Lithium sulfur rechargeable battery fuel gauge systems and methods

• US 7,688,075 B2
• Filed: 04/20/2005
• Issued: 03/30/2010
• Est. Priority Date: 04/20/2005
• Status: Active Grant

• Current Assignee: Sion Power Corporation
• Original Assignee: Sion Power Corporation
• Inventors: Kelley, Tracy E, Puglisi, Vincent J, Scordilis-Kelley, Chariclea
• Primary Examiner(s): Tso; Edward
• Assistant Examiner(s): Fantu; Yalkew
• Application Number:
  US11/111,262
• Publication Number:
  US 20060238203A1
• Time in Patent Office: 1,805 Days
• Field of Search: 324/426, 324/433, 320/132, 320/134, 320/133
• US Class Current: 324/426
• CPC Class Codes: G01R 31/389 Measuring internal impedance, internal conductance or related variables
• CPC Class Codes: G01R 31/392 Determining battery ageing or deterioration, e.g. state of health

Abstract

Systems and methods for accurately determining the state of charge and the relative age of lithium sulfur batteries are provided. The cell resistance and taper input charge of a particular type of lithium sulfur battery are respectively measured to determine the state of charge and age of the battery.

Claims

1. A method for creating a look-up table of cell resistance versus state of charge for a lithium sulfur battery of a particular type and determining the capacity thereof, said method comprising the steps of:

a) charging said battery until a voltage across said battery increases to a predetermined maximum voltage;

b) continuing to charge said battery at said predetermined maximum voltage until an input current to said battery decreases to a predetermined minimum current;

c) measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at 100% state of charge for said particular type of lithium sulfur battery;

d) recording said cell resistance at 100% state of charge;

e) discharging said battery at a discharge rate to a predetermined lower cutoff voltage and recording a discharge time period;

f) integrating said discharge time period with said discharge rate and storing the result, said integration result being defined as the battery capacity for said particular type of lithium sulfur battery;

g) measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at 0% state of charge for said particular type of lithium sulfur battery;

h) recording said cell resistance at 0% state of charge;

i) charging said battery with a predetermined percentage of said battery capacity so that a present battery state of charge exceeds a previous battery state of charge;

j) measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at the present state of charge for said particular type of lithium sulfur battery;

k) recording said cell resistance at the present state of charge;

l) repeating said steps (i), (j), and (k) until the present state of charge of said battery equals said battery capacity for said particular type of lithium sulfur battery; and

m) creating said look-up table of cell resistance versus state of charge for state of charge values from 0% to 100%.

2. The method of claim 1 further comprising the step of:

n) allowing said battery to stabilize for a period of time, wherein said period of time is the time required for the rate of change of the open-circuit voltage of said battery to decrease below a predefined threshold.

3. The method of claim 2, wherein said predefined threshold for rate of change of the open-circuit voltage is within a range of 0.001 to 0.01 Volts/minute.

4. The method of claim 1, wherein said predetermined percentage of said battery capacity is 10%.

5. The method of claim 1, wherein all the steps of claim 1 are repeated at a set of predetermined temperatures.

6. The method of claim 5, wherein said set of predetermined temperatures consists of −

40°

Celsius, −

30°

Celsius, −

20°

Celsius, −

10°

Celsius, 0°

Celsius, +10°

Celsius, +20°

Celsius, +30.degree. Celsius, +40°

Celsius, +50°

Celsius, and +60°

Celsius.

7. The method of claim 1, wherein all the steps of claim 1 are repeated at a set of predetermined ages in the life of said battery.

8. The method of claim 7, wherein said set of predetermined ages consists of said battery after having been subjected to 1, 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 200, 300, 400, 500, 600, 700, 800, 900, and 1000 charge/discharge cycles.

