Method of highlighting with a reversible highlighting mixture, highlighting kit, and highlighted complex

• US 7,704,308 B2
• Filed: 12/21/2004
• Issued: 04/27/2010
• Est. Priority Date: 10/07/2003
• Status: Expired due to Fees

• Current Assignee: Sanford LP (Newell Brands Inc.)
• Original Assignee: Sanford LP (Newell Brands Inc.)
• Inventors: Sum, Vincent Wing, Davies-Smith, Leighton
• Primary Examiner(s): Lorengo; Jerry
• Assistant Examiner(s): FAISON, VERONICA F
• Application Number:
  US11/018,750
• Publication Number:
  US 20050158471A1
• Time in Patent Office: 1,953 Days
• Field of Search: 106/31.32, 106/31.28
• US Class Current: 106/31.32
• CPC Class Codes: C09D 11/037 characterised by the pigment
• CPC Class Codes: C09D 11/16 Writing inks
• CPC Class Codes: C09D 11/17 characterised by colouring agents
• CPC Class Codes: C09D 11/18 specially adapted for ball-point writing instruments
• CPC Class Codes: C09D 11/32 characterised by colouring agents
• CPC Class Codes: C09D 11/322 Pigment inks
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks

Abstract

A highlightable mixture, such as an ink, including a colored pigment, an eradicable colorant, and a non-eradicable colorant; a kit including the highlightable mixture and an eradicator fluid; an colorant complex including a colorless or substantially colorless eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, and methine dyes, and a colored pigment; and methods of applying an eradicator to at least a portion of a marking made with a highlightable mixture, are described herein.

Claims

1. A method of reversibly highlighting, comprising the steps of applying a mixture comprising water, a colored pigment, and an eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and combinations thereof to a substrate to make a mark, applying an eradicator fluid to said mark, and applying an oxidizing agent to said mark.

2. The method of claim 1, wherein said eradicator fluid comprises a reducing agent.

3. The method of claim 2, wherein said reducing agent is selected from the group consisting of a sulfur-containing reducing agent, a basic reducing agent, and combinations thereof.

4. The method of claim 3, wherein said sulfur-containing reducing agent is selected from the group consisting of a sulfite reducing agent, a bisulfite reducing agent, a metasulfite reducing agent, a thiosulfite reducing agent, and combinations thereof.

5. The method of claim 1, wherein said oxidizing agent comprises an acid.

6. The method of claim 5, wherein said acid is selected from the group consisting of mineral acids, organic acids, and combinations thereof.

7. The method of claim 6, wherein said mineral acids are selected from the group consisting of hydrochloric acid, hydrobromic acid, hydroiodic acid, hydrofluoric acid, nitric acid, sulfuric acid, carbonic acid, chromic acid, phosphoric acid, phosphorous acid, phosphonic acid, and combinations thereof.

8. The method of claim 6, wherein said organic acids are selected from the group consisting of benzoic acid, lactic acid, acetic acid, propanoic acid, acetoacetic acid, crotonic acid, formic acid, glycolic acid, glyoxylic acid, pyruvic acid, trans-aconitic acid, fumaric acid, maleic acid, malic acid, tartaric acid, acetylenedicarboxylic acid, tetrahydrophthalic acid, mesaconic acid, phthalic acid, isophthalic acid, terephthalic acid, itaconic acid, trans-ethyleneoxidedicarboxylic acid, succinic acid, adipic acid, pimellic acid, suberic acid, azelic acid, substituted phosphoric acid, substituted phosphorous, citric acid, hemimellitic acid, trimellitic, trimesic acid, 2carboxyethyliminodiacetic acid, nitrilotriacetic acid, phosphonic acid, substituted phosphonic acid, mellophanic acid, prehnitic acid, pyromellitic acid, 2-phosphonoethyliminodiacetic acid, diethylenetetraacetic acid, and combinations thereof.

9. The method of claim 1, wherein said oxidizing agent is a strong nucleophile.

10. The method of claim 9, wherein said strong nucleophile is an alkoxide.

11. The method of claim 1, wherein said mixture is black.

12. The method of claim 1, wherein said substrate is paper.

13. The method of claim 12, wherein said paper is non-porous paper.

14. The method of claim 1, wherein said eradicable dye is a triarylmethane derivative.

15. The method of claim 1, wherein said eradicable dye is present in said mixture in an amount at least about 0.01% and up to about 40% by weight of the total weight of the mixture.

16. The method of claim 15, wherein said eradicable dye is present in said mixture in an amount at least about 0.1% and up to about 10% by weight of the total weight of the mixture.

17. The method of claim 1, wherein said colored pigment is present in said mixture in an amount at least about 0.01% and up to about 50% by weight of the total weight of the mixture.

18. The method of claim 17, wherein said colored pigment is present in said mixture in an amount at least about 0.1% and up to about 20% by weight of the total weight of the mixture.

19. The method of claim 1, wherein said mixture further comprises a non-eradicable dye.

20. The method of claim 19, wherein said non-eradicable dye is selected from the group consisting of non-eradicable blue dyes, non-eradicable red dyes, non-eradicable violet dyes, non-eradicable yellow dyes, non-eradicable orange dyes, and combinations of the foregoing.

