Single phase color change agents

• US 7,651,989 B2
• Filed: 08/29/2003
• Issued: 01/26/2010
• Est. Priority Date: 08/29/2003
• Status: Active Grant

• Current Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Original Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Inventors: Kim, Jaeho, MacDonald, John Gavin, Wei, Ning, Yang, Kaiyuan, Huang, Yanbin
• Primary Examiner(s): Ogden, Jr.; Necholus
• Application Number:
  US10/651,421
• Publication Number:
  US 20050049157A1
• Time in Patent Office: 2,342 Days
• Field of Search: 510/130, 510/156, 510/424, 510/481, 436/136
• US Class Current: 510/130
• CPC Class Codes: C11D 3/0042 Reducing agents
• CPC Class Codes: C11D 3/221 Mono, di- or trisaccharides or derivatives thereof
• CPC Class Codes: C11D 3/40 Dyes ; Pigments

Abstract

There is provided a color change composition that remains stable in a single phase and that contains an indicator that produces an observable color change after a period of time to show that sufficient cleaning has been done or to indicate the thoroughness of the cleaning. This use indicating color change is useful for, for example, in soap for teaching children to wash their hands for a sufficient period of time. This composition may be added to many different base materials to indicate time of use or as a way to introduce enjoyment to the activity.

Claims

1. A liquid cleansing formulation comprising:

a base material, the base material comprising water and a surfactant;

a reducing agent, wherein the reducing agent includes a sugar; and

a redox dye, wherein the ratio of the reducing agent to the redox dye is at least about 5 to 1 and wherein the redox dye is present in the cleansing formulation in an amount of from about 0.001 to about 0.5 weight percent and the reducing agent is present in the cleansing formulation in an amount of from about 0.1 to about 2.0 weight percent;

wherein exposure of the liquid cleansing formulation to an excess concentration of oxygen causes oxidation of the redox dye and produces an observable color change.

2. The liquid cleansing formulation of claim 1, wherein the ratio of the reducing agent to the redox dye is at least about 10 to 1.

3. The liquid cleansing formulation of claim 1, wherein the sugar includes glucose, fructose, galactose, xylose, or combinations thereof.

4. The liquid cleansing formulation of claim 3, wherein the sugar includes glucose.

5. The liquid cleansing formulation of claim 1, wherein the reducing agent is present in the cleansing formulation in an amount of from about 0.3 to about 1.0 weight percent.

6. The liquid cleansing formulation of claim 1, wherein the redox dye includes Food Blue 1, Food Blue 2, Food Green 3, Basic Blue 17, resazurin, FD&

C Blue No. 2, FD&

C Green No. 3, 1,9-dimethyl methylene blue, saframine O, or combinations thereof.

7. The liquid cleansing formulation of claim 1, further comprising a pH sensitive dye.

8. The liquid cleansing formulation of claim 7, wherein the pH sensitive dye includes carminic acid, bromocresol green, chrysoidin, methyl red/Na salt, cochineal, chlorphenol red, bromocresol purple, 4-nitrophenol, alizarin, nitrazine yellow, bromothymol blue, brilliant yellow, neutral red, rosolic acid, phenol red, 3-nitrophenol, orange II, or combinations thereof.

9. The liquid cleansing formulation of claim 1, wherein the redox dye is present in the cleansing formulation in an amount of from about 0.003 to about 0.1 weight percent.

10. The liquid cleansing formulation of claim 1, further comprising a catalyst.

11. The liquid cleansing formulation of claim 10, wherein the catalyst is an enzyme.

12. The liquid cleansing formulation of claim 11, wherein the enzyme is glucose oxidase.

13. The liquid cleansing formulation of claim 1, further comprising a pH buffer.

14. The liquid cleansing formulation of claim 1, wherein the reducing agent further includes a hydroquinone, ascorbic acid, cysteine, dithionite, ferric ions, copper ions, silver ions, chlorine, phenol, permanganate ions, glucothione, iodine, iron protoporyphyrin complex, iron-sulfur protein, or combinations thereof.

15. The liquid cleansing formulation of claim 1, wherein the base material comprises an oil, emulsifier, film former, wax, perfume, preservative, emollient, solvent, thickener, humectant, chelating agent, stabilizer, pH adjuster, or combinations thereof.

16. The liquid cleansing formulation of claim 1, wherein the reducing agent has a reduction potential of about +0.9 to about −

0.9 volts.

17. The liquid cleansing formulation of claim 1, wherein the formulation is a soap.

18. The liquid cleansing formulation of claim 1, wherein the formulation is a skin lotion.

19. The liquid cleansing formulation of claim 1, wherein the formulation is a hard surface cleaner.