Method and apparatus for measuring the rate of permeation

• US 7,685,865 B2
• Filed: 03/16/2007
• Issued: 03/30/2010
• Est. Priority Date: 03/30/2006
• Status: Active Grant

• Current Assignee: Technolox Ltd.
• Original Assignee: Technolox Ltd.
• Inventors: Norenberg, Holger
• Primary Examiner(s): Williams; Hezron
• Assistant Examiner(s): KOLB, NATHANIEL J
• Application Number:
  US11/687,208
• Publication Number:
  US 20070227233A1
• Time in Patent Office: 1,110 Days
• Field of Search: 73/38
• US Class Current: 73/38
• CPC Class Codes: G01N 15/0826 and measuring fluid flow rate, i.e. permeation rate or pressure change

Abstract

A method and an apparatus are provided for measuring the rate of permeation of a gas or vapour through a test sample with the gas container detachable from the sensor. The gas container consists of an upstream and a downstream chamber in communication with a test sample. The upstream chamber of the gas container containing the test sample is filled with a gas or vapour. The pressure increase in the downstream chamber is monitored and recorded at successive increments of time. To estimate the rate of permeation one or more experimental pressure values can be used as input for a mathematical approximation procedure. Using the starting pressure and one or more pressure values taken at different times allows the gas container with the test sample to be detached from the sensor and hence an increased sample throughput is realised.

Claims

1. A method of measuring the rate of permeation of a gas or a vapour including water vapour through a material comprising:

providing a test sample made of the material in a gas container between the upstream chamber with volume V_up and a downstream chamber with volume V_down of the gas container;

providing a means to remove gas or vapour from the upstream chamber and the downstream chamber;

providing an amount of gas or vapour in the upstream chamber of the gas container;

providing one or more sensors in communication with the upstream chamber and downstream chamber for pressure measurement as a function of time;

approximating the experimental pressure data with an exponential function with an exponential parameter τ

;

wherein if it is a gas calculating the rate of permeation dN_down/dt from the exponential parameter and the amount of gas N₀ according to

${\frac{d<br><br>N_{\mathrm{down}}}{d<br><br>t}<br><br>}_{t=0}=\mathrm{\tau <br><br>}·<br><br>\frac{N_0·<br><br>V_{\mathrm{down}}}{V_{\mathrm{up}}+V_{\mathrm{down}}}<br><br>\left(1+\frac{V_{\mathrm{down}}}{V_{\mathrm{up}}}\right).$

wherein if it is a vapour calculating the rate of permeation dN_down/dt from the exponential parameter and the amount of water vapour N_up according to

${\frac{d<br><br>N_{\mathrm{down}}}{d<br><br>t}<br><br>}_{t=0}=\mathrm{\tau <br><br>}·<br><br>N_{\mathrm{up}}·<br><br>\frac{V_{\mathrm{down}}}{V_{\mathrm{up}}}.$

2. The method as claimed in claim 1 wherein the test sample is a film.

3. The method as claimed in claim 1 where the exponential parameter τ

is determined from one measured pressure value and the gas pressure the upstream chamber is initially filled at.

4. The method as claimed in claim 1 where the exponential parameter τ

is determined from one measured pressure value and the vapour pressure of the vapour.

5. The method as claimed in claim 1 wherein, after the step of calculating the rate of permeation the method further comprises:

removing the gas or vapour from the upstream chamber and the downstream chamber;

measuring successive pressure increases in the upstream and downstream chamber over successive increments of time;

adding the incremental pressure increases to obtain a total pressure increase;

calculating a total amount of gas or vapour outgassed from the sample using the total pressure increase and the ideal gas law.