Method of continuous processing of lignocellulosic feedstock

• US 7,754,457 B2
• Filed: 06/02/2006
• Issued: 07/13/2010
• Est. Priority Date: 06/03/2005
• Status: Expired due to Fees

• Current Assignee: Iogen Energy Corporation (Iogen Corporation)
• Original Assignee: Iogen Energy Corporation (Iogen Corporation)
• Inventors: Tolan, Jeffrey S., Foody, Brian
• Primary Examiner(s): Lilling; Herbert J.
• Application Number:
  US11/916,347
• Publication Number:
  US 20080293114A1
• Time in Patent Office: 1,502 Days
• Field of Search: None
• US Class Current: 435/165
• CPC Class Codes: C12P 19/14 produced by the action of a carbohydrase (EC 3.2.x), e.g. by alpha-amylase , e.g. by cellulase, hemicellulase
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: D21C 1/02 with water or steam
• CPC Class Codes: D21C 1/04 with acid reacting compounds
• CPC Class Codes: D21C 11/0007 Recovery of by-products, i.e. compounds other than those necessary for pulping, for multiple uses or not otherwise provided for volatile compounds obtained by decomposition of spent liquors in order to regenerate them D21C11/125; compounds obtained by fractionating the liquors in order to regenerate them D21C11/0042
• CPC Class Codes: D21C 5/00 Other processes for obtaining cellulose, e.g. cooking cotton linters obtaining fibres for spinning D01C; Processes characterised by the choice of cellulose-containing starting materials
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A continuous process for treating a lignocellulosic feedstock is provided. This method comprises pretreating the lignocellulosic feedstock under pressure in a pretreatment reactor at a pH between about 0.4 and about 2.0. One or more than one soluble base is added to this pressurized, pretreated feedstock after it exits the pretreatment reactor to adjust the pretreated lignocellulosic feedstock to an intermediate pH of between about pH 2.5 to about pH 3.5. This pressurized, partially-neutralized feedstock is then further processed at the intermediate pH. This may include flashing one or more than one time at the intermediate pH. The pH of the pressurized, partially-neutralized feedstock may then be adjusted with one or more than one base to produce a neutralized feedstock having a pH between about 4 and about 6. Prior to adjusting the pH to between about 2.5 and about 3.5, the pressurized, pretreated feedstock truly be partially depressurized.

Claims

1. A continuous process for providing a processed lignocellulosic feedstock comprising the steps of:

a. pretreating a lignocellulosic feedstock at elevated pressure in a pretreatment reactor at a pH between about 0.4 and about 2.0 to produce a pressurized, pretreated lignocellulosic feedstock;

b. adding one or more than one soluble base to the pressurized, pretreated lignocellulosic feedstock after exit from the pretreatment reactor to adjust the pressurized, pretreated lignocellulosic feedstock to an intermediate pH of between about pH 2.5 and about pH 3.5 to produce a pressurized, partially-neutralized feedstock; and

c. further processing the pressurized, partially-neutralized feedstock at the intermediate pH to produce the processed lignocellulosic feedstock.

2. The process of claim 1, wherein the step of further processing (step c.) comprises, flashing or venting the pressurized, partially-neutralized feedstock.

3. The process of claim 1, wherein the step of pretreating (step a.) is performed at a pressure between about 50 and about 700 psig.

4. The process of claim 3, wherein the step of pretreating (step a.) is performed at a pressure between about 75 and about 600 psig.

5. The process of claim 1, wherein, prior to the step of adding (step b.) and after the step of pretreating (step a.), the pressurized, pretreated feedstock is partially depressurized.

6. The process of claim 1, wherein the step of pretreating (step a.) comprises pumping the lignocellulosic feedstock through the pretreatment reactor and heating the lignocellulosic feedstock to a temperature between about 160°

C. and about 280°

C. with steam for a time sufficient to hydrolyze at least a portion of hemicellulose in the feedstock to produce a sugar monomer selected from the group consisting of xylose, arabinose, mannose, galactose and a combination thereof and a portion of cellulose in the feedstock to produce glucose.

8. The process of claim 1, wherein, prior to the step of pretreating (step a.), the lignocellulosic feedstock is slurried to produce a feedstock slurry having a solids content of about 4-32% (w/w).

9. The process of claim 8, wherein the feedstock slurry is prepared in water.

10. The process of claim 8, wherein the feedstock slurry is prepared in a mixture of water and a liquid that is immiscible or miscible with water.