9. The method of claim 1, wherein said discharge rate is variable.

10. A method for creating a look-up table of cell resistance versus state of charge for a lithium sulfur battery of a particular type with a known capacity, said method comprising the steps of:

a) charging said battery until a voltage across said battery increases to a predetermined maximum voltage;

b) continuing to charge said battery at said predetermined maximum voltage until an input current to said battery decreases to a predetermined minimum current;

c) measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at 100% state of charge for said particular type of lithium sulfur battery;

d) recording said cell resistance at 100% state of charge;

e) discharging said battery by a predetermined percentage of the capacity of said battery so that a present battery state of charge is less than a previous battery state of charge;

f) measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at the present state of charge for said particular type of lithium sulfur battery;

g) recording said cell resistance at the present state of charge;

h) repeating said steps (e), (f), and (g) until the present state of charge of said battery equals a predetermined lower cutoff voltage; and

i) creating said look-up table of cell resistance versus state of charge for state of charge values from 100% to 0%.

11. A method for determining the state of charge of a lithium sulfur battery of a particular type using a look-up table of cell resistance versus state of charge for said particular type of lithium sulfur battery, said method comprising the steps of:

a) inputting a battery type into a computer;

b) measuring a cell resistance for said battery, said cell resistance being input into said computer;

c) executing a cell resistance correlation algorithm based on inputs comprising;

i) the type of said battery inputted into said computer; and

ii) the measured cell resistance for said battery; and

d) determining the state of charge of said lithium sulfur battery based on said cell resistance correlation algorithm.

12. The method of claim 11, wherein said cell resistance correlation algorithm comprises a table look-up followed by linear interpolation.

13. The method of claim 11, wherein said inputs to said cell resistance correlation algorithm further comprise measured battery temperature.

14. The method of claim 11 further comprising the step of:

e) inputting an age of said battery into said computer.

15. The method of claim 14, wherein said inputs to said cell resistance correlation algorithm further comprise the age of said battery inputted into said computer.

16. A method for creating a look-up table of taper input charge versus age for a lithium sulfur battery of a particular type, said method comprising the steps of:

a) subjecting said battery to a first known number of fully charging and discharging cycles;

b) charging said battery until a voltage across said battery increases to a predetermined maximum voltage;

c) taper charging said battery at said predetermined maximum voltage until an input current to said battery decreases to a predetermined minimum current and recording a taper charge time period;

d) integrating said taper charge time period by said input current during said taper charge time period and storing the product, said integration product being defined as the taper input charge for said particular type of lithium sulfur battery at the age of said particular number;

e) recording said taper input charge at said age of said particular number;

f) repeating said steps (a), (b), (c), (d), and (e) for additional known numbers of fully charging and discharging cycles for said battery, said recording step (e) recording said taper input charges for the additional known numbers of fully charging and discharging cycles for said battery; and

g) creating said look-up table of taper input charge versus age for said particular type of lithium sulfur battery using said first known and said additional known numbers of fully charging and discharging cycles for said battery.

17. The method of claim 16, wherein said first known and said additional known numbers of fully charging and discharging cycles for said battery are 1, 10, 20, 30, 40, 50, 60, 70, 80, 90, 100, 200, 300, 400, 500, 600, 700, 800, 900, and 1000.

18. The method of claim 16, wherein all the steps of claim 16 are repeated at a set of predetermined temperatures.

19. The method of claim 18, wherein said set of predetermined temperatures consists of −

40°

Celsius, −

30°

Celsius, −

20°

Celsius, −

10°

Celsius, 0°

Celsius, +10°

Celsius, +20°

Celsius, +30°

Celsius, +40°

Celsius, +50°

Celsius, and +60°

Celsius.

20. A method for determining the age of a lithium sulfur battery of a particular type using a look-up table of taper input charge versus age for said particular type of lithium sulfur battery, said method comprising the steps of:

a) inputting a battery type into a computer;

b) measuring a taper input charge for said battery, said taper input charge being input into said computer;

c) executing a taper input charge correlation algorithm based on inputs comprising;

i) the type of said battery inputted into said computer; and

ii) the measured taper input charge for said battery; and

d) determining the age of said lithium sulfur battery based on said taper input charge correlation algorithm.

21. The method of claim 20, wherein said inputs to said taper input charge correlation algorithm further comprise measured battery temperature.

