Reducing mercury emissions from the burning of coal

• US 7,674,442 B2
• Filed: 01/09/2009
• Issued: 03/09/2010
• Est. Priority Date: 03/17/2005
• Status: Active Grant

• Current Assignee: Nox Ii Ltd. (Arthur J Gallagher & Company)
• Original Assignee: Nox Ii Ltd. (Arthur J Gallagher & Company)
• Inventors: Comrie, Douglas C.
• Primary Examiner(s): Vanoy; Timothy C
• Application Number:
  US12/351,191
• Publication Number:
  US 20090117019A1
• Time in Patent Office: 424 Days
• Field of Search: 431/2, 423/210, 423/242.1, 423/244.01, 423/244.07, 423/DIG.5, 445/05, 446/03, 446/04, 446/20, 446/21, 446/22, 446/24, 422/105, 422/108, 422/111
• US Class Current: 423/210
• CPC Class Codes: B01D 2253/104 Alumina
• CPC Class Codes: B01D 2253/11 Clays
• CPC Class Codes: B01D 2257/30 Sulfur compounds
• CPC Class Codes: B01D 2257/602 Mercury or mercury compounds
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/30 Controlling by gas-analysis apparatus regulating non electrical variables in general G05D
• CPC Class Codes: B01D 53/485 containing only one sulfur compound other than sulfur oxides or hydrogen sulfide
• CPC Class Codes: B01D 53/64 Heavy metals or compounds thereof, e.g. mercury
• CPC Class Codes: B01D 53/78 with gas-liquid contact
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/043 Carbonates or bicarbonates, e.g. limestone, dolomite, aragonite
• CPC Class Codes: B01J 20/046 containing halogens, e.g. halides
• CPC Class Codes: B01J 20/06 comprising oxides or hydroxides of metals not provided for in group B01J20/04
• CPC Class Codes: B01J 20/12 Naturally occurring clays or bleaching earth
• CPC Class Codes: B01J 20/16 Alumino-silicates B01J20/12 takes precedence
• CPC Class Codes: B01J 2220/42 Materials comprising a mixture of inorganic materials materials coated or impregnated on a carrier B01J20/32
• CPC Class Codes: C10L 10/00 Use of additives to fuels or fires for particular purposes additives for liquid carbonaceous fuels characterised by their chemical nature C10L1/10; using binders for briquetting solid fuels C10L5/10; using additives to improve the combustion of solid fuels C10L9/10
• CPC Class Codes: C10L 10/02 for reducing smoke development
• CPC Class Codes: C10L 9/10 by using additives
• CPC Class Codes: F23J 15/00 Arrangements of devices for treating smoke or fumes
• CPC Class Codes: F23J 15/025 : using filters
• CPC Class Codes: F23J 15/04 : using washing fluids scrubbers for removing solids only F23J15/022
• CPC Class Codes: F23J 7/00 : Arrangement of devices for supplying chemicals to fire
• CPC Class Codes: F23K 1/00 : Preparation of lump or pulverulent fuel in readiness for delivery to combustion apparatus
• CPC Class Codes: F23K 2201/505 : with additives
• CPC Class Codes: Y02P 40/10 : Production of cement, e.g. improving or optimising the production methods; Cement grinding
• CPC Class Codes: Y10S 423/05 : Automatic, including computer, control

Abstract

Processes and compositions are provided for decreasing emissions of mercury upon combustion of fuels such as coal. Various sorbent compositions are provided that contain components that reduce the level of mercury and/or sulfur emitted into the atmosphere upon burning of coal. In various embodiments, the sorbent compositions are added directly to the fuel before combustion; are added partially to the fuel before combustion and partially into the flue gas post combustion zone; or are added completely into the flue gas post combustion zone. In preferred embodiments, the sorbent compositions comprise a source of halogen and preferably a source of calcium. Among the halogens, iodine and bromine are preferred. In various embodiments, inorganic bromides make up a part of the sorbent compositions.

Claims

1. A method for burning coal in a coal burning process with reduced levels of undesirable elements escaping into the environment, the method comprising

adding a mercury sorbent composition comprising a halogen into the coal burning process;

adding a sulfur sorbent composition comprising a calcium powder into the coal burning process;

burning the coal to produce ash and combustion gases;

measuring the level of sulfur in the combustion gases;

measuring the level of mercury in the combustion gases;

adjusting the amount of mercury sorbent composition added into the coal burning process based on the measured level of mercury; and

adjusting the amount of sulfur sorbent composition added into the coal burning process based on the measured level of sulfur.

2. A method according to claim 1, wherein the mercury sorbent composition comprises calcium bromide.

3. A method according to claim 1, comprising adding a sufficient amount of bromine to capture in the ash 90% or more of the mercury in the coal.

4. A method according to claim 1, wherein the mercury sorbent composition comprises calcium bromide.

5. A method according to claim 1, wherein the sulfur sorbent composition comprises Portland cement, cement kiln dust, or lime kiln dust.

