Process and apparatus for producing olefin polymers

• US 7,740,808 B2
• Filed: 04/29/2005
• Issued: 06/22/2010
• Est. Priority Date: 04/29/2004
• Status: Active Grant

• Current Assignee: Borealis Technology Oy (IPIC Holdings GmbH)
• Original Assignee: Borealis Technology Oy (IPIC Holdings GmbH)
• Inventors: Zitting, Samuli, Vuorikari, Marianna, Korhonen, Esa, Andtsjo, Henrik
• Primary Examiner(s): Cheung; William K
• Application Number:
  US11/578,138
• Publication Number:
  US 20080039597A1
• Time in Patent Office: 1,880 Days
• Field of Search: 422/132, 526/67, 526/64, 526/89, 526/90, 526/226
• US Class Current: 422/132
• CPC Class Codes: B01J 19/1837 Loop-type reactors
• CPC Class Codes: B01J 2208/00274 involving reactant vapours
• CPC Class Codes: B01J 2208/003 involving reactant slurries
• CPC Class Codes: B01J 2208/00761 Discharging
• CPC Class Codes: B01J 2219/00006 Large-scale industrial plants
• CPC Class Codes: B01J 8/0015 Feeding of the particles in the reactor; Evacuation of the particles out of the reactor
• CPC Class Codes: C08F 10/02 Ethene
• CPC Class Codes: C08F 110/02 Ethene
• CPC Class Codes: C08F 2/14 Organic medium
• CPC Class Codes: C08F 210/08 Butenes
• CPC Class Codes: C08F 210/16 Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
• CPC Class Codes: C08F 6/003 from polymer solutions, suspensions, dispersions or emulsions without recovery of the polymer therefrom
• CPC Class Codes: C08F 6/20 Concentration
• CPC Class Codes: C08L 23/04 Homopolymers or copolymers of ethene

Abstract

The present invention concerns a process and an apparatus for continuous polymerisation of olefin monomers. In particular, the present invention concerns a process and an apparatus for continuous polymerisation olefin monomers like ethylene and other monomers, wherein an olefin monomer is polymerised in slurry phase in an inert hydrocarbon diluent in at least one loop reactor. According to the invention, a polymer slurry is continuously withdrawn from the loop reactor and concentrated. The concentrated slurry is conducted to a flash unit in order to remove the remaining fluid phase, and gas obtained is compressed in a flash gas compressor before it is being fed to a distillation section. By means of the present invention it is possible reduce the size of the flash gas compressor and the capacity of the distillation sections. This significantly reduces investment cost for a continuously operated polymerization apparatus.

Claims

1. A process for producing olefin polymers in a loop reactor, wherein at least one olefin monomer is polymerised in slurry phase in a hydrocarbon diluent or liquid monomer, said process comprising

polymerizing at least one olefin in a loop reactor in slurry phase,

continuously withdrawing a polymer slurry from the loop reactor,

increasing the concentration of the polymer slurry by separating it from an overhead stream,

recycling the overhead stream to the loop reactor,

recycling a first part of the concentrated slurry back to the loop reactor,

conducting a second part of the concentrated slurry to a flash unit,

recovering the polymer from the flash unit,

compressing a first part of the overhead gas stream in a flash compressor,

passing the compressed flash gas stream into a heavies column in order to separate oligomers and other heavy components from the gas stream,

passing a second part of the overhead stream from the heavies column into a flash vessel in order to form a liquid phase and a vapour phase, and

directing at least a part of the liquid phase into a lights column in order to separate the low-boiling components from the liquid phase.

2. The process according to claim 1, wherein at least a part of the bottom steam of the lights column is conducted into a recycle diluent stream which is recycled into the loop reactor.

3. The process according to claim 1, wherein at least a part of the vapour phase of the flash vessel is conducted into a recycle lights stream which is recycled into the loop reactor.

4. The process according to claim 1, wherein the bottom stream of the lights column is conducted into a comonomer column and at least a part of the overhead stream from the comonomer column is conducted into the loop reactor, whereas at least a part of the bottom stream of the comonomer column is conducted into a recycle comonomer stream for recycling into the loop reactor.

5. The process according to claim 1, wherein the solids content of the concentrated slurry is 30 to 55% by volume.

6. The process according to claim 1, wherein 10-90% of the concentrated slurry is recycled to the loop reactor and a second part of concentrated slurry is conducted to the flash.

7. The process according to claim 1, wherein the slurry is concentrated in a hydrocyclone to provide an underflow, which comprises the concentrated slurry, and an overflow, which is rich in hydrocarbon(s).

