Lubricant and fuel additives derived from treated amines
First Claim
1. A composition for use as an additive for fuels or lubricants comprising a reaction product comprising Mannich adducts derived from hydrocarbyl-substituted phenols, formaldehydes and treated amines, wherein the reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography, and wherein the treated amine comprises an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or at least one homologue thereof followed by reduction to the primary amine,with the proviso that the aliphatic amine is chosen from aminoguanidine bicarbonate;
- a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the proviso that the aromatic amine is chosen from N-arylphenylenediamines; and
with the further proviso that if the aliphatic amine is a hydroxyamine, the hydroxyamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol.
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Accused Products
Abstract
A composition for use as an additive for fuels or lubricants. The composition includes a reaction product of a treated amine and a compound selected from the group consisting of hydrocarbyl succinic anhydrides, Mannich adducts derived from hydrocarbyl-substituted phenols reacted with formaldehydes, ethylene-propylene copolymers grafted with ethylenically unsaturated carboxylic groups, copolymers of unsaturated acids and polyolefins, and acid or ester functionalized hydrocarbon polymers. The reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography. The treated amine includes an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with an aliphatic or aromatic nitrile and hydrogen.
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Citations
38 Claims
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1. A composition for use as an additive for fuels or lubricants comprising a reaction product comprising Mannich adducts derived from hydrocarbyl-substituted phenols, formaldehydes and treated amines, wherein the reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography, and wherein the treated amine comprises an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or at least one homologue thereof followed by reduction to the primary amine,
with the proviso that the aliphatic amine is chosen from aminoguanidine bicarbonate; - a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the proviso that the aromatic amine is chosen from N-arylphenylenediamines; and with the further proviso that if the aliphatic amine is a hydroxyamine, the hydroxyamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 35, 38)
- a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
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12. A lubricant additive comprising a reaction product comprising Mannich adducts derived from hydrocarbyl-substituted phenols, formaldehydes and treated amines, wherein the reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography, and wherein the treated amine comprises an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or one of its homologues, followed by reduction to the primary amine,
with the proviso that the aliphatic amine is chosen from aminoguanidine bicarbonate; - a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the proviso that the aromatic amine is chosen from N-arylphenylenediamines; and with the further proviso that if the aliphatic or aromatic amine is a hydroxyamine, the hydroxyamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol. - View Dependent Claims (13, 14, 15, 16, 21)
- a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
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17. A fuel additive comprising a reaction product comprising Mannich adducts derived from hydrocarbyl-substituted phenols, formaldehydes and treated amines, wherein the reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography, and wherein the treated amine comprises an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or at least one homologue thereof, followed by reduction to the primary amine
with the proviso that the aliphatic amine is chosen from aminoguanidine bicarbonate; - a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the proviso that the aromatic amine is chosen from N-arylphenylenediamines; and with the further proviso that if the aliphatic or aromatic amine is a hydroxyamine, the hydroxyamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol. - View Dependent Claims (18, 19, 20)
- a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
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22. A method of lubricating moving parts of a vehicle, the method comprising using as a lubricating oil for one or more moving parts of the vehicle a lubricant composition containing a lubricant and a lubricant additive, the lubricant additive including a reaction product comprising Mannich adducts derived from hydrocarbyl-substituted phenols, formaldehydes and treated amines, wherein the reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography, and wherein the treated amine comprises an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or a homologue thereof, followed by reduction to the primary amine,
with the proviso that the aliphatic amine is chosen from aminoguanidine bicarbonate; - a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the proviso that the aromatic amine is chosen from N-arylphenylenediamines; and with the further proviso that if the aliphatic or aromatic amine is a hydroxyamine, the hydroxyamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol. - View Dependent Claims (23, 24, 25, 26, 27)
- a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
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28. A method for lubricating moving parts comprising contacting the moving parts with a lubricant composition containing a lubricant and a lubricant additive, the lubricant additive comprising a reaction product comprising Mannich adducts derived from hydrocarbyl-substituted phenols, formaldehydes and treated amines, wherein the reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography, and wherein the treated amine comprises an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or homologue thereof, followed by reduction to the primary amine,
with the proviso that the aliphatic amine is chosen from aminoguanidine bicarbonate; - a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the proviso that the aromatic amine is chosen from N-arylphenylenediamines; and with the further proviso that if the aliphatic or aromatic amine is a hydroxyamine, the hydroxyamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol. - View Dependent Claims (29, 30, 31, 32)
- a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
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33. A method for decreasing combustion chamber deposits and/or intake valve deposits in an engine comprising providing a fuel containing an additive comprising Mannich adducts derived from hydrocarbyl-substituted phenols reacted with formaldehydes and amines,
wherein the amines comprise treated aliphatic or aromatic amines, wherein the treated amines comprise an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or homologue thereof, followed by reduction to the primary amine, with the proviso that the aliphatic amine is chosen from aminoguanidine bicarbonate; - a mixture of amines comprising tetraethylene pentamine, and pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the proviso that the aromatic amine is chosen from N-arylphenylenediamines; and with the further proviso that if the aliphatic or aromatic amine is a hydroxyamine, the hydroxyamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol. - View Dependent Claims (34)
- a mixture of amines comprising tetraethylene pentamine, and pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
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36. A composition for use as an additive for fuels or lubricants comprising a reaction product comprising Mannich adducts derived from hydrocarbyl-substituted phenols, formaldehydes and treated amines, wherein the reaction product is oil soluble and has a number average molecular weight ranging from about 900 to about 50,000 as determined by gel permeation chromatography, and wherein the treated amine comprises an aliphatic or aromatic amine containing at least one primary or secondary amino group reacted with acrylonitrile or at least one homologue thereof, followed by reduction to the primary amine,
with the proviso that the aliphatic amine is chosen from anioguanidine bicarbonate; - a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
heavy polyamines; and
hydroxyamines,with the further proviso that if the aliphatic amine is a hydroxylamine, the hydroxylamine is chosen from oligomers, polymers, aminoethylethanolamine, aminopropyldiethanolamine, partially propoxylated hexamethylene diamine, 3-amino-1,2-propanediol, tris(hydroxymethyl)aminomethane, and 2-amino-1,3-propanediol. - View Dependent Claims (37)
- a mixture of amines comprising tetraethylene pentamine, pentaethylene hexamine, hexaethylene heptamine, and compounds having the structure H2NCH2CH2(NHCH2CH2)xNH2, wherein x is 3 or higher;
Specification