Inorganic matrix compositions and composites incorporating the matrix composition
First Claim
1. A glass consisting essentially of the following formula:
-
a(A′
2O)xb(GfO)yc(A″
O)z where A′
represents at least one alkali metal glass modifier comprising lithium that functions as a fluxing agent, Gf represents at least one glass former comprising boron and phosphorus, A″
represents at least one glass network modifier comprising zinc oxide, lead oxide, aluminum oxide, zirconium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, or silicon oxide, or any combination thereof, a represents the number of fluxing agents present and ranges from about 1 to about 5, b represents the number of glass formers present and ranges from about 1 to about 10, c represents the number of glass network modifiers and ranges from about 1 to about 30, x represents the mole fraction of fluxing agent and is from about 0.11 to about 0.225, y represents the mole fraction of glass former and is from about 0.475 to about 0.675 with the proviso that the amount of boron as B2O3 is at least about 0.040, z represents the mole fraction of glass network modifiers and is from about 0.10 to about 0.30, x+y+z=1, and x<
y, and wherein said glass is acidic.
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Accused Products
Abstract
A modified alkali silicate composition for forming an inorganic network matrix. The modified alkali silicate matrix is made by reacting an alkali silicate (or its precursors such as an alkali hydroxide, a SiO2 source and water), an acidic inorganic composition, such as a reactive glass, water and optional fillers, additives and processing aids. An inorganic matrix composite can be prepared by applying a slurry of the modified aqueous alkali silicate composition to a reinforcing medium and applying the temperature and pressure necessary to consolidate the desired form. The composite can be shaped by compression molding as well as other known fabrication methods. A notable aspect of the invention is that, although composite and neat resin components prepared from the invention can exhibit excellent dimensional stability to 1000° C. and higher, they can be prepared at the lower temperatures and pressures typical to organic polymer processing.
68 Citations
12 Claims
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1. A glass consisting essentially of the following formula:
-
a(A′
2O)xb(GfO)yc(A″
O)zwhere A′
represents at least one alkali metal glass modifier comprising lithium that functions as a fluxing agent, Gf represents at least one glass former comprising boron and phosphorus, A″
represents at least one glass network modifier comprising zinc oxide, lead oxide, aluminum oxide, zirconium oxide, magnesium oxide, calcium oxide, strontium oxide, barium oxide, or silicon oxide, or any combination thereof, a represents the number of fluxing agents present and ranges from about 1 to about 5, b represents the number of glass formers present and ranges from about 1 to about 10, c represents the number of glass network modifiers and ranges from about 1 to about 30, x represents the mole fraction of fluxing agent and is from about 0.11 to about 0.225, y represents the mole fraction of glass former and is from about 0.475 to about 0.675 with the proviso that the amount of boron as B2O3 is at least about 0.040, z represents the mole fraction of glass network modifiers and is from about 0.10 to about 0.30, x+y+z=1, and x<
y, and wherein said glass is acidic. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10)
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11. A glass consisting essentially of the following formula
(Li2O)x(P2O5)y1 (B2O3)y2 (MgO)z1 (BaO)z2 where x ranges from 0.11 to about 0.20, y1 ranges from about 0.425 to 0.625, y2 ranges from about 0.04 to 0.075, z1 ranges from about 0.01 to about 0.10, z2 ranges from about 0.01 to about 0.20, and x+y1+y2+z1+z2=1 and x< - y1+y2.
- View Dependent Claims (12)
Specification