Compositions including hardness ions and gluconate and methods employing them to reduce corrosion and etch

• US 7,741,262 B2
• Filed: 10/31/2008
• Issued: 06/22/2010
• Est. Priority Date: 05/04/2007
• Status: Expired due to Fees

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab, Inc.
• Inventors: Smith, Kim R., Lawrence, Michel M., Bartelme, Michael J.
• Primary Examiner(s): Boyer; Charles I
• Application Number:
  US12/263,021
• Publication Number:
  US 20090149363A1
• Time in Patent Office: 599 Days
• Field of Search: 510/227, 510/220, 510/235, 510/255, 510/287, 510/401, 510/514
• US Class Current: 510/227
• CPC Class Codes: C02F 2303/14 Maintenance of water treatment installations
• CPC Class Codes: C02F 2303/22 Eliminating or preventing deposits, scale removal, scale prevention C02F1/042, C02F1/4602, C02F5/00 take precedence
• CPC Class Codes: C02F 5/02 Softening water by precipitation of the hardness
• CPC Class Codes: C02F 5/06 using calcium compounds
• CPC Class Codes: C11D 2111/14 Hard surfaces
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 7/10 Salts
• CPC Class Codes: C23F 11/08 in other liquids
• CPC Class Codes: C23F 11/124 Carboxylic acids
• CPC Class Codes: C23F 11/18 using inorganic inhibitors
• CPC Class Codes: C23G 1/20 Other heavy metals
• CPC Class Codes: C23G 1/22 Light metals

Abstract

The present invention relates to compositions including a water soluble magnesium salt, water soluble calcium salt, and gluconate, which have a beneficial effect on corrosion during cleaning. The present compositions can reduce corrosion of a variety of surfaces including glass, aluminum, chrome, copper, and steel. The present invention also relates to methods employing these compositions.

Claims

1. A method for cleaning an instrument comprising:

contacting the instrument with a cleaning composition comprising;

(a) a corrosion inhibitor composition comprising;

i) a water soluble magnesium salt;

ii) a water soluble calcium salt; and

iii) a gluconate;

(b) a source of alkalinity; and

(c) a chelating agent;

such that the instrument is cleaned, wherein the cleaning composition reduces corrosion of the instrument by at least about 10%, and wherein the weight ratio of water soluble magnesium salt to water soluble calcium salt is 2;

1, and the weight ratio of water soluble magnesium salt to gluconate is 1;

9.

2. The method of claim 1, wherein the weight ratio of water soluble calcium salt to gluconate is 1:

19.

3. The method of claim 1, wherein the water soluble magnesium salt is selected from the group consisting of magnesium acetate, magnesium benzoate, magnesium bromide, magnesium bromate, magnesium chlorate, magnesium chloride, magnesium chromate, magnesium citrate, magnesium formate, magnesium gluconate, magnesium hexafluorosilicate, magnesium iodate, magnesium iodide, magnesium lactate, magnesium molybdate, magnesium nitrate, magnesium perchlorate, magnesium phosphinate, magnesium salicylate, magnesium sulfate, magnesium sulfite, magnesium thiosulfate, a hydrate thereof, and a mixture thereof.

4. The method of claim 1, wherein the water soluble calcium salt is selected from the group consisting of calcium acetate, calcium benzoate, calcium bromate, calcium bromide, calcium chlorate, calcium chloride, calcium chromate, calcium dihydrogen phosphate, calcium dithionate, calcium formate, calcium gluconate, calcium glycerophosphate, calcium hydrogen sulfide, calcium iodide, calcium lactate, calcium metasilicate, calcium nitrate, calcium nitrite, calcium pantothenate, calcium perchlorate, calcium permanganate, calcium phosphate, calcium phosphinate, calcium salicylate, calcium succinate, a hydrate thereof, and a mixture thereof.

5. The method of claim 1, wherein the gluconate is selected from the group consisting of sodium gluconate, lithium gluconate, potassium gluconate or a mixture thereof.

6. The method of claim 1, wherein the source of alkalinity comprises sodium bicarbonate.

7. The method of claim 1, wherein the chelating agent comprises sodium citrate.

8. The method of claim 1, wherein the cleaning composition comprises:

(a) about 10% of the corrosion inhibitor composition;

(b) about 10% of the source of alkalinity; and

(c) about 20% of the chelating agent, wherein the cleaning composition is substantially free of NTA, EDTA, and phosphorous containing compounds.

9. The method of claim 8, wherein the cleaning composition is substantially free of zinc and aluminum containing compounds.