21. The method of claim 1, wherein said applying said mixture comprises dispensing said mixture from a writing instrument.

22. The method of claim 1, wherein said applying said mixture comprises dispensing said mixture from a printer cartridge.

23. The method of claim 22, said applying said mixture comprises dispensing said mixture from a continuous ink-jet printhead.

24. The method of claim 22, said applying said mixture comprises dispensing said mixture from a drop-on-demand ink-jet printhead.

25. The method of claim 24, wherein said drop-on-demand ink-jet printhead comprises a printhead selected from the group consisting of a piezoelectric ink-jet printhead, and a thermal ink-jet printhead.

26. A kit, comprising a first solution comprising a mixture comprising water, a colored pigment, and an eradicable dye selected from the group consisting of diarylmethane derivatives, triarylmethane derivatives, methine dyes, and combinations thereof;

a second solution comprising an eradicator fluid; and

a third solution comprising an oxidizing agent.

27. The kit of claim 26, wherein said eradicator comprises a reducing agent.

28. The kit of claim 27, wherein said reducing agent is selected from the group consisting of a sulfur-containing reducing agent, a basic reducing agent, and combinations thereof.

29. The kit of claim 28, wherein said sulfur-containing reducing agent is selected from the group consisting of a sulfite reducing agent, a bisulfite reducing agent, a metasulfite reducing agent, a thiosulfite reducing agent, and combinations thereof.

30. The kit of claim 26, wherein said oxidizing agent comprises an acid.

31. The kit of claim 30, wherein said acid is selected from the group consisting of mineral acids, organic acids, and combinations thereof.

32. The kit of claim 31, wherein said mineral acids are selected from the group consisting of hydrochloric acid, hydrobromic acid, hydroiodic acid, hydrofluoric acid, nitric acid, sulfuric acid, carbonic acid, chromic acid, phosphoric acid, phosphorous acid, phosphonic acid, and combinations thereof.

33. The kit of claim 31, wherein said organic acids are selected from the group consisting of benzoic acid, lactic acid, acetic acid, propanoic acid, acetoacetic acid, crotonic acid, formic acid, glycolic acid, glyoxylic acid, pyruvic acid, trans-aconitic acid, fumaric acid, maleic acid, malic acid, tartaric acid, acetylenedicarboxylic acid, tetrahydrophthalic acid, mesaconic acid, phthalic acid, isophthalic acid, terephthalic acid, itaconic acid, trans-ethyleneoxidedicarboxylic acid, succinic acid, adipic acid, pimellic acid, suberic acid, azelic acid, substituted phosphoric acid, substituted phosphorous, citric acid, hemimellitic acid, trimellitic, trimesic acid, 2-carboxyethyliminodiacetic acid, nitrilotriacetic acid, phosphonic acid, substituted phosphonic acid, mellophanic acid, prehnitic acid, pyromellitic acid, 2-phosphonoethyliminodiacetic acid, diethylenetetraacetic acid, and combinations thereof.

34. The kit of claim 26, wherein said mixture is black.

35. The kit of claim 26, wherein said eradicable dye is a triarylmethane derivative.

36. The kit of claim 26, wherein said eradicable dye is present in said mixture in an amount at least about 0.01% and up to about 40% by weight of the total weight of the mixture.

37. The kit of claim 36, wherein said eradicable dye is present in said mixture in an amount at least about 0.1% and up to about 10% by weight of the total weight of the mixture.

38. The kit of claim 26, wherein said colored pigment is present in said mixture in an amount at least about 0.01% and up to about 50% by weight of the total weight of the mixture.

39. The kit of claim 38, wherein said colored pigment is present in said mixture in an amount at least about 0.1% and up to about 20% by weight of the total weight of the mixture.

40. The kit of claim 26, wherein said mixture further comprises a non-eradicable dye.

41. The kit of claim 40, wherein said non-eradicable dye is selected from the group consisting of non-eradicable blue dyes, non-eradicable red dyes, non-eradicable violet dyes, non-eradicable yellow dyes, non-eradicable orange dyes, and combinations of the foregoing.

42. The kit of claim 26, wherein said mixture further comprises a binder resin.

43. The kit of claim 26, wherein said mixture further comprises an organic solvent.

44. The kit of claim 26, wherein said mixture further comprises an additive selected from the group consisting of pH buffers, surfactants, biocides, anti-corrosive agents, sequestering agents, anti-crusting agents, rehology control agents, binder resins, film-forming agents, and combinations thereof.

45. The kit of claim 26, wherein said mixture is disposed in a writing instrument.

46. The kit of claim 26, wherein said mixture is disposed in a printer cartridge.

47. The kit of claim 46, wherein said mixture is disposed in a continuous ink-jet printhead.

48. The kit of claim 46, wherein said mixture is disposed in a drop-on-demand ink-jet printhead.

49. The kit of claim 48, wherein said drop-on-demand ink-jet printhead comprises a printhead selected from the group consisting of a piezoelectric ink-jet printhead, and a thermal ink-jet printhead.