Method and apparatus for isolation of ionic species from a liquid

• US 7,704,361 B2
• Filed: 12/06/2001
• Issued: 04/27/2010
• Est. Priority Date: 12/12/2000
• Status: Expired due to Fees

• Current Assignee: Carlsberg A/S
• Original Assignee: Jurag Separation A/S
• Inventors: Jonsson, Gunnar, Rype, Jens-Ulrik, Garde, Arvid
• Primary Examiner(s): Phasge; Arun S
• Application Number:
  US10/450,558
• Publication Number:
  US 20040079704A1
• Time in Patent Office: 3,064 Days
• Field of Search: 204/522, 204/537, 204/631, 204/633
• US Class Current: 204/522
• CPC Class Codes: B01D 61/445 with bipolar membranes; Water splitting

Abstract

The present invention relates to a method for isolation of ionic species from a liquid and an apparatus for isolation of ionic species from a liquid. Moreover the invention relates to an electro enhanced dialysis cell and the use of the cell in the method and the apparatus.

Claims

1. An ionic transfer apparatus comprising a plurality of chambers including at least

a) an electrode chamber at each end of the apparatus and bounded by an end membrane, each electrode chamber containing an electrode, each electrode having opposite polarity from the electrode in the electrode chamber at the opposite end of the apparatus, the end membranes are selected from the group consisting of cation exchange membranes, anion exchange membranes, and neutral membranes;

b) a first and a second ionic transfer chamber, each of the ionic transfer chambers being adjacent to one of the end membranes and having a first and a second ionic membrane spaced apart from said end membrane, each of the first and second ionic membranes having a different ionic property compared to each end membrane;

c) either no additional ionic membrane or, optionally, an even-number of supplemental ionic membranes disposed between said first and second ionic membranes and spaced apart from said first and second ionic membranes and from each other to form at least one additional ionic transfer chamber between said first and second ionic transfer chambers, the first and second ionic membranes, and supplemental ionic membranes, if present, are either all cation exchange membranes or all anion exchange membranes; and

d) means for reversing the polarities of said electrodes during operation of said apparatus;

e) a first liquid from which ions are to be transferred contained in the at least one additional ionic transfer chamber, a second liquid into which ions are to be transferred contained in the first and second ionic transfer chambers, wherein when a plurality of additional ionic transfer chambers are present between the first and second ionic transfer chambers, the additional ionic chambers alternately contain the first liquid and the second liquid such that no two adjacent ionic transfer chambers contain the same liquid;

f) means for circulating the second liquid from the first and second ionic transfer chambers and additional ionic chambers, if present, into a bipolar electrodialysis cell; and

g) a bipolar electrodialysis cell for transferring ions from the second liquid into a third liquid.

2. The apparatus according to claim 1 further comprising means for separating undesired ions from the third liquid.

3. The apparatus according to claim 2, wherein the means for separating undesired ions from the third liquid is an electrodialysis cell.

4. The apparatus according to claim 3 in which said electrodialysis cell is placed downstream of said bipolar electrodialysis cell.

5. The apparatus according to claim 1 further comprising means for evaporating or crystallizing or chromatographically treating the third liquid.

6. An ionic transfer apparatus comprising a plurality of chambers including at least:

a) an electrode chamber at each end of the apparatus and bounded by an end membrane, each electrode chamber containing an electrode, each electrode having opposite polarity from the electrode in the electrode chamber at the opposite end of the apparatus, the end membranes are members selected from the group consisting of cation exchange membranes, anion exchange membranes, and neutral membranes;

b) a first and a second ionic transfer chamber, each of the ionic transfer chambers being adjacent to one of the end membranes and having a first and a second ionic membrane spaced apart from said end membrane;

c) either no additional ionic membrane or, optionally, an even-number of supplemental ionic membranes disposed between said first and second ionic membranes and spaced apart from said first and second ionic membranes and from each other to form at least one additional ionic transfer chamber between said first and second ionic transfer chambers, the first and second ionic membranes, and supplemental ionic membranes, if present, are either all cation exchange membranes or all anion exchange membranes;

d) means for reversing the polarities of said electrodes during operation of said apparatus;

e) a first liquid from which ions are to be transferred contained in the at least one additional ionic transfer chamber, a second liquid into which ions are to be transferred contained in the first and second ionic transfer chambers, wherein when a plurality of additional ionic transfer chambers are present between the first and second ionic transfer chambers, the additional ionic chambers alternately contain the first liquid and the second liquid such that no two adjacent ionic transfer chambers contain the same liquid;

f) means for circulating the second liquid from the first and second ionic transfer chambers and additional ionic chambers, if present, into a bipolar electrodialysis cell; and

g) a bipolar electrodialysis cell for transferring ions from the second liquid into a third liquid.

7. A method for transferring ions comprising the steps of:

a) passing a first liquid from which ions are to be transferred through at least a first ionic transfer chamber formed between at least two ionic membranes spaced apart from each other, which at least two ionic membranes are both cation exchange membranes or both anion exchange membranes;

b) passing a second liquid into which ions are to be transferred through at least a second ionic transfer chamber and a third ionic transfer chamber, each of said second and third ionic transfer chambers being adjacent to an ionic membrane of the first ionic transfer chamber, and having spaced apart from said ionic transfer membrane an end membrane, which end membranes are members selected from the group consisting of cation exchange membranes, anion exchange membranes and neutral membranes;

c) applying an electric field across the end membranes and the ionic transfer membranes by means of two electrodes, each electrode contained in an electrode chamber bounded by an end membrane and having opposite polarity from the electrode contained in the other electrode chamber;

d) reversing the direction of the electric field across said end membranes and said ionic transfer membranes by reversing the polarity of said electrodes;

e) passing the second liquid to a bipolar electrodialysis cell; and

f) transferring ions from the second liquid into a third liquid in the bipolar electrodialysis cell.

