Hydrogen storage tank and method of using

• US 7,721,601 B2
• Filed: 06/18/2007
• Issued: 05/25/2010
• Est. Priority Date: 06/16/2006
• Status: Active Grant

• Current Assignee: Indiana University Research & Technology Corporation (Indiana University)
• Original Assignee: Packer Engineering, Inc. (The Packer Group, Inc.)
• Inventors: Schubert, Peter J., Yen, David W., Zhang, JingYing
• Primary Examiner(s): Williams; Hezron
• Assistant Examiner(s): KOLB, NATHANIEL J
• Application Number:
  US11/764,341
• Publication Number:
  US 20100024542A1
• Time in Patent Office: 1,072 Days
• Field of Search: 732/92, 732/91, 732/99, 732/95
• US Class Current: 73/292
• CPC Class Codes: F17C 11/005 for hydrogen
• CPC Class Codes: G01F 23/18 Indicating, recording or alarm devices actuated electrically
• CPC Class Codes: G01F 23/804 containing circuits handling parameters other than liquid level
• CPC Class Codes: Y02E 60/32 Hydrogen storage
• CPC Class Codes: Y02P 90/45 Hydrogen technologies in production processes

Abstract

A hydrogen storage tank for containing solid-state hydrogen storage media, and method for determining the hydrogen fill level in the tank. The tank has at least one compartment for storing the storage media, passages for transporting hydrogen gas to and from the compartment, and a heat distribution system for establishing a substantially uniform temperature in the storage media. A look-up table is generated for the tank that relates hydrogen pressure changes in the tank versus hydrogen fill levels in the tank as a function of temperature. The tank is filled to full capacity by adsorbing hydrogen on the storage media. Thereafter, hydrogen is released from the storage media for a time period during which there is a substantially constant demand on the tank, the change in pressure of the released hydrogen gas is measured, and the look-up table is applied to determine the hydrogen fill level in the tank.

Claims

1. A method for determining the hydrogen fill level in a hydrogen storage tank containing a solid-state hydrogen storage media, the method comprising:

equipping the hydrogen storage tank with at least one compartment for storing the storage media, passages for transporting hydrogen gas to the hydrogen storage tank and into the compartment and for transporting hydrogen gas out of the compartment, and means for distributing heat within the compartment so as to establish a substantially uniform temperature in the storage media within the compartment;

generating a look-up table derived from a series of plots relating changes in pressure of the hydrogen gas in the hydrogen storage tank versus fill levels of hydrogen in the hydrogen storage tank as a function of temperature;

filling the hydrogen storage tank to full capacity by flowing hydrogen gas through the passages and into the compartment so as to adsorb hydrogen on the storage media;

causing hydrogen release from the storage media for a time period during which there is a substantially constant demand on the hydrogen storage tank;

measuring a change in pressure of the hydrogen gas released from the storage media during the time period; and

then

applying the look-up table to determine the hydrogen fill level in the hydrogen storage tank.

2. The method according to claim 1, wherein the look-up table is generated by:

filling the hydrogen storage tank with hydrogen gas at predetermined fill levels by adsorbing the hydrogen gas on the storage media;

heating the storage media to a plurality of temperatures and, at each of the temperatures and each of the predetermined fill levels, sensing the pressure of hydrogen gas desorbed from the storage media; and

turning on a light source and sensing a change in the pressure of the hydrogen gas desorbed from storage media during a time period at each of the temperatures and each of the predetermined fill levels, the light source generating light at wavelengths to which the storage media is at least partially transparent and at which bonds between hydrogen and the storage media will absorb at least a portion of the light so as to promote the release of hydrogen gas from the storage media.

3. The method according to claim 2, wherein the light generated by the light source includes infrared wavelengths.

4. The method according to claim 1, further comprising:

after filling the hydrogen storage tank, heating the storage media to a temperature and sensing the pressure of hydrogen gas released from the compartment; and

turning on a light source for a time period and sensing a change in the pressure of hydrogen gas released from storage media, the light source generating light at wavelengths to which the storage media is at least partially transparent and at which bonds between hydrogen and the storage media will absorb at least a portion of the light so as to promote the release of hydrogen gas from the storage media.

5. The method according to claim 4, wherein the light generated by the light source includes infrared wavelengths.

6. The method according to claim 1, wherein hydrogen is released from the storage media during the time period when there is a substantially constant demand on the hydrogen storage tank by turning on a light source that generates light at wavelengths to which the storage media is at least partially transparent and at which bonds between hydrogen and the storage media will absorb at least a portion of the light so as to promote the release of hydrogen gas from the storage media.

7. The method according to claim 6, wherein the light generated by the light source includes infrared wavelengths.

8. The method according to claim 1, further comprising generating an electric field within the compartment.

9. The method according to claim 1, wherein heat is distributed in the compartment by flowing a coolant through at least one heat exchanger tube that passes through the compartment.

10. The method according to claim 9, wherein the at least one tube removes heat from the compartment during hydrogen adsorption.

11. The method according to claim 9, wherein the at least one tube imports waste heat from a fuel cell during hydrogen desorption.

12. The method according to claim 1, wherein the compartment is one of a plurality of compartments within the hydrogen storage tank.

