Delivery device comprising gas diffuser for thin film deposition

• US 7,789,961 B2
• Filed: 01/08/2007
• Issued: 09/07/2010
• Est. Priority Date: 01/08/2007
• Status: Active Grant

• Current Assignee: Eastman Kodak Company
• Original Assignee: Eastman Kodak Company
• Inventors: Kerr, Roger S., Nelson, Shelby F., Levy, David H.
• Primary Examiner(s): Zervigon; Rudy
• Application Number:
  US11/620,740
• Publication Number:
  US 20080166884A1
• Time in Patent Office: 1,338 Days
• Field of Search: 118/715, 118/718, 118/729, 156/345.29, 156/345.33, 156/345.34, 156/345.54
• US Class Current: 118/715
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing
• CPC Class Codes: C23C 16/4412 Details relating to the exhausts, e.g. pumps, filters, scrubbers, particle traps
• CPC Class Codes: C23C 16/45517 Confinement of gases to vicinity of substrate
• CPC Class Codes: C23C 16/45519 Inert gas curtains
• CPC Class Codes: C23C 16/45551 for relative movement of the substrate and the gas injectors or half-reaction reactor compartments
• CPC Class Codes: C23C 16/45559 Diffusion of reactive gas to substrate
• CPC Class Codes: C23C 16/45568 Porous nozzles
• CPC Class Codes: C23C 16/45574 Nozzles for more than one gas
• CPC Class Codes: C23C 16/54 Apparatus specially adapted for continuous coating

Abstract

A process for depositing a thin film material on a substrate is disclosed, comprising simultaneously directing a series of gas flows from the output face of a delivery head of a thin film deposition system toward the surface of a substrate, and wherein the series of gas flows comprises at least a first reactive gaseous material, an inert purge gas, and a second reactive gaseous material, wherein the first reactive gaseous material is capable of reacting with a substrate surface treated with the second reactive gaseous material. A system capable of carrying out such a process is also disclosed.

Claims

1. A delivery device for thin-film material deposition onto a substrate comprising:

(a) a plurality of inlet ports comprising at least a first inlet port, a second inlet port, and a third inlet port capable of receiving a common supply for a first gaseous material, a second gaseous material, and a third gaseous material, respectively;

(b) at least one exhaust port capable of receiving exhaust gas from thin-film material deposition and at least two elongated exhaust channels, each of the elongated exhaust channels capable of gaseous fluid communication with the at least one exhaust port;

(c) at least three groups of elongated emissive channels, (i) a first group comprising one or more first elongated emissive channels, (ii) a second group comprising one or more second elongated emissive channels, and (iii) a third group comprising at least two third elongated emissive channels, each of the first, second, and third elongated emissive channels capable of gaseous fluid communication, respectively unmixed, with one of the corresponding first inlet port, second inlet port, and third inlet port;

wherein each of the first, second, and third elongated emissive channels and each of the elongated exhaust channels extend in a length direction substantially in parallel;

wherein each first elongated emissive channel is separated on at least one elongated side thereof from a nearest second elongated emissive channel by a relatively nearer elongated exhaust channel and a relatively less near third elongated emissive channel;

wherein each first elongated emissive channel and each second elongated emissive channel is situated between relatively nearer elongated exhaust channels and between relatively less nearer elongated emissive channels;

(d) a gas diffuser associated with at least one group of the three groups of elongated emissive channels such that at least one of the first, second, and third gaseous material, respectively, is capable of passing through the gas diffuser prior to delivery from the delivery device to the substrate, during thin-film material deposition onto the substrate, and wherein the gas diffuser maintains flow isolation of the at least one of first, second, and third gaseous material downstream from each of the elongated emissive channels in the at least one group of elongated emissive channels;

wherein the gas diffuser is capable of providing a friction factor that is greater than 1×

10², assuming a representative gas that is nitrogen at 25°

C. and a representative average velocity between 0.01 and 0.5 m/sec of gaseous material passing through the gas diffuser.