8. The process according to claim 1, wherein the slurry is withdrawn from the loop reactor in such a manner that the concentration of solids at the outlet is higher than the concentration of solids in the loop reactor.

9. The process according to claim 8, wherein the overflow is recycled to the loop reactor.

10. The process according to claim 9, wherein the ratio of the recycled overflow to the underflow withdrawn from the hydrocyclone is 0.01 to 10.

11. The process according to claim 8, wherein the solids concentration of the slurry of the overflow is 0.001 to 5% by volume of the flow.

12. The process according to claim 1, wherein the flash unit comprises a flash pipe, which is optionally heated, in which the remaining hydrocarbons of the concentrated slurry are at least partly evaporated to form an overflow containing the evaporated fluid phase, and a receiving vessel to form an overflow containing the evaporated fluid phase and a product flow containing the polymer particles and a minor amount of the fluid phase.

13. The process according to claim 1, wherein the product flow from the flash unit contains less than 0.1 mol-% of hydrogen.

14. The process according to claim 1, wherein the monomer is ethylene, which is optionally copolymerised with one or more C₄ to C₁₀ alpha-olefins.

15. The process according to claim 1, wherein the catalytic system comprises a Ziegler-Natta catalyst, single site catalyst, multi site catalyst or a combination or mixture of the above.

25. The process according to claim 1, wherein the solids content of the concentrated slurry is 40 to 52% by volume.

26. The process according to claim 9, wherein the ratio of the recycled overflow to the underflow withdrawn from the hydrocyclone is 0.01 to 5.

27. The process according to claim 9, wherein the ratio of the recycled overflow to the underflow withdrawn from the hydrocyclone is 0.1 to 2.

16. An apparatus for producing an olefin polymer in the presence of a catalytic system comprising

a loop reactor,

a separation device for increasing the solids content of the slurry withdrawn from the loop reactor to provide a concentrated slurry,

a flash unit for essentially evaporating all of the remaining liquid-phase hydrocarbons of the slurry phase diluent to provide a gas/solids mixture containing polymer solids gases,

a flash gas compressor connected to the outlet of the flash unit for compressing at least a part of the overhead gas of the flash unit, and

a distillation section for recovering and recycling heavy and light components of the overhead gas of the flash unit.

17. The apparatus according to claim 16, wherein the separation device for increasing the solids content of the slurry comprises a hydrocyclone.

18. The apparatus according to claim 16, wherein the distillation section is connected to the outlet of the flash gas compressor.

19. The apparatus according to claim 16, wherein the distillation section comprises, in a cascade, at least one heavies column for separating heavy components from the compressed gas of the flash unit, and at least one lights column for separating light components from the overhead product of the heavies column.

20. The apparatus according to claim 16, comprising in combination

a loop reactor for polymerising olefin monomer in slurry phase in a reaction mixture comprising fluid hydrocarbons and optionally hydrogen and polymer particles and provided with at least one outlet to allow for continuous withdrawal of polymer slurry,

at least one hydrocyclone having at least one inlet for the polymer slurry and at least one first outlet for concentrated slurry and at least one second outlet for an overhead flow, said inlet being connected to the outlet of the loop reactor, and said hydrocyclone being adapted to separate the fluid phase from the polymer slurry to provide a concentrated slurry,

a flash unit having at least one inlet for the slurry and at least one first outlet for a suspension of polymer solids and gases and at least one second outlet for evaporated fluid phase, said inlet being connected to the first outlet of the hydrocyclone, and said flash unit being adapted to separate the fluid phase from the concentrated slurry,

a flash gas compressor connected to the second outlet of the flash unit for compressing at least a part of the overhead gas of the flash unit, said compressor having an outlet for the compressed flash gas,

at least one heavies column for separating heavy components, having an inlet for compressed gas connected to the outlet of the compressor, and having a first outlet for an overhead product and a second outlet for a bottom product, and

at least one lights column connected to the first outlet of the heavies column for separating light components from the overhead product.

21. The apparatus according to claim 16, further comprising a comonomer column connected to the outlet of a bottom stream of the lights column.

22. The apparatus according to claim 16, wherein the comonomer column comprises an outlet for an overhead stream which is connected to a recycle line to the loop reactor.

23. The apparatus according to claim 16, wherein the flash is a high pressure flash.

24. The apparatus according to claim 16, wherein the outlet of the loop reactor is placed at a suitable location downstream of the loop circulation pump.