Coating compositions exhibiting corrosion resistance properties, related coated substrates, and methods

• US 7,745,010 B2
• Filed: 03/20/2006
• Issued: 06/29/2010
• Est. Priority Date: 08/26/2005
• Status: Active Grant

• Current Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Original Assignee: PRC-DeSoto International, Inc. (Nouryon BV)
• Inventors: Schneider, John R.
• Primary Examiner(s): Feely; Michael J
• Application Number:
  US11/384,970
• Publication Number:
  US 20070048540A1
• Time in Patent Office: 1,562 Days
• Field of Search: None
• US Class Current: 428/450
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08K 3/32 Phosphorus-containing compounds
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08K 3/38 Boron-containing compounds
• CPC Class Codes: C09D 5/084 Inorganic compounds
• CPC Class Codes: C09D 7/48 Stabilisers against degradation by oxygen, light or heat
• CPC Class Codes: C09D 7/67 Particle size smaller than 100 nm
• CPC Class Codes: C09D 7/68 Particle size between 100-1000 nm
• CPC Class Codes: Y10S 977/778 within specified host or matrix material, e.g. nanocomposite films
• CPC Class Codes: Y10S 977/779 Possessing nanosized particles, powders, flakes, or clusters other than simple atomic impurity doping
• CPC Class Codes: Y10T 428/256 Heavy metal or aluminum or compound thereof
• CPC Class Codes: Y10T 428/258 Alkali metal or alkaline earth metal or compound thereof
• CPC Class Codes: Y10T 428/259 Silicic material
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/31522 Next to metal
• CPC Class Codes: Y10T 428/31529 Next to metal
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31855 Of addition polymer from unsaturated monomers

Abstract

Coating compositions are disclosed that include corrosion resisting particles such that the coating composition can exhibit corrosion resistance properties. Also disclosed are substrates at least partially coated with a coating deposited from such a composition and multi-component composite coatings, wherein at least one coating later is deposited from such a coating composition. Methods and apparatus for making ultrafine solid particles are also disclosed.

Claims

1. A method for enhancing the corrosion resistance of a substrate comprising an aluminum alloy, the method comprising coating at least a portion of the substrate with a composition comprising:

(a) a film-forming resin;

(b) particles comprising magnesium oxide, wherein said particles have an average primary particle size of no more than 100 nanometers; and

(c) an alkoxy-monosilane compound.

2. The method of claim 1, wherein said particles consist essentially of magnesium oxide.

3. The method of claim 1, wherein said particles comprising magnesium oxide have an average primary particle size of no more than 50 nanometers.

4. The method of claim 1, wherein said film-forming resin comprises a polyvinyl polymer.

5. The method of claim 1, wherein said composition further comprises an adhesion promoting component comprising at least one of:

(a) tannic acid, gallic acid, phosphoric acid, phosphorous acid, citric acid, malonic acid, a derivative thereof, or a mixture thereof;

(b) a metal phosphate;

(c) an organophosphate;

(d) an organophosphonate; and

(e) a phosphatized epoxy resin.

6. The method of claim 1, wherein said film-forming resin comprises a phenolic resin.

7. The method of claim 1, wherein the aluminum alloy comprises:

(a) 90.7 to 94.7 weight percent aluminum;

(b) 3.8 to 4.9 weight percent copper;

(c) 1.2 to 1.8 weight percent magnesium; and

(d) 0.3 to 0.9 weight percent manganese.

8. The method of claim 7, wherein the substrate is a bare metal substrate comprising the aluminum alloy.

9. The method of claim 8, with the proviso that the composition is free of phosphoric acid.

10. The method of claim 1, with the proviso that the substrate is not aluminum plated steel.

11. The method of claim 1, wherein the composition comprises phosphoric acid.

12. A substrate comprising an aluminum alloy, wherein the substrate is at least partially coated with a primer coating comprising:

(a) a film-forming resin;

(b) particles comprising magnesium oxide, wherein said particles have an average primary particle size of no more than 100 nanometers;

(c) an alkoxy-monosilane compound.

13. The aluminum substrate of claim 12, wherein said particles consist essentially of magnesium oxide.

14. The aluminum substrate of claim 12, wherein said particles comprising magnesium oxide have an average primary particle size of no more than 50 nanometers.

15. The aluminum substrate of claim 12, wherein said film-forming resin comprises a polyvinyl polymer.

16. The aluminum substrate of claim 12, wherein said composition further comprises an adhesion promoting component comprising at least one of:

(a) tannic acid, gallic acid, phosphoric acid, phosphorous acid, citric acid, malonic acid, a derivative thereof, or a mixture thereof;

(b) a metal phosphate;

(c) an organophosphate;

(d) an organophosphonate; and

(e) a phosphatized epoxy resin.

17. The aluminum substrate of claim 12, wherein said film-forming resin comprises a phenolic resin.

18. The substrate of claim 12, wherein the aluminum alloy comprises:

(a) 90.7 to 94.7 weight percent aluminum;

(b) 3.8 to 4.9 weight percent copper;

(c) 1.2 to 1.8 weight percent magnesium; and

(d) 0.3 to 0.9 weight percent manganese.

19. The substrate of claim 18, wherein the primer coating is deposited directly over a bare metal substrate comprising the aluminum alloy.

20. The substrate of claim 12, wherein the primer coating is deposited directly over a bare metal substrate comprising an aluminum alloy.

21. The substrate of claim 20, with the proviso that the composition is free of phosphoric acid.

22. The substrate of claim 12, with the proviso that the substrate is not aluminum plated steel.

23. The substrate of claim 12, wherein the primer coating comprises phosphoric acid.

24. A method for coating a metal substrate comprising an aluminum alloy, the method comprising depositing a coating directly to at least a portion of the metal substrate, the coating being deposited from a composition comprising:

(a) a film-forming resin;

(b) particles comprising magnesium oxide, wherein said particles have an average primary particle size of no more than 100 nanometers; and

(c) an alkoxy-monosilane compound

wherein the aluminum alloy comprises

(i) 90.7 to 94.7 weight percent aluminum;

(ii) 3.8 to 4.9 weight percent copper;

(iii) 1.2 to 1.8 weight percent magnesium; and

(iv) 0.3 to 0.9 weight percent manganese.

25. The method of claim 24, wherein the film-forming resin comprises a phenolic resin.

26. The method of claim 24, with the proviso that the composition is free of phosphoric acid.

27. The method of claim 24, with the proviso that the substrate is not aluminum plated steel.

28. The method of claim 24, wherein the composition comprises phosphoric acid.

29. A method for coating an aluminum alloy substrate, the method comprising depositing a coating directly to at least a portion of the aluminum alloy substrate, the coating being deposited from a composition comprising:

(a) a film-forming resin;

(b) particles comprising magnesium oxide, wherein said particles have an average primary particle size of no more than 100 nanometers; and

(c) an alkoxy-monosilane compound;

wherein the composition is free of phosphoric acid.