System and method for sensing and analyzing gases

• US 7,763,208 B2
• Filed: 11/01/2004
• Issued: 07/27/2010
• Est. Priority Date: 11/12/2003
• Status: Expired due to Fees

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Betsill, Harry Edwards, Steichen, John Carl
• Primary Examiner(s): Griffin; Walter D
• Assistant Examiner(s): Ramdhanie; Bobby
• Application Number:
  US10/978,773
• Publication Number:
  US 20070202012A1
• Time in Patent Office: 2,094 Days
• Field of Search: 422/88
• US Class Current: 422/88
• CPC Class Codes: G01N 33/0031 comprising two or more sensors, e.g. a sensor array electrochemical electrode arrays G01N27/27

Abstract

Disclosed herein is a device and method for converting the resistances of an array of metal oxide sensors into digital signals, wherein the sensors respond to the concentration of gases surrounding the sensor array. The device includes an electronic excitation device that provides an excitation voltage to the sensors; analog-to-digital signal conversion devices that convert the resistances of the sensors to digital signals; and means for calculating gas concentrations from the digital signals.

Claims

1. A device for converting the resistances of an array of N number of metal oxide sensors into digital signals, wherein the sensors respond to the concentration of gases surrounding the sensor array, comprising

(a) an electronic excitation source that provides an excitation voltage to each sensor and to a reference resistor associated with that sensor;

(b) an operational amplifier pair associated with each sensor/resistor pair to output to a comparator pair signals related to the resistance of the sensor and of the resistor; and

(c) a microcontroller having multiple inputs that receives on an input pair signals that are output by a comparator pair, wherein the microcontroller measures as a digital signal the time required for each comparator to change state after a trigger signal.

2. The device of claim 1, wherein the electronic excitation device provides an excitation voltage comprising a short pulse to each sensor, the pulse being applied for less than 10% of the measurement time for each sensor.

3. The device of claim 1, wherein the electronic excitation device provides an excitation voltage comprising a constant direct current voltage.

4. The device of claim 1, wherein the resistance of each sensor is converted to a digital number representing the ratio of the sensor resistance to the resistance of the reference resistor.

5. The device of claim 1, wherein the resistance of each sensor is converted to a digital number representing the log of the ratio of the sensor resistance to the resistance of the reference resistor.

6. The device of claim 1, wherein the resistance of each sensor is converted to a digital number representing the numerical log of the sensor resistance.

7. The device of claim 1, wherein the resistance of each sensor is converted to a digital number representing the reciprocal of the sensor resistance.

8. The device of claim 1, wherein the sensor array is contained in a housing that includes a cable for connecting the array to the device and an information storage device so that information about the calibration of the sensor array is included in one of the housing or the cable.

9. The device of claim 1, wherein the sensors are arrayed on one surface of a strip of electrically insulating material and a heater is aligned with the array on the other side of the electrically insulating strip, and wherein the temperature of the heater is controlled with a temperature control circuit.

10. The device of claim 9, wherein the heater is comprised of two dissimilar metals forming a thermocouple near the array, the heater being a source of heat and simultaneously a temperature measurement point for the temperature control circuit.

11. The device of claim 9, wherein two sensing conductors are attached to opposite ends of a heat-generating section of the heater to form heat sensing leads of a four-wire resistance measuring circuit.

12. The device of claim 9, wherein one of the sensors is a thermistor that is a control point for the temperature control circuit and a variable in the determination of gas concentrations.

13. The device of claim 9, wherein the control point temperature is calculated from the sensor resistances.

27. The device of claim 1 further comprising means for calculating gas concentrations from the digital signals.

28. The device of claim 1 wherein an operational amplifier pair outputs signals related to the log of the resistance of the sensor and of the resistor, and/or the trigger signal is related to the charging of a capacitor.

29. The device of claim 1 wherein the electronic excitation source provides an excitation voltage to the sensors that periodically reverses polarity.

14. A method for converting the resistances of an array of metal oxide sensors into digital signals, wherein the sensors respond to the concentration of gases surrounding the sensor array, comprising

(a) performing an electronic excitation voltage to each sensor and to a reference resistor associated with that sensor;

(b) outputting from an operational amplifier pair associated with each sensor/resistor pair to a comparator pair signals related to the resistance of the sensor and of the resistor; and

(c) receiving on an input pair of a microcontroller having multiple inputs signals as output by a comparator pair, wherein the microcontroller measures as a digital signal the time required for each comparator to change state after a trigger signal.

15. The method of claim 14, wherein the electronic excitation step comprises providing an excitation voltage comprising a short pulse to each sensor, the pulse being applied for less than 10% of the measurement time for each sensor.

16. The method of claim 14, wherein the electronic excitation step comprises providing an excitation voltage comprising a constant direct current voltage.

17. The method of claim 14, wherein the resistance of each sensor is converted to a digital number representing the ratio of the sensor resistance to the resistance of the reference resistor.

18. The method of claim 14, wherein the resistance of each sensor is converted to a digital number representing the log of the ratio of the sensor resistance to the resistance of the reference resistor.

19. The method of claim 14, wherein the resistance of each sensor is converted to a digital number representing the numerical log of the sensor resistance.

20. The method of claim 14, wherein the resistance of each sensor is converted to a digital number representing the reciprocal of the sensor resistance.

21. The method of claim 14, further comprising providing a housing that contains the sensor array and includes a cable for connecting the array to the device and an information storage device so that information about the calibration of the sensor array is included in one of the housing or the cable.

22. The method of claim 14, further comprising:

arraying the sensors on one surface of a strip of electrically insulating material;

aligning a heater with the array on the other side of the electrically insulating strip; and

controlling the temperature of the heater with a temperature control circuit.

23. The method of claim 22, wherein the heater is comprised of two dissimilar metals forming a thermocouple near the array, the heater being a source of heat and simultaneously a temperature measurement point for the temperature control circuit.

24. The method of claim 22, further comprising:

attaching two sensing conductors to opposite ends of a heat-generating section of the heater to form heat sensing leads of a four-wire resistance measuring circuit.

25. The method of claim 22, wherein one of the sensors is a thermistor that is a control point for the temperature control circuit and a variable in the determination of gas concentrations.

26. The method of claim 14, further comprising:

arraying a first plurality of sensors on a surface of an electrically insulating material;

arraying a second plurality of sensors on another surface of the electrically insulating material;

aligning a heater within the electrically insulating material, between the sensor arrays; and

controlling the temperature of the heater with a temperature control circuit.

30. The method of claim 14 further comprising a step of calculating gas concentrations from the digital signals.