High throughput screening methods for lubricating oil compositions

• US 7,698,929 B2
• Filed: 11/28/2006
• Issued: 04/20/2010
• Est. Priority Date: 10/31/2003
• Status: Expired due to Fees

• Current Assignee: Chevron Oronite Company LLC (Chevron Corp.)
• Original Assignee: Chevron Oronite Company LLC (Chevron Corp.)
• Inventors: Wollenberg, Robert H., Balk, Thomas J.
• Primary Examiner(s): Williams; Hezron
• Assistant Examiner(s): SHABMAN, MARK A
• Application Number:
  US11/605,127
• Publication Number:
  US 20070068228A1
• Time in Patent Office: 1,239 Days
• Field of Search: 73/530.5, 738/648.2, 738/648.5
• US Class Current: 73/53.05
• CPC Class Codes: B01J 2219/00702 Processes involving means for analysing and characterising the products
• CPC Class Codes: B01J 2219/00756 Compositions, e.g. coatings, crystals, formulations
• CPC Class Codes: G01N 3/56 Investigating resistance to wear or abrasion
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30
• CPC Class Codes: G01N 33/30 for lubricating properties
• CPC Class Codes: G01N 35/028 having reaction cells in the form of microtitration plates

Abstract

A method for determining storage stability for a plurality of fluid lubricant samples of different lubricating oil compositions is provided. Each sample includes a combination of one or more base oils and one or more lubricating oil additives. The methods can advantageously be optimized using combinatorial chemistry, in which a database of combinations of lubricating oil additives or lubricating oil compositions containing such additives is generated. As market conditions vary and/or product requirements or customer specifications change, conditions suitable for forming desired products can be identified with little or no downtime.

Claims

1. A high throughput system for screening a plurality of lubricating oil compositions, comprising:

a) a supply of a major amount of at least one base oil of lubricating viscosity;

b) a supply of a minor amount of at least one lubricating oil additive;

c) a plurality of test receptacles;

d) means for conducting molecular modeling of the at least one base oil of lubricating viscosity and the at least one lubricating oil additive to provide leading candidates of the at least one base oil of lubricating viscosity and at least one lubricating oil additive for combination to formulate a leading candidate lubricating oil composition for testing;

e) means for combining selected quantities of the major amount of the at least one leading base oil of lubricating viscosity candidate with selected quantities of the minor amount of the at least one leading lubricating oil additive candidate in the plurality of test receptacles to form a plurality of leading candidate lubricating oil composition samples in the plurality of test receptacles;

f) a moving unit configured to individually position each of the plurality of leading candidate lubricating oil composition samples in a testing station to test each of the leading candidate lubricating oil composition samples for wear stability and measure the wear stability of each test; and

,

g) a controller coupled to the testing station and configured to receive and store the measurements of the wear stability tests of each of the plurality of leading candidate lubricating oil composition samples.

2. The system of claim 1, wherein the controller is provided with software for automatically receiving and storing the measurements of wear stability of each of the plurality of lubricating oil compositions.

3. The system of claim 2, wherein the controller is provided with software for assembling the stored measurements of wear stability of each of the plurality of leading candidate lubricating oil composition samples processed on the testing station in an electronic library.

4. The system of claim 3, wherein the testing station includes at least one apparatus configured to conduct at least one wear stability test for measuring the wear stability of each of the plurality of leading candidate lubricating oil composition samples.

5. The system of claim 4, wherein the at least one wear stability test is selected from the group consisting of an extreme pressure test, hydrodynamic test, corrosive test and a combination thereof, the at least one apparatus being coupled to the controller having software, which executes thereon for selectively changing a plurality of conditions for the at least one wear stability test, the plurality of conditions being selected from the group consisting of duration of the at least one wear stability test, load generated during the at least one wear stability test, acid amount delivered during the at least one wear stability test and a combination thereof.

6. The system of claim 5, further comprising at least one additional apparatus coupled to the controller and configured to conduct each of the extreme pressure, hydrodynamic and corrosive tests of the plurality of leading candidate lubricating oil composition samples.

7. The system of claim 6, wherein the at least one additional apparatus operates simultaneously with the at least one apparatus, the controller being provided with software operating thereon for controlling each of the simultaneously operating apparatuses so that each one of the apparatuses conducts a respective test selected from the group consisting of an extreme pressure, hydrodynamic and corrosive wear stability test.

8. The system of claim 7, wherein the simultaneously operating apparatuses each conduct a respective one of the extreme pressure, hydrodynamic and corrosive tests different from the test conducted on the other one of simultaneously operating apparatuses.

