Toner particles of controlled morphology

• US 7,662,535 B2
• Filed: 12/15/2006
• Issued: 02/16/2010
• Est. Priority Date: 12/15/2006
• Status: Expired due to Fees

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Taft, Sandra G., Nair, Mridula, Yang, Xiqiang
• Primary Examiner(s): Chapman; Mark A
• Application Number:
  US11/611,208
• Publication Number:
  US 20080145779A1
• Time in Patent Office: 1,159 Days
• Field of Search: 430/137.14, 430/137.1
• US Class Current: 430/137.14
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/08702 comprising macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
• CPC Class Codes: G03G 9/08704 Polyalkenes
• CPC Class Codes: G03G 9/08708 Copolymers of styrene
• CPC Class Codes: G03G 9/08711 with esters of acrylic or methacrylic acid
• CPC Class Codes: G03G 9/08713 Polyvinylhalogenides
• CPC Class Codes: G03G 9/08722 Polyvinylalcohols; Polyallylalcohols; Polyvinylethers; Polyvinylaldehydes; Polyvinylketones; Polyvinylketals
• CPC Class Codes: G03G 9/08728 Polymers of esters

Abstract

The present invention is a method for the preparation of electrostatographic toner that includes the following steps. A polymer material is dissolved in an organic solvent to form an organic phase that includes a metal complex of zinc dimethyldithiocarbamate; zinc diethyldithiocarbamate; dibenzyldithiocarbamate, zinc di-n-butyldithiocarbamate. The organic phase is dispersed in an aqueous phase that includes a particulate stabilizer to form a dispersion and the resultant dispersion is homogenized. The organic solvent is evaporated and the resultant product is recovered, washed and dried.

Claims

1. A method for the preparation of electrostatographic toner comprising the steps of:

a) dissolving a polymer material in an organic solvent to form an organic phase, where the organic phase further includes a shape control agent comprising a metal complex selected from the group consisting of zinc dimethyldithiocarbamate;

zinc diethyldithiocarbamate;

zinc dibenzyldithiocarbamate, and zinc di-n-butyldithiocarbamate;

b) dispersing the organic phase in an aqueous phase comprising a particulate stabilizer to form a dispersion and homogenizing the resultant dispersion;

c) evaporating the organic solvent and recovering a resultant product having a shape modified by the shape control agent; and

d) washing and drying the resultant product.

2. The method of claim 1 wherein a charge control agent or pigment is added in step a).

3. The method of claim 1 wherein a promoter is added in step in b).

4. The method of claim 3 wherein the promoter is selected from the group consisting of sulfonated polystyrene, alginate, carboxymethylcellulose, tetramethyl ammonium hydroxide, tetramethyl ammonium chloride, diethylaminoethyl methacrylate, water soluble complex resinous amine condensation products of ethylene oxide, urea, formaldehyde, polyethyleneimine gelatin, casein, albumin, gluten and methoxycellulose.

5. The method of claim 3 wherein the promoter is present an amount of from about 0.2 to about 0.6 parts per 100 parts, by weight, of aqueous phase.

6. The method of claim 1 wherein the solvent is selected from the group consisting of chloroform, dichloromethane, ethyl acetate, vinyl chloride, and methyl ethyl ketone.

7. The method of claim 1 wherein the amount of particulate stabilizer is between 1 to 15 parts, by weight, based on 100 parts of total solids in the toner.

8. The method of claim 1 wherein the ratio of the aqueous phase to the organic phase, by volume, ranges from 1:

1 to 9;

1.

9. The method of claim 1 wherein the organic phase contains charge control agents, lubricants or waxes.

10. The method of claim 1 wherein the polymer material comprises a homopolymer or copolymer selected from the group consisting of polyethylene, polypropylene, polyisobutylene, polyisopentylene, polytrifluoroolefins, polyamides, acrylic resins, ethylene-methyl acrylate copolymers, ethylene-ethyl acrylate copolymers, ethylene-ethyl methacrylate copolymers, polystyrene and copolymers of styrene with unsaturated monomers, polyesters, polyvinyl resins, ethylene-allyl alcohol copolymers, polytetrafluoroethylene, polytrifluorochloroethylene, poly(hexamethylene adipamide), poly(hexamethylene sebacamide), polycaprolactam, poly(methyl methacrylate), poly(methyl acrylate), poly(ethyl methacrylate) and poly(styrene-methyl methacrylate).

11. The method of claim 1 wherein the metal complex comprises from 0.02 to 2.0 percent of the organic phase.

12. The method of claim 1 wherein the organic phase further comprises pigments.

13. The method of claim 12 wherein the pigment is selected from the group consisting of phthalocyanines, lithols, TiO₂, carbon black, anthraquinone vat pigments, brominated pyranthrones and azo pigments.

14. The method of claim 12 wherein the pigments comprise an amount to give a content thereof in the toner from about 1% to 40%, by weight, based upon the weight of the resultant product.