2. The delivery device of claim 1 wherein the gas diffuser is associated with each of the three groups of elongated emissive channels such that each of the first, second, and third gaseous material, respectively, is capable of separately passing from the delivery device to the substrate during thin-film material deposition on the substrate, and wherein the gas diffuser maintains flow isolation of each of first, second, and third gaseous material downstream from each of the elongated emissive channels in the three groups of elongated emissive channels.

3. The delivery device of claim 2 wherein the gas diffuser is a mechanical assembly housing separate flow paths associated with each of the first elongated emissive channels, separate flow paths associated with each of the second elongated emissive channels, and separate flow paths associated with each of the third elongated emissive channels.

4. The delivery device of claim 1 wherein the gas diffuser occupies at least a portion of each of the individual elongated emissive channels in the at least one of the three groups of elongated emissive channels.

5. The delivery device of claim 1 wherein the gas diffuser element is capable of providing a friction factor that is between 1×

10⁴ to 1×

10⁸.

6. The delivery device of claim 1 wherein there are at least two second elongated emissive channels and wherein each first elongated emissive channel is separated on both elongated sides thereof from the nearest second elongated emissive channel by a relatively nearer elongated exhaust channel and a relatively less near third elongated emissive channel.

7. The delivery device of claim 1 wherein there are a plurality of second elongated emissive channels and a plurality of first elongated emissive channels;

wherein each first elongated emissive channel is separated on both elongated sides thereof from the nearest second elongated emissive channel by a relatively nearer elongated exhaust channel and a relatively less near third elongated emissive channel; and

wherein each second elongated emissive channel is separated on both elongated sides thereof from the nearest first elongated emissive channel by a relatively nearer elongated exhaust channel and a relatively less near third elongated emissive channel.

8. The delivery device of claim 7 wherein the delivery device comprises an additional first or second elongated emissive channel at each of two ends of the delivery head that does not have, on one side thereof, a second or first elongated emissive channel, respectively, on the side closest to an edge of an output face of the delivery device.

9. The delivery device of claim 2 wherein the gas diffuser is a unit that is designed to be separable from a delivery assembly, comprising the rest of the delivery device, and that substantially covers the most downstream flow passages of the delivery assembly for the first, second, and third gaseous material.

10. The delivery device of claim 1 wherein the gas diffuser is designed to be an inseparable part of the delivery device.

11. The delivery device of claim 1 wherein the gas diffuser comprises a mechanically formed assembly comprising interconnected openings in at least two elements, thereby providing the required friction factor.

12. The delivery device of claim 11 wherein the at least two elements are steel, and the interconnected openings are formed by molding, mechanical machining, or laser or lithographic techniques.

13. The delivery device of claim 2 wherein for each individual first, second, and third elongated emissive channel, the gas diffuser comprises at least two vertically overlying passages, respectively, in at least two vertically arranged gas-diffuser plates, in combination providing a flow path for gaseous material that comprises two substantially vertical flow paths separated by a substantially horizontal flow path, wherein the substantially vertical flow path is provided by passages, or components of passages, extending in an elongated direction parallel to corresponding elongated emissive channels, and wherein the substantially horizontal flow path is provided by a relatively thin space between parallel surface areas in parallel gas diffuser plates, wherein vertical refers to the orthogonal direction with respect to an output face of the delivery device.

14. The delivery device of claim 13 wherein the at least two vertically arranged gas diffuser plates have substantially horizontally extending surfaces on each side and form substantially flat, stacked apertured plates.

15. The delivery device of claim 13 wherein the gas diffuser comprises at least three vertically overlying sets of passages, respectively, in at least three vertically arranged gas diffuser plates, wherein the relatively thin space is defined by a thickness of a central gas diffuser plate situated between two substantially parallel gas diffuser plates.