10. The method of claim 1, wherein the cleaning composition further comprises:

(d) an enzyme.

11. The method of claim 10, wherein the enzyme is selected from the group consisting of proteases, lipases, amylases, and mixtures thereof.

12. The method of claim 1, wherein the instrument is a medical or dental instrument selected from the group consisting of diagnostic instruments, trays, pans, holders, racks, forceps, scissors, shears, saws, bone saws, saw blades, hemostats, knives, chisels, rongeurs, files, nippers, drills, drill bits, rasps, burrs, spreaders, breakers, elevators, clamps, needle holders, carriers, clips, hooks, gouges, curettes, retractors, straighteners, punches, extractors, scoops, keratomes, spatulas, expressors, trocars, dilators, cages, glassware, tubing, catheters, cannulas, plugs, stents, scopes, endoscopes, stethoscopes, arthoscopes, and combinations thereof.

13. The method of claim 1, wherein the cleaning composition reduces corrosion by at least about 50%.

14. A composition for cleaning an instrument comprising:

(a) a corrosion inhibitor composition comprising;

i) a water soluble magnesium salt;

ii) a water soluble calcium salt; and

iii) a gluconate;

(b) a source of alkalinity; and

(c) a chelating agent;

wherein the composition reduces corrosion of the instrument by at least about 10%, and wherein the weight ratio of water soluble magnesium salt to water soluble calcium salt is 2;

1, and the weight ratio of water soluble magnesium salt to gluconate is 1;

9.

15. The composition of claim 14, wherein the weight ratio of water soluble calcium salt to gluconate is 1:

19.

16. The composition of claim 14, wherein the water soluble magnesium salt is selected from the group consisting of magnesium acetate, magnesium benzoate, magnesium bromide, magnesium bromate, magnesium chlorate, magnesium chloride, magnesium chromate, magnesium citrate, magnesium formate, magnesium gluconate, magnesium hexafluorosilicate, magnesium iodate, magnesium iodide, magnesium lactate, magnesium molybdate, magnesium nitrate, magnesium perchlorate, magnesium phosphinate, magnesium salicylate, magnesium sulfate, magnesium sulfite, magnesium thiosulfate, a hydrate thereof, and a mixture thereof.

17. The composition of claim 14, wherein the water soluble calcium salt is selected from the group consisting of calcium acetate, calcium benzoate, calcium bromate, calcium bromide, calcium chlorate, calcium chloride, calcium chromate, calcium dihydrogen phosphate, calcium dithionate, calcium formate, calcium gluconate, calcium glycerophosphate, calcium hydrogen sulfide, calcium iodide, calcium lactate, calcium metasilicate, calcium nitrate, calcium nitrite, calcium pantothenate, calcium perchlorate, calcium permanganate, calcium phosphate, calcium phosphinate, calcium salicylate, calcium succinate, a hydrate thereof, and a mixture thereof.

18. The composition of claim 14, wherein the gluconate is selected from the group consisting of sodium gluconate, lithium gluconate, potassium gluconate or a mixture thereof.

19. The composition of claim 14, wherein the source of alkalinity comprises sodium bicarbonate.

20. The composition of claim 14, wherein the chelating agent comprises sodium citrate.

21. The composition of claim 14, wherein the cleaning composition comprises:

(a) about 10% of the corrosion inhibitor composition;

(b) about 10% of the source of alkalinity; and

(c) about 20% of the chelating agent, wherein the cleaning composition is substantially free of NTA, EDTA, and phosphorous containing compounds.

22. The composition of claim 21, wherein the cleaning composition is substantially free of zinc and aluminum containing compounds.

23. The composition of claim 14, wherein the cleaning composition further comprises:

(d) an enzyme.

24. The composition of claim 23, wherein the enzyme is selected from the group consisting of proteases, lipases, amylases, and mixtures thereof.

25. The composition of claim 14, wherein the instrument is a medical or dental instrument selected from the group consisting of diagnostic instruments, trays, pans, holders, racks, forceps, scissors, shears, saws, bone saws, saw blades, hemostats, knives, chisels, rongeurs, files, nippers, drills, drill bits, rasps, burrs, spreaders, breakers, elevators, clamps, needle holders, carriers, clips, hooks, gouges, curettes, retractors, straighteners, punches, extractors, scoops, keratomes, spatulas, expressors, trocars, dilators, cages, glassware, tubing, catheters, cannulas, plugs, stents, scopes, endoscopes, stethoscopes, arthoscopes, and combinations thereof.

26. The composition of claim 14, wherein the cleaning composition reduces corrosion by at least about 50%.