, block copolymers, graft copolymers
• CPC Class Codes: B01J 20/267 Cross-linked polymers
• CPC Class Codes: B01J 20/28004 Sorbent size or size distribution, e.g. particle size
• CPC Class Codes: B01J 20/28014 characterised by their form
• CPC Class Codes: B01J 20/28016 Particle form
• CPC Class Codes: B01J 20/28023 Fibres or filaments fibres or filaments in the form of membranes B01J20/28038; B01J20/28007 takes precedence
• CPC Class Codes: B01J 20/2803 Sorbents comprising a binder, e.g. for forming aggregated, agglomerated or granulated products
• CPC Class Codes: B01J 20/28097 being coated, filled or plugged with specific compounds
• CPC Class Codes: B01J 20/3287 Layers in the form of a liquid
• CPC Class Codes: B01J 20/3416 of sorbents or filter aids comprising free carbon, e.g. activated carbon
• CPC Class Codes: B01J 20/3425 of sorbents or filter aids comprising organic materials
• CPC Class Codes: B01J 20/3433 of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
• CPC Class Codes: B01J 20/3466 with steam
• CPC Class Codes: B01J 2220/44 Materials comprising a mixture of organic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: B01J 2220/46 Materials comprising a mixture of inorganic and organic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: B01J 2220/58 Use in a single column

Abstract

A process for the removal of liquid, gaseous and/or dissolved constituents from a process stream. The process stream is contacted with an adsorbent comprising a first porous material which has been incorporated into a second porous material at least 30 vol. % of the pores of the first and second porous materials of which are filled with an extraction liquid. The affinity between the adsorbent and the constituents to be removed exceeds the affinity between the constituents and the extraction liquid.

Claims

1. A process for the removal of liquid, gaseous and/or dissolved constituents from a process stream, comprising contacting the process stream with an adsorbent comprising a first porous material and which has been incorporated into a second porous material, and wherein at least 30 vol. % of the pores of the first and second porous materials of which is filled with an extraction liquid including paraffin oil and a dialkyl phthalate with an alkyl group having eight to sixteen carbon atoms, and where the affinity between the adsorbent and the constituents to be removed exceeds the affinity between said constituents and the extraction liquid.

2. The process according to claim 1 wherein at least 50 vol. % of the pores is filled with an extraction liquid.

3. The process according to claim 1 wherein at least 90 vol. % of the pores is filled with an extraction liquid.

4. The process according to claim 1 wherein the amount of adsorbent is at least 2.5 wt. %, calculated on the overall solids content.

5. The process according to claim 1 wherein the adsorbent is selected from the group of activated carbon, zeolites, carbonized sulphonated cross-linked polystyrene, and cross-linked polystyrene.

6. The process according to claim 1 wherein the adsorbent comprising the first porous material is incorporated into the second porous material obtained by dissolving a polymer as the second porous material in one or more liquid and miscible compounds at a temperature above the upper critical phase separation temperature Tc in the presence of 2.5 to 80 wt. %, calculated on the overall solids content, of a first porous material with adsorbent properties which is solid at said temperature, followed by a lowering of the temperature and the forming of a fibre, film, granulate or powder from the polymer filled with the liquid compounds, optionally followed by the removal of at least part of the liquid therefrom an by refilling or filling up with an extraction liquid to at least 30% of the pore volume.

7. The process according to claim 6 wherein the weight percentage of the adsorbent amounts to 20 to 60 wt. % of the overall solids content.

8. The process according to claim 6 wherein the weight ratio of adsorbent to extraction liquid is in the range of 1/10 to 2/1.

9. The process according to claim 1 wherein the adsorbent or the second porous material into which the adsorbent has been incorporated is present in the form of a granulate or powder having a particle size of 0.1 to 10 mm.

10. The process according to claim 1 wherein the material after becoming saturated with the constituent to be extracted is regenerated with steam.

11. A process for the removal of liquid, gaseous and/or dissolved constituents from a process stream, comprising contacting the process stream with an adsorbent comprising a first porous material and which has been incorporated into a second porous material at least 30 vol. % of the pores of the first and second porous materials of which is filled with an extraction liquid comprising diisodecyl phthalate, and where the affinity between the adsorbent and the constituents to be removed exceeds the affinity between said constituents and the extraction liquid.

12. A process for the removal of liquid, gaseous and/or dissolved constituents from a process stream, comprising contacting the process stream with an adsorbent comprising a first porous material and which has been incorporated into a second porous material, and wherein at least 30 vol. % of the pores of the first and second porous materials of which is filled with an extraction liquid including paraffin oil and a dialkyl phthalate with an alkyl group having eight to sixteen carbon atoms, and where the affinity between the adsorbent and the constituents to be removed exceeds the affinity between said constituents and the extraction liquid, and wherein the adsorbent is selected from the group consisting of activated carbon, zeolites, carbonized sulphonated cross-linked polystyrene, and cross-linked polystyrene.