13. The method according to claim 12, wherein the compartments are defined by boxes individually placed and stacked in parallel columns within the hydrogen storage tank.

14. The method according to claim 1, wherein the storage media is nano-porous silicon.

15. A method for determining the hydrogen fill level in a hydrogen storage tank containing a solid-state hydrogen storage media, the method comprising:

equipping the hydrogen storage tank with at least one compartment for storing the storage media, passages for transporting hydrogen gas to the hydrogen storage tank and into the compartment and for transporting hydrogen gas out of the compartment, and means for distributing heat within the compartment so as to establish a substantially uniform temperature in the storage media within the compartment;

filling the hydrogen storage tank to full capacity by flowing hydrogen gas through the passages and into the compartment so as to adsorb hydrogen on the storage media;

heating the storage media to a temperature and sensing the pressure of hydrogen gas released from the compartment at the temperature;

turning on a light source for a time period during which the storage media is at the temperature, the light source generating light at wavelengths to which the storage media is at least partially transparent and at which bonds between hydrogen and the storage media will absorb at least a portion of the light so as to promote the release of hydrogen gas from the storage media;

sensing a change in the pressure of hydrogen gas released from storage media at the temperature while the light source is on;

drawing hydrogen gas from the hydrogen storage tank;

causing hydrogen release from the storage media for a time period during which there is a substantially constant demand on the hydrogen storage tank by turning on the light source;

measuring a change in pressure of the hydrogen gas released from the storage media during the time period; and

then

comparing the measured change in pressure to a look-up table to determine the hydrogen fill level in the hydrogen storage tank, the look-up table being derived from a series of plots relating changes in pressure of the hydrogen gas in the hydrogen storage tank versus fill levels of hydrogen in the hydrogen storage tank as a function of temperature.

16. The method according to claim 15, wherein the look-up table is generated by:

filling the hydrogen storage tank with hydrogen gas at predetermined fill levels by adsorbing the hydrogen gas on the storage media;

heating the storage media to a plurality of temperatures and, at each of the temperatures and each of the predetermined fill levels, sensing the pressure of hydrogen gas desorbed from the storage media; and

turning on a light source and sensing a change in the pressure of the hydrogen gas desorbed from storage media during a time period at each of the temperatures and each of the predetermined fill levels, the light source generating light at wavelengths to which the storage media is at least partially transparent and at which bonds between hydrogen and the storage media will absorb at least a portion of the light so as to promote the release of hydrogen gas from the storage media.

17. The method according to claim 15, wherein the light generated by the light source includes infrared wavelengths.

18. The method according to claim 15, further comprising generating an electric field within the compartment.

19. The method according to claim 15, wherein heat is distributed in the compartment by flowing a coolant through at least one heat exchanger tube that passes through the compartment.

20. The method according to claim 15, wherein the storage media is nano-porous silicon.

21. A hydrogen storage tank comprising:

a plurality of separate compartments within the hydrogen storage tank;

a solid-state hydrogen storage media within the compartments, the storage media being capable of adsorbing and desorbing hydrogen at surfaces thereof;

passages for transporting hydrogen gas to the hydrogen storage tank and into each of the compartments and for transporting hydrogen gas out of each of the compartments;

means for distributing heat within and among the compartments so as to establish a substantially uniform temperature in the storage media within the compartments;

means for desorbing hydrogen from the storage media; and

means for sensing the pressure of hydrogen gas released by desorption from the storage media within the compartments.

22. The hydrogen storage tank according to claim 21, further comprising:

a look-up table derived from a series of plots relating change in hydrogen gas pressure measured by the sensing means versus fill levels of hydrogen gas in the hydrogen storage tank as a function of temperature; and

means for utilizing the look-up table to determine the fill level of hydrogen gas in the hydrogen storage tank.

23. The hydrogen storage tank according to claim 21, further comprising a light source that generates light at wavelengths to which the storage media is at least partially transparent and at which bonds between hydrogen and the storage media will absorb at least a portion of the light so as to promote the release of hydrogen from the storage media.

24. The hydrogen storage tank according to claim 23, wherein the light generated by the light source includes infrared wavelengths.

25. The hydrogen storage tank according to claim 21, further comprising means for generating an electric field within the compartments.

26. The hydrogen storage tank according to claim 21, wherein the heat distributing means comprises heat exchanger tubes that pass through each of the compartments.

27. The hydrogen storage tank according to claim 21, wherein the compartments are defined within the hydrogen storage tank by dividers and the compartments are substantially parallel to each other.

28. The hydrogen storage tank according to claim 27, wherein the heat distributing means comprises heat exchanger tubes, each of the tubes individually passing through a corresponding one of the compartments.

29. The hydrogen storage tank according to claim 27, wherein each of the passages individually passes through a corresponding one of the compartments.

30. The hydrogen storage tank according to claim 21, wherein the compartments are defined by boxes individually placed and stacked in parallel columns within the hydrogen storage tank.

31. The hydrogen storage tank according to claim 30, wherein the heat distributing means comprises heat exchanger tubes, each of the tubes individually passing through a corresponding one of the columns.

32. The hydrogen storage tank according to claim 30, wherein each of the passages individually passes through a corresponding one of the columns.

33. The hydrogen storage tank according to claim 21, wherein the storage media is nano-porous silicon.