22. A system for creating a look-up table of cell resistance versus state of charge for a lithium sulfur battery of a particular type and determining the capacity thereof, said system comprising:

a) means for charging said battery until a voltage across said battery increases to a predetermined maximum voltage;

b) means for continuing to charge said battery at said predetermined maximum voltage until an input current to said battery decreases to a predetermined minimum current;

c) means for measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at 100% state of charge for said particular type of lithium sulfur battery;

d) means for recording said cell resistance at 100% state of charge;

e) means for discharging said battery at a discharge rate to a predetermined lower cutoff voltage and means for recording a discharge time period;

f) means for integrating said discharge time period with said discharge rate and means for storing the result, said integration result being defined as the battery capacity for said particular type of lithium sulfur battery;

g) means for measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at 0% state of charge for said particular type of lithium sulfur battery;

h) means for recording said cell resistance at 0% state of charge;

i) means for charging said battery with a predetermined percentage of said battery capacity so that a present battery state of charge exceeds a previous battery state of charge;

j) means for measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at the present state of charge for said particular type of lithium sulfur battery;

k) means for recording said cell resistance at the present state of charge; and

l) means for creating said look-up table of cell resistance versus state of charge for state of charge values from 0% to 100%.

23. A system for creating a look-up table of cell resistance versus state of charge for a lithium sulfur battery of a particular type with a known capacity, said system comprising:

a) means for charging said battery until a voltage across said battery increases to a predetermined maximum voltage;

b) means for continuing to charge said battery at said predetermined maximum voltage until an input current to said battery decreases to a predetermined minimum current;

c) means for measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at 100% state of charge for said particular type of lithium sulfur battery;

d) means for recording said cell resistance at 100% state of charge;

e) means for discharging said battery by a predetermined percentage of the capacity of said battery so that a present battery state of charge is less than a previous battery state of charge;

f) means for measuring a cell resistance for said battery, said cell resistance being defined as the cell resistance at the present state of charge for said particular type of lithium sulfur battery;

g) means for recording said cell resistance at the present state of charge; and

h) means for creating said look-up table of cell resistance versus state of charge for state of charge values from 100% to 0%.

24. A system for determining the state of charge of a lithium sulfur battery of a particular type using a look-up table of cell resistance versus state of charge for said particular type of lithium sulfur battery, said system comprising:

a) means for inputting a battery type into a computer;

b) means for measuring a cell resistance for said battery, said cell resistance being input into said computer;

c) means for executing a cell resistance correlation algorithm based on inputs comprising;

i) the type of said battery inputted into said computer; and

ii) the measured cell resistance for said battery; and

d) means for determining the state of charge of said lithium sulfur battery based on said cell resistance correlation algorithm.

25. A system for creating a look-up table of taper input charge versus age for a lithium sulfur battery of a particular type, said system comprising:

a) means for subjecting said battery to a first known number of fully charging and discharging cycles;

b) means for charging said battery until a voltage across said battery increases to a predetermined maximum voltage;

c) means for taper charging said battery at said predetermined maximum voltage until an input current to said battery decreases to a predetermined minimum current and means for recording a taper charge time period;

d) means for integrating said taper charge time period with said input current during said taper charge time period and storing the result, said integration result being defined as the taper input charge for said particular type of lithium sulfur battery at the age of said particular number;

e) means for recording said taper input charge at said age of said particular number; and

f) means for creating said look-up table of taper input charge versus age for said particular type of lithium sulfur battery using said first known and additional known numbers of fully charging and discharging cycles for said battery.

26. A system for determining the age of a lithium sulfur battery of a particular type using a look-up table of taper input charge versus age for said particular type of lithium sulfur battery, said method comprising the steps of:

a) means for inputting a battery type into a computer;

b) means for measuring a taper input charge for said battery;

c) means for inputting said taper input charge into said computer;

d) means for executing a taper input charge correlation algorithm based on inputs comprising;

i) the type of said battery inputted into said computer; and

ii) the measured taper input charge for said battery; and

e) means for determining the age of said lithium sulfur battery based on said taper input charge correlation algorithm.