7. A continuous process for treating a lignocellulosic feedstock comprising the steps of:

a. pretreating the lignocellulosic feedstock at elevated pressure in a pretreatment reactor at a pH between about 0.4 and about 2.0 to produce a pressurized, pretreated feedstock;

b. adding one or more than one soluble base to the pressurized, pretreated feedstock after exit from the pretreatment reactor to adjust the pressurized, pretreated feedstock to an intermediate pH of between about pH 2.5 and about pH 3.5 to produce a pressurized, partially-neutralized feedstock;

c. flashing the pressurized, partially-neutralized feedstock one or more than one time at the intermediate pH to produce a flashed feedstock; and

d. adjusting the pH of the flashed feedstock with one or more than one base to produce a neutralized feedstock having a pH between about 4 and about 6.

11. The process of claim 7, wherein the step of pretreating (step a.) is performed at a pressure between about 50 and about 700 psig.

12. The process of claim 11, wherein the step of pretreating (step a.) is performed at a pressure between about 75 and about 600 psig.

13. The process of claim 7, wherein, prior to the step of adding (step b.) and after the step of pretreating (step a.), the pressurized, pretreated feedstock is partially depressurized.

14. The process of claim 13, wherein the pressurized, pretreated feedstock is partially depressurized by one or more than one flashing step.

15. The process of claim 7, wherein the step of pretreating (step a.) comprises pumping the lignocellulosic feedstock through the pretreatment reactor and heating the lignocellulosic feedstock to a temperature between about 160°

C. and about 280°

C. with steam for a time sufficient to hydrolyze at least a portion of cellulose in the feedstock to produce glucose and at least a portion of hemicellulose in the feedstock to produce a sugar monomer selected from the group consisting of xylose, arabinose, mannose, galactose and a combination thereof.

16. The process of claim 7, wherein, prior to the step of pretreating (step a.), one or more than one acid selected from the group consisting of sulfuric acid, sulfurous acid, sulfur dioxide and a mixture thereof is added to the lignocellulosic feedstock.

17. The process of claim 16, wherein the acid is sulfuric acid.

18. The process of claim 7, wherein, in the step of flashing (step c.), the steam is flashed to produce flashed steam, and a portion of the flashed steam is recovered.

19. The process of claim 7, wherein, in the step of adjusting (step d), the pH of the neutralized feedstock is adjusted to between about pH 4.0 and about pH 5.5.

20. The process of claim 19, wherein the pH of the neutralized feedstock is adjusted to between about pH 4.5 and about pH 5.5.

21. The process of claim 7, wherein, in the step of adding (step b.), the one or more than one soluble base is selected from the group consisting of ammonia, ammonium hydroxide, potassium hydroxide, sodium hydroxide, potassium carbonate, potassium bicarbonate, sodium carbonate, sodium bicarbonate and a mixture thereof.

22. The process of claim 21, wherein, in the step of adding (step b.), the one or more than one soluble base is selected from the group consisting of ammonia, ammonium hydroxide and sodium hydroxide.

23. The process of claim 22, wherein, in the step of adding (step b.), the one or more than one base is ammonia.

24. The process of claim 7, wherein, in the step of flashing (step c.), the flashed feedstock is at a temperature of between about 40°

C. and about 125°

C.

25. The process of claim 24, wherein the flashed feedstock is at a temperature of between about 40°

C. and about 100°

C.

26. The process of claim 25, wherein the flashed feedstock is at a temperature of between about 50°

C. and about 90°

C.

27. The process of claim 7, wherein, in the step of adjusting (step d.), the one or more than one base is selected from the group consisting of ammonia, ammonium hydroxide, lime, calcium hydroxide, potassium hydroxide, magnesium hydroxide, sodium hydroxide, potassium carbonate, potassium bicarbonate, sodium carbonate, sodium bicarbonate and a mixture thereof.

28. The process of claim 7, wherein, in the step of adjusting (step d.), the one or more than one base is a soluble base.

29. The process of claim 27, wherein, in the step of adjusting (step d.), the one or more than one base is selected from the group consisting of ammonia, ammonium hydroxide and sodium hydroxide.

30. The process of claim 7, wherein the lignocellulosic feedstock is selected from the group consisting of wheat straw, barley straw, corn stover, soybean stover, canola straw, oat straw, rice straw, switch grass, cord grass, miscanthus and reed canary grass.

31. The process of claim 7, further comprising the steps of

e. enzymatically hydrolyzing the neutralized feedstock produced in step d. to produce a sugar stream;

and

f. fermenting the sugar stream to produce ethanol.