16. The delivery device of claim 1 wherein the gas diffuser is a multilevel system comprising a series of at least three substantially horizontally extending gas diffuser plates with substantially parallel surfaces facing each other in an orthogonal direction with respect to an output face of the delivery device, each of said gas diffuser plates having a plurality of flow passages each in gaseous communication with one of the individual elongated emissive channels among the first, second, and third elongated emissive channels;

wherein the plurality of passages in at least two of the gas diffuser plates, a sequential first and third diffuser plate, extends in an elongated direction, and wherein the each of the plurality of passages in the first gas diffuser plate is horizontally offset, in a direction perpendicular to the length of the elongated direction, with respect to the each of the plurality of passages in the third diffuser plates that is in gaseous fluid communication therewith;

wherein a sequentially second gas diffuser plate positioned between the first and third diffuser plate comprises a plurality of elongated center openings each of which is relatively broader than the width of the corresponding passages in flow communication thereof in each of the first and the third second diffuser plates, such that each elongated center opening is defined by two elongated sides and from the vertical direction contains within its borders the horizontally offset passages, of the first diffuser component and the third diffuser plate, in flow communication therewith; and

whereby the gas diffuser is capable of substantially deflecting flow of gaseous material passing therethrough.

17. The delivery device of claim 11 wherein the gas diffuser unit is capable of deflecting flow at an angle of 45 to 135 degrees, such that orthogonal flow is changed to a parallel flow with respect to a surface of an output face of the delivery device.

18. The delivery device of claim 11 wherein the gas diffuser sequentially provides (i) flow of gaseous material substantially vertical through the one or more passages, or components of passages in the at least two elements, and (ii) flow of gaseous material substantially horizontally in a narrow space formed between substantially parallel surface areas of the at least two elements, wherein the narrow space in vertical cross-section forms an elongated channel parallel to an associated elongated emissive channel, wherein vertical means perpendicular with respect to an output face of the delivery device and horizontal means parallel with respect to the output face of the delivery device.

19. The delivery device of claim 16 wherein the passages in the first gas diffuser plate comprises a plurality of individual sets of perforations extending along an elongated line, wherein each individual set of perforations is in gaseous flow communication with one of the passages in the second gas diffuser plate.

20. The delivery device of claim 1 wherein each of the elongated emissive channels in at least one group of the three groups of elongated emissive channels are designed to provide at least one of the first, second, and third gaseous material indirectly to the substrate after passing through a porous material that is either (i) within each individual emissive elongated channel among the at least one group of elongated emissive channels and/or (ii) upstream of each individual emissive elongated channel among the at least one group of elongated emissive channels.

21. The delivery device of claim 20 in which the porous material comprises pores that are formed by a chemical transformation or present in a naturally occurring porous material.

22. The delivery device of claim 21 wherein the porous material comprises pores that are less than 10,000 nm in average diameter, which volume is substantially available for flow of gaseous material.

23. The delivery device of claim 20 wherein the porous material comprises pores formed from the interstitial space between particles or pores that are interconnected voids in a solid material formed by a voiding agent.

24. The delivery device of claim 20 wherein the porous material is formed from microfibers.

25. The delivery device of claim 20 wherein the porous material comprises an isolating, non-connecting pores structure in which pores are substantially vertical to the surface.

26. The delivery device of claim 20 wherein the porous material is an alumina material made from anodized aluminum.

27. The delivery device of claim 20 wherein the porous material comprises one or more layers of different porous materials or a layer of porous material supported by a perforated sheet, which layers are optionally separated by spacer elements.

28. The delivery device of claim 20 wherein the porous material comprises a layer that is 5 to 1000 micrometers thick.

29. The delivery device of claim 20 wherein the porous material is formed from the interstitial space between inorganic or organic particles which is held together by bonding.

30. The delivery device of claim 20 wherein the porous material results from the processing of a polymer film to generate porosity.