8. An apparatus for separating ionic species from liquids containing particles of organic material and multivalent inorganic metal ions by transferring ionic species from a first liquid to a second liquid comprising:

at least two ion exchange members selected from the group consisting of cation exchange members and anion exchange members, the two ion exchange members defining there between a first chamber for the first liquid, the first chamber including an inlet for the first liquid at one end of the chamber and an exit for the first liquid at another end of the first chamber;

at least two further chambers for the second liquid, each further chamber being located adjacent to the at least one first chamber;

a set of end membranes;

means for applying an electric field over the membranes and means for changing the direction of the electric field at predetermined substantially regular intervals being between about 5 seconds and 6000 seconds;

means for treating the second liquid in a biopolar electrodialysis cell to transfer the ionic species from the second liquid into a third liquid.

9. The apparatus according to claim 8, comprising means for separating the ionic species from the third liquid.

10. The apparatus according to claim 9, wherein the means for separating the ionic species from the third liquid comprises an electrodialysis cell adapted to remove undesired ions from the third liquid.

11. The apparatus according to claim 10, wherein the electrodialysis cell is placed downstream of the biopolar electrodialysis cell.

12. The apparatus according to claim 8, further comprising means for performing at least one treatment on the third liquid, the at least one treatment being selected from the group consisting of:

evaporation, crystallization, and a chromatographical treatment.

13. A method of separating ionic species from liquids containing particles of organic material and multivalent inorganic metal ions by transfering ionic species from a first liquid to a second liquid comprising the steps of:

passing the first liquid through at least one first chamber defined by a pair of either cation exchange membranes or anion exchange membranes by entering the first liquid at one end of the first chamber and removing the first liquid at an opposite end of the first chamber;

passing the second liquid which has an ionic component in a higher concentration than a concentration of the same component in the first liquid, through at least two further chambers, each further chamber being located adjacent to at least one first chamber;

applying an electric field over the membranes by means of at least two electrodes and changing the direction of the electric field during transfer of ionic species in predetermined substantially regular intervals that are within a range from 5 seconds to 6000 seconds;

wherein the second liquid is treated in a biopolar electrodialysis cell to transfer the ionic species from the second liquid into a third liquid.

14. The method of claim 13, wherein the ionic species are separated from the third liquid.

15. The method of claim 13, wherein the third liquid is stored in a third tank after being discharged from the bipolar electrodialysis.

16. The method of claim 15, wherein at least part of the third liquid is recycled from the third liquid to the bipolar electrodialysis cell.

17. The method of claim 13, further comprising the step of treating the third liquid in an electrodialysis cell to remove undesired ions.

18. The method of claim 13, further comprising the step of performing at least one treatment on the third liquid, the at least one treatment being selected from the group consisting of:

evaporation, crystallization, and a chromatographical treatment.

19. A method of separating ionic species from liquids containing particles of organic material and multivalent inorganic metal ions by transfering ionic species from a first liquid to a second liquid comprising the steps of:

passing the first liquid through at least one first chamber defined by a pair of either cation exchange membranes or anion exchange membranes by entering the first liquid at one end of the first chamber and removing the first liquid at an opposite end of the first chamber, where the pair of either cation exchange membranes or anion exchange membranes have the same charge and valence selectivity with respect to each other;

passing the second liquid which has an ionic component in a higher concentration than a concentration of the same component in the first liquid, through at least two further chambers, each further chamber being located adjacent to at least one first chamber;

applying an electric field over the membranes by means of at least two electrodes and changing the direction of the electric field during transfer of ionic species in predetermined substantially regular intervals that are within a range from 5 seconds to 6000 seconds;

wherein the liquid containing particles of organic material and multivalent inorganic metal ions is a fermentation liquid.

20. The method of claim 19, wherein the ionic component of the second liquid is either H⁺ or OH⁻

.

21. The method of claim 19, wherein the liquids are passed through chambers defined by membranes where the chambers are alternatingly adapted to receive either the first liquid or the second liquid.

22. The method of claim 19, further comprising the step of using an end membrane disposed between the electrode and another membrane.

23. The method of claim 22, further comprising using end membranes selected from the group consisting of neutral membranes, cation membranes and anion membranes.

24. The method of claim 19, further comprising the step of applying an electrode rinsed to the electrode chamber.

25. The method of claim 24, wherein the electrode rinse is a separate liquid.

26. The method of claim 25, wherein the separate liquid is a solution of electrolytes.

27. The method of claim 26, wherein the electrolytes are selected between K₂SO₄ and Na₂SO₄.

28. The method of claim 19, further comprising the step of providing a turbulent flow in at least the first chamber.

29. The method of claim 19, wherein the intervals are within a range from 8 second to 1000 seconds.

30. The method of claim 29, wherein the intervals are within a range from 10 seconds to 360 seconds.

31. The method of claim 19, wherein the ionic species comprises anions.

32. The method of claim 31, wherein the anions are selected from a group consisting of anions from inorganic acids, organic acids, enzymes, peptides, hormones, antibiotics and amino acids.

33. The method of claim 19, wherein the ionic species have a molar weight up to 1000 g/mol.

34. The method of claim 19, wherein the liquid containing particles of organic material and multivalent inorganic metal ions is a stream from food processing.

35. The method of claim 19, further comprising the step of storing the first liquid in a first tank before being passed through the first chamber.

36. The method of claim 35, wherein at least a part of the first liquid is recycled to the first tank.

37. The method of claim 19, further comprising the step of storing the second liquid in a second tank before being passed through the further chambers.

38. The method of claim 37, wherein at least a part of the second liquid is recycled to the flow chambers after being treated in the bipolar electrodialysis cell.