6. A method according to claim 1, wherein the sulfur sorbent composition comprises 60-71% CaO, 12-15% SiO₂, 4-18% Al₂O₃, 1-4% Fe₂O₃, 0.5-1.5% MgO, and 0.1-0.5% Na₂O.

7. A method according to claim 1, wherein the sulfur sorbent comprises an aluminosilicate clay.

8. A method according to claim 7, wherein the aluminosilicate clay comprises montmorillonite or kaolin.

9. A method according to claim 1, wherein the sulfur sorbent composition comprises at least 2% silica and at least 2% alumina.

10. A method according to claim 1, comprising applying a liquid composition comprising a bromine compound onto the coal pre-combustion.

11. A method according to claim 10, wherein the liquid composition comprises calcium bromide.

12. A method according to claim 1, comprising applying the sulfur sorbent composition onto the coal.

13. A method according to claim 12, wherein the powder sorbent comprises an aluminosilicate clay and at least one of Portland cement, cement kiln dust, lime kiln dust, calcium oxide, calcium hydroxide, and calcium carbonate.

14. A method according to claim 1, comprising adding the mercury sorbent composition at a rate of 0.01-10% by weight based on the weight of the coal.

15. A method according to claim 1, comprising adding the sulfur sorbent composition at a rate of 1% to 9% by weight based on the weight of the coal.

16. A method according to claim 1, comprising adding the sulfur sorbent along with the mercury sorbent.

17. A method for reducing mercury emissions from a coal burning furnace, the method comprising:

applying a sorbent composition onto coal, wherein the sorbent composition comprises a halogen compound and further comprises a nitrate compound, a nitrite compound, or a combination of a nitrate and nitrite compound;

delivering the coal with the sorbent into the furnace of a coal burning plant;

combusting the coal with the sorbent to produce ash and flue gases;

measuring a level of mercury in the flue gases; and

adjusting the amount of sorbent composition added, depending on the measured mercury level.

18. A method according to claim 17, wherein the sorbent composition comprises calcium bromide.

19. A method according to claim 17, wherein the sorbent composition comprises calcium nitrate or calcium nitrite.

20. A method according to claim 17, wherein the halogen compound comprises a bromine compound.

21. A method according to claim 17, further comprising adding a sorbent composition comprising a halogen and one of a nitrite compound, a nitrate compound, and a combination of nitrite and nitrate compounds into the flue gases where the temperature is 1500°

F. to 2700°

F.

22. A method according to claim 17, wherein the sorbent composition is a liquid.

23. A method according to claim 17, wherein the sorbent composition is a solid.

24. A method for reducing mercury emissions from a furnace in a coal burning facility, the method comprising:

burning coal in the furnace to produce ash and flue gases;

injecting a sorbent composition into the convective pathway downstream of the furnace where the flue gases have a temperature of 1500°

F. to 2700°

F.;

measuring the level of mercury escaping from the facility; and

adjusting the rate of injection of the sorbent composition depending on the measured mercury level,

wherein the sorbent composition comprises a source of halogen and a source of calcium.

25. A method according to claim 24, wherein the sorbent composition comprises calcium bromide.

26. A method according to claim 24, wherein the sorbent composition further comprises a nitrite compound, a nitrate compound, or a combination of a nitrite compound and a nitrate compound.

27. A method according to claim 24, wherein the sorbent composition is a liquid.

28. A method according to claim 24, wherein the sorbent composition is a solid.

29. A method for reducing mercury emissions from a coal burning facility in a process comprising delivering coal to a furnace and combusting the coal in the furnace to produce ash and flue gases, the method comprising

a) at least one of

a1) adding a sorbent comprising an iodine compound onto the coal before it is delivered to the furnace;

and

a2) injecting a sorbent comprising an iodine compound into a convection path of the furnace where the temperature of the gases is 1500°

F. to 2700°

F.;

b) measuring a mercury level in the flue gases; and

c) adjusting the level of sorbent added in step a1) or step a2) depending on the measured mercury level in step b).

30. A method according to claim 29, wherein the sorbent comprises calcium iodide.

31. A method according to claim 29, wherein the sorbent is a liquid.

32. A method according to claim 29, wherein the sorbent is a solid.

33. A method according to claim 29, wherein the sorbent further comprises a source of calcium.

34. A method according to claim 29, comprising adding the sorbent comprising an iodine compound onto the coal before it is delivered to the furnace.

35. A method according to claim 29, comprising injecting the sorbent comprising an iodine compound into a convective pathway of the furnace where the temperature of the gases is 1500°

F. to 2700°

F.

36. A method according to claim 29, comprising adding a sorbent composition comprising an iodine compound onto the coal before it is delivered to the furnace;

and

injecting a sorbent comprising an iodine compound into a convective pathway of the furnace where the temperature of the gases is 1500°

F. to 2700°

F.