Solid perfumed preparation in the form of microbeads and the use thereof

• US 7,723,284 B2
• Filed: 03/16/2001
• Issued: 05/25/2010
• Est. Priority Date: 03/20/2000
• Status: Expired due to Fees

• Current Assignee: V. Mane Fils
• Original Assignee: V. MANE FILS
• Inventors: Dailland, Pascal, Bleuez, Lo c, Delpech, Guy, Hoc, Nathalie, Mane, Jean, Hannetel, Jean-Michel
• Primary Examiner(s): JARRETT, LORE RAMILLANO
• Application Number:
  US10/239,022
• Publication Number:
  US 20040106536A1
• Time in Patent Office: 3,357 Days
• Field of Search: 512/4, 512/1, 512/2, 512/25, 436/55, 424/66
• US Class Current: 512/1
• CPC Class Codes: A61L 9/012 characterised by being in a special form, e.g. gels, emulsions A61L9/048 takes precedence
• CPC Class Codes: Y10T 436/12 Condition responsive control

Abstract

The invention concerns a solid perfumed preparation with high persistency in the form of microbeads and comprising a volatile aromatic raw material, or a mixture of volatile aromatic raw materials, and one or several fusible excipients. Said preparation can further comprise one of the following constituents: one or more polymers dispersible in the melted mass formed by the constituents of the preparation, one or more mineral additives, one or more surfactants, one or more antioxidants, one or more colouring agents. The invention can be used in cosmetics and in household product industries.

Claims

1. A solid fragranced preparation with increased persistence in the form of round microbeads obtained from forcing a molten mass through a nozzle, wherein the microbeads consist essentially of:

10 to 40% by weight of a volatile aromatic raw material or a mixture of volatile aromatic raw materials,

60 to 90% by weight of meltable excipients comprising one or more meltable alkylmethyl siloxanes and none or at least one meltable excipient selected from the group consisting of fatty alcohols, fatty acids, glycerol esters, hydrogenated oils, fatty acid salts, waxes selected from the group consisting of microcrystalline waxes, white wax, carnauba wax and paraffin, polyethylene glycols of high molecular weight, plant fats, and fatty acid esters, and

none or at least one member of the group consisting of polymers that are soluble or dispersible in the molten mass, mineral additives, surfactants, antioxidants, colorants, and any combination thereof, wherein polymers soluble or dispersible in the molten mass are selected from the group consisting of cellulose derivatives, acrylic resins, polyvinyl acetates, allyl methacrylate cross polymers, polyalkylene resins, polylactic resins, maleic anhydride resins, silicone resins, and any combination thereof, and

wherein the microbeads have a melting point between 25°

C. and 45°

C.

2. The solid fragranced preparation of claim 1, wherein 70% to 80% by weight of meltable excipients are present in the microbeads.

3. The solid fragranced preparation of claim 1, wherein 20% to 30% by weight of volatile aromatic raw material or mixture of volatile aromatic raw materials are present in the microbeads.

4. The solid fragranced preparation of claim 1, wherein the volatile aromatic raw material or mixture of volatile aromatic raw materials is selected from the group consisting of aromatic, terpenic and/or sesquiterpenic hydrocarbons;

aromatic alcohols;

primary, secondary or tertiary, saturated or unsaturated, cyclic or acyclic nonaromatic alcohols;

aldehydes;

phenols;

carboxylic acids;

aromatic and/or nonaromatic ethers and acetals in their acyclic or cyclic form;

heterocycles containing a nitrogen atom;

ketones;

aromatic or nonaromatic sulfides, disulfides and mercaptans, essentials oils, and any combination thereof.

5. The solid fragranced preparation of claim 1, wherein the volatile aromatic raw material or mixture of volatile aromatic raw materials is selected from the group consisting of 2,6-dimethyl-7-octen-2-ol, methyl dihydrojasmonate, and any combination thereof.

6. The solid fragranced preparation of claim 1, wherein the microbeads have a diameter of between 5 μ

m and 5 mm.

7. The solid fragranced preparation of claim 6, wherein the microbeads have a diameter of between 10 μ

m and 4 mm.

8. The solid fragranced preparation of claim 7, wherein the microbeads have a diameter of between 10 μ

m and 1500 μ

m.

9. A cosmetic composition comprising a solid fragranced preparation of claim 1.

10. The cosmetic composition of claim 9, selected from the group consisting of freelancing products, bodycare and facialcare products, rinse-out foaming products, conditioning products, and sun creams.

11. The cosmetic composition of claim 9, in a form selected from the group consisting of a solid perfume, a milk, a cream, a hydrogel, a shampoo, a shower gel, a fixing hair gel and a conditioner.

12. A household product comprising a solid fragranced preparation of claim 1.

13. The household product of claim 12, selected from the group consisting of detergent products, softening products and textile treatment products.

14. A method for manufacturing a preparation of a solid fragrance with increased persistence in the form of round microbeads, said method consisting essentially of:

mixing 10% to 40% by weight of a volatile aromatic raw material or a mixture of volatile aromatic raw materials with 60% to 90% by weight of meltable excipients comprising one or more meltable alkylmethyl siloxanes and none or at least one meltable excipient selected from the group consisting of fatty alcohols;

fatty acids;

glycerol esters;

hydrogenated oils;

fatty acid salts;

waxes selected from the group consisting of microcrystalline waxes, white wax, carnauba wax, and paraffin;

polyoxyethylene glycols of high molecular weight;

plant fats; and

fatty acid esters;

to obtain a molten mass;

adding to the molten mass none or at least one member of the group consisting of polymers that are soluble or dispersible in the molten mass, mineral additives, surfactants, antioxidants, colorants, and any combination thereof wherein polymers soluble or dispersible in the molten mass are selected from the group consisting of cellulose derivatives, acrylic resins, polyvinyl acetates, allyl methacrylates cross polymers, polyalkylene resins, polylactic resins, maleic anhydride resins, silicone resins, and any combination thereof;

forcing the molten mass through a nozzle to obtain round microbeads; and

cooling the round microbeads to obtain solidified products,

wherein the temperature reached during the method does not exceed 100°

C. depending on the duration of heating, which is between a few seconds and 4 hours, and wherein the microbeads obtained have a melting point between 25°

C. and 45°

C.

15. A solid fragranced preparation with increased persistence in the form of round microbeads prepared by the method of claim 14.

16. The solid fragranced preparation of claim 15 formulated in a hydrogel.