9. The system of claim 8, wherein one of the simultaneously operating apparatuses is configured to conduct the corrosive test simultaneously with one of the extreme pressure and hydrodynamic tests.

10. The system of claim 5, wherein the controller has software operating thereon for analyzing a rate of change of a result of each of the extreme pressure, hydrodynamic and corrosive tests of a respective one of the plurality of leading candidate lubricating oil composition samples to select multiple groups thereof, each of which includes the lubricating oil compositions better suited for a particular one of the extreme pressure, hydrodynamic and corrosive tests.

11. The system of claim 10, wherein the controller further has software operating thereon for optimizing each of the selected multiple groups by balancing a cost of each of leading candidate lubricating oil composition samples included in a respective one of the selected multiple groups and a respective wear-stability result of the each of the leading candidate lubricating oil composition samples of the selected group.

12. The system of claim 1, wherein the plurality of leading candidate lubricating oil composition samples each is contained in a respective test receptacle.

13. The system of claim 12, wherein the moving unit includes a robotic arm configured to grasp and deliver each of the test receptacles to the testing station.

14. The system of claim 12, wherein each test receptacle has a bar code affixed to an outer surface thereof.

15. The system of claim 1, wherein the leading base oil of lubricating viscosity candidate is a natural oil.

16. The system of claim 1, wherein the at least one leading lubricating oil additive candidate is selected from the group consisting of antioxidants, anti-wear agents, detergents, rust inhibitors, dehazing agents, demulsifying agents, metal deactivating agents, friction modifiers, pour point depressants, antifoaming agents, co-solvents, package compatibilisers, corrosion-inhibitors, ashless dispersants, dyes, extreme pressure agents and mixtures thereof.

17. The system of claim 1, wherein the at least one leading lubricating oil additive candidate is an anti-wear agent.

18. The system of claim 1, wherein the at least one wear stability test is selected from the group consisting of an extreme pressure test, hydrodynamic test, corrosive test and a combination thereof.

19. The system of claim 1, wherein the leading base oil of lubricating viscosity candidate is a synthetic oil.

20. A high throughput system for screening a plurality of lubricating oil compositions, under program control, comprising:

(a) a plurality of test receptacles, each containing a different lubricating oil composition each comprising (i) a major amount of at least one base oil of lubricating viscosity and (ii) a minor amount of at least one lubricating oil additive;

(b) a moving unit configured to individually position each of the plurality of lubricating oil compositions in a testing station to test each of the lubricating oil compositions for wear stability and measure the wear stability of each test, wherein the wear stability test is selected from the group consisting of an extreme pressure wear test, hydrodynamic wear test, corrosive wear test and a combination thereof; and

,

(c) a controller coupled to the testing station and configured to receive and store the measurements of each of the extreme pressure, hydrodynamic and corrosive wear tests of each of the plurality of lubricating oil compositions, thereby assembling a library of the outputted results associated with each of the plurality of lubricating oil compositions, wherein each one of the wear tests is selected to be indicative of performance of a selected part of or an entire running internal combustion engine; and

comparing the outputted results of at least one of the extreme pressure, hydrodynamic and corrosive wear tests of the plurality of lubricating oil compositions to a stored reference value selected from desired operating conditions or statutory requirements in accordance with the program control, wherein the controller has software operating thereon for analyzing a rate of change of a result of each of the extreme pressure, hydrodynamic and corrosive tests of a respective one of the plurality of lubricating oil compositions to select multiple groups thereof, each of which includes the lubricating oil compositions better suited for a particular one of the extreme pressure, hydrodynamic and corrosive tests.

21. The system of claim 20, wherein the controller is provided with software for automatically receiving and storing the measurements of each of the extreme pressure, hydrodynamic and corrosive wear tests of each of the plurality of lubricating oil compositions.

22. The system of claim 21, wherein the controller is provided with software for assembling the stored measurements of each of the extreme pressure, hydrodynamic and corrosive wear tests of each of the plurality of lubricating oil compositions processed on the testing station in an electronic library.

23. The system of claim 22, wherein the testing station includes at least one apparatus configured to conduct at least one of the extreme pressure, hydrodynamic and corrosive wear tests for measuring the wear stability of each of the plurality of lubricating oil compositions.

24. The system of claim 21, wherein the at least one apparatus being coupled to the controller having software, which executes thereon for selectively changing a plurality of conditions for the at least one of the extreme pressure, hydrodynamic and corrosive wear tests, the plurality of conditions being selected from the group consisting of duration of the at least one wear stability test, load generated during the at least one wear stability test, acid amount delivered during the at least one wear stability test and a combination thereof.

