Regeneration of ion exchangers that are used for salt removal from acid gas capture plants

• US 7,776,296 B2
• Filed: 03/10/2006
• Issued: 08/17/2010
• Est. Priority Date: 03/10/2006
• Status: Active Grant

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Cansolv Technologies Inc. (Shell Plc)
• Inventors: Sarlis, John Nicolas
• Primary Examiner(s): Mulcahy; Peter D.
• Assistant Examiner(s): HU, HENRY S
• Application Number:
  US11/371,924
• Publication Number:
  US 20070213415A1
• Time in Patent Office: 1,621 Days
• Field of Search: 423/229, 423/226, 423/228, 423/230, 423/242.7, 210/669, 55/73
• US Class Current: 423/229
• CPC Class Codes: B01D 53/1425 Regeneration of liquid absorbents
• CPC Class Codes: B01D 53/1456 Removing acid components
• CPC Class Codes: B01J 49/60 Cleaning or rinsing ion-exchange beds

Abstract

A process for the removal of an amine capturable gas from a feed gas stream using an amine solvent, the process comprises (a) contacting the feed gas stream with a lean amine solvent to form a rich amine solvent, wherein heat stable salts are present in the rich amine solvent; (b) stripping amine capturable gas from the rich amine solvent to form the lean amine solvent and an overhead reflux stream; (c) periodically contacting at least a portion of one or both of the lean amine solvent and the rich amine solvent with an anion exchange resin to form a first heat stable salt lean amine solvent; (d) periodically regenerating the anion exchange resin, wherein during the regeneration of the anion exchange resin, at least a portion of the reflux stream is used to wash the amine solvent from the anion exchange resin to produce a second heat stable salt lean amine solvent; and, (e) recycling at least a portion of the first and the second heat stable salt lean amine solvent for use in capturing the amine capturable gas from the feed gas.

Claims

1. A process for regenerating an ion exchange resin comprising:

(a) obtaining a solvent solution containing heat stable salts from an amine treater process;

(b) contacting the solvent solution with an anion exchange resin to obtain a heat stable salt lean solvent solution;

(c) periodically regenerating the anion exchange resin, wherein prior to the regeneration of the anion exchange resin, the anion exchange resin is washed with at least a portion of a reflux stream from the amine treater process to produce a heat stable salt lean amine stream; and

,

(d) recycling the heat stable salt lean amine to the amine treater process.

2. The method of claim 1 wherein the amine treater process treats a feed gas to remove one or more of SO₂, H₂S and CO₂.

3. The method of claim 1 wherein during step (c):

the anion exchange resin is contacted with the at least a portion of the reflux stream to wash amine solvent from the anion exchange resin;

the anion exchange resin is subsequently contacted with a regeneration agent to obtain regenerated anion exchange resin and spent regeneration agent solution; and

,

the anion exchange resin is washed with water to remove the regeneration agent therefrom and to obtain a regeneration agent wash effluent.

4. The method of claim 3 further comprising washing the regenerated anion exchange resin with water to remove the regeneration agent therefrom prior to using the regenerated anion exchange resin in step (b) of claim 1 wherein at least a portion of the water is obtained from the reflux stream.

5. The method of claim 3 further comprising:

subjecting a feed gas stream provided to the amine treater process to a pre-scrubbing operation;

using all or a portion of one or both of the spent regeneration agent solution and the regeneration agent wash effluent in the pre-scrubbing operation.

6. The method of claim 3 further comprising draining amine solvent from the anion exchange resin prior to contacting the anion exchange resin with water to wash amine solvent from the anion exchange resin.

7. The method of claim 1 wherein the heat stable salt lean amine is recycled to the amine treater process.

8. The method of claim 1 wherein the reflux is utilized without dilution to wash the amine solvent from the anion exchange resin.

9. The method of claim 1 wherein the amine treater process comprises:

contacting a feed gas stream comprising an amine capturable gas with a lean amine solvent to form a rich amine solvent, wherein heat stable salts are present in the rich amine solvent;

stripping amine capturable gas from the rich amine solvent to form the lean amine solvent and an overhead reflux stream; and

,

periodically using at least a portion of one or both of the lean amine solvent and the rich amine solvent as the solvent solution;

and the method further comprises selecting the lean amine solvent as the solvent solution that is contacted with the anion exchange resin.

10. The method of claim 1 further comprising selecting the solvent solution to comprise an amine solvent, which has an amine with a pKa in the range 2.5-6.

11. The method of claim 10 further comprising selecting SO₂ as an amine capturable gas to be captured by the amine treater process.

12. The process of claim 1 further comprising selecting the solvent solution to comprise an amine solvent, which has an amine with a pKa in the range 7.5-10.

13. The method of claim 12 further comprising selecting one or more of H₂S and CO₂ as an amine capturable gas to be captured by the amine treater process.

14. The method of claim 1 wherein the amine treater process comprises:

(a) contacting a feed gas stream comprising an amine capturable gas with a lean amine solvent to form a rich amine solvent, wherein heat stable salts are present in the rich amine solvent;

(b) stripping amine capturable gas from the rich amine solvent to form the lean amine solvent and an overhead reflux stream; and

,

(c) periodically using at least a portion of one or both of the lean amine solvent and the rich amine solvent as the solvent solution;

and the method further comprises recycling the heat stable salt lean amine to step 31(a).

15. The method of claim 1 wherein the amine treater process comprises:

(a) contacting a feed gas stream comprising an amine capturable gas with a lean amine solvent to form a rich amine solvent, wherein heat stable salts are present in the rich amine solvent;

(b) stripping amine capturable gas from the rich amine solvent to form the lean amine solvent and an overhead reflux stream; and

,

(c) periodically using at least a portion of one or both of the lean amine solvent and the rich amine solvent as the solvent solution;

and the method further comprises recycling the heat stable salt lean amine to step 32(b).

16. The method of claim 15 further comprising selecting SO₂ as the amine capturable gas.