31. The delivery device of claim 20 wherein the porous material is in the form of at least one horizontally disposed layer that covers the face of the delivery device.

32. The delivery device of claim 20 wherein the porous material forms a continuous layer, optionally with passages mechanically formed therein.

33. The delivery device of claim 32 wherein the mechanically formed openings are elongated channels for the relatively unimpeded flow of exhaust gaseous material back through the delivery device.

34. The delivery device of claim 20 wherein the layer of porous material is in the form of a substantially continuous plate in a stack of plates.

35. The delivery device of claim 20 wherein the gas diffuser is an assembly of elements in which porous material is held in separate confined areas.

36. The delivery device of claim 20 wherein the porous material is introduced or formed inside elongated channels, wherein the elongated channels are at least partially filled by the porous material.

37. The delivery device of claim 36 wherein the elongated channels are elongated channels in a steel plate in which particles are introduced and then sintered to form a gas diffuser element or portion thereof.

40. A deposition system wherein the delivery device of claim 1 is capable of providing thin film deposition of a solid material onto a substrate in a system in which a substantially uniform distance is maintained between an output face of the delivery head and the substrate surface during thin film deposition.

41. The deposition system of claim 40 wherein pressures generated due to flow of one or more of the gaseous materials from the delivery head to the substrate surface for thin film deposition provides at least part of the force separating the output face of the delivery head from the surface of the substrate.

42. The deposition system of claim 40 wherein a substrate support is a moving web and/or the substrate is a moving web.

43. The deposition system of claim 40 wherein the substrate support maintains the substrate surface at a separation distance of within 0.4 mm of the output face of the delivery head.

44. The deposition system of claim 42 wherein movement of the web provided by the transport apparatus is continuous, optionally reciprocating.

45. The deposition system of claim 40 wherein the substrate and the delivery head are open to the atmosphere.

46. The deposition system of claim 40 wherein gas flows are provided through substantially parallel elongated openings on the output face of the delivery head, which are substantially straight or substantially concentric.

47. The deposition system of claim 40 wherein the substantially uniform distance maintained between the output face of the delivery head and the substrate is less than 1 mm.

38. A delivery device for thin-film material deposition onto a substrate comprising:

(a) a plurality of inlet ports comprising at least a first inlet port, a second inlet port, and a third inlet port capable of receiving a common supply for a first gaseous material, a second gaseous material, and a third gaseous material, respectively;

(b) at least one exhaust port capable of receiving exhaust gas from thin-film material deposition and at least two elongated exhaust channels, each of the elongated exhaust channels capable of gaseous fluid communication with the at least one exhaust port;

(c) at least three groups of elongated emissive channels, (i) a first group comprising one or more first elongated emissive channels, (ii) a second group comprising one or more second elongated emissive channels, and (iii) a third group comprising at least two third elongated emissive channels, each of the first, second, and third elongated emissive channels capable of gaseous fluid communication, respectively unmixed, with one of the corresponding first inlet port, second inlet port, and third inlet port;

wherein each of the first, second, and third elongated emissive channels and each of the elongated exhaust channels extend in a length direction substantially in parallel;

wherein each first elongated emissive channel is separated on at least one elongated side thereof from a nearest second elongated emissive channel by a relatively nearer elongated exhaust channel and a relatively less near third elongated emissive channel;

wherein each first elongated emissive channel and each second elongated emissive channel is situated between relatively nearer elongated exhaust channels and between relatively less nearer elongated emissive channels;

(d) a gas diffuser associated with at least one group of the three groups of elongated emissive channels such that at least one of the first, second, and third gaseous material, respectively, is capable of passing through the gas diffuser prior to delivery from the delivery device to the substrate, during thin-film material deposition onto the substrate, and wherein the gas diffuser maintains flow isolation of the at least one of first, second, and third gaseous material downstream from each of the elongated emissive channels in the at least one group of elongated emissive channels;

wherein the