25. The system of claim 24, further comprising at least one additional apparatus coupled to the controller and configured to conduct each of the extreme pressure, hydrodynamic and corrosive tests of the plurality of lubricating oil compositions.

26. The system of claim 25, wherein the at least one additional apparatus operates simultaneously with the at least one apparatus, the controller being provided with software operating thereon for controlling each of the simultaneously operating apparatuses so that each one of the apparatuses conducts a respective one of the extreme pressure, hydrodynamic and corrosive wear tests.

27. The system of claim 26, wherein the simultaneously operating apparatuses each conduct a respective one of the extreme pressure, hydrodynamic and corrosive tests different from the test conducted on the other one of simultaneously operating apparatuses.

28. The system of claim 27, wherein one of the simultaneously operating apparatuses is configured to conduct the corrosive test simultaneously with one of the extreme pressure and hydrodynamic tests.

29. The system of claim 20, wherein the base oil of lubricating viscosity is a natural or synthetic oil.

30. The system of claim 20, wherein the at least one lubricating oil additive is selected from the group consisting of antioxidants, anti-wear agents, detergents, rust inhibitors, dehazing agents, demulsifying agents, metal deactivating agents, friction modifiers, pour point depressants, antifoaming agents, co-solvents, package compatibilisers, corrosion-inhibitors, ashless dispersants, dyes, extreme pressure agents and mixtures thereof.

31. The system of claim 20, wherein the at least one lubricating oil additive is an anti-wear agent.

32. A high throughput system for screening a plurality of lubricating oil compositions, under program control, comprising:

a) a supply of a major amount of at least one base oil of lubricating viscosity;

b) a supply of a minor amount of at least one lubricating oil additive;

c) a plurality of test receptacles;

d) means for conducting molecular modeling of the at least one base oil of lubricating viscosity and the at least one lubricating oil additive to provide leading candidates of the at least one base oil of lubricating viscosity and at least one lubricating oil additive for combination to formulate a leading candidate lubricating oil composition for testing;

e) means for combining selected quantities of the major amount of the at least one leading base oil of lubricating viscosity candidate with selected quantities of the minor amount of the at least one leading lubricating oil additive candidate in the plurality of test receptacles to form a plurality of leading candidate lubricating oil composition samples in the plurality of test receptacles;

f) moving unit configured to individually position each of the plurality of lubricating oil compositions in a testing station to test of the leading candidate lubricating oil composition samples for wear stability and measure the wear stability of each test, wherein the wear stability test is selected from the group consisting of an extreme pressure wear test, hydrodynamic wear test, corrosive wear test and a combination thereof; and

,

g) a controller coupled to the testing station and configured to receive and store the measurements of each of the extreme pressure, hydrodynamic and corrosive wear tests of each of the plurality of lubricating oil compositions, thereby assembling a library of the outputted results associated with each of the plurality of leading candidate lubricating oil composition samples, wherein each one of the wear tests is selected to be indicative of performance of a selected part of or an entire running internal combustion engine; and

further configured to analyze a change of the outputted results of each of the extreme pressure, hydrodynamic and corrosive wear stability tests stored in the library upon changing a plurality of conditions in accordance with the program control.

33. The system of claim 32, wherein the controller is provided with software for automatically receiving and storing the measurements of each of the extreme pressure, hydrodynamic and corrosive wear tests of each of the plurality of leading candidate lubricating oil composition samples.

34. The system of claim 33, wherein the controller is provided with software for assembling the stored measurements of each of the extreme pressure, hydrodynamic and corrosive wear tests of each of the plurality of leading candidate lubricating oil composition samples processed on the testing station in an electronic library.

35. The system of claim 32, wherein the testing station includes at least one apparatus configured to conduct at least one wear stability test for measuring the wear stability of each of the plurality of leading candidate lubricating oil composition samples.

36. The system of claim 32, wherein the controller is provided with software for selectively changing the plurality of conditions for the at least one of the wear test, the plurality of conditions being selected from the group consisting of duration of the at least one wear stability test, load generated during the at least one wear stability test, acid amount delivered during the at least one wear stability test and a combination thereof.

37. The system of claim 32, wherein the leading base oil of lubricating viscosity candidate is a natural or synthetic oil.

38. The system of claim 32, wherein the at least one leading lubricating oil additive candidate is selected from the group consisting of antioxidants, anti-wear agents, detergents, rust inhibitors, dehazing agents, demulsifying agents, metal deactivating agents, friction modifiers, pour point depressants, antifoaming agents, co-solvents, package compatibilisers, corrosion-inhibitors, ashless dispersants, dyes, extreme pressure agents and mixtures thereof.

39. The system of claim 32, wherein the at least one leading lubricating oil additive candidate is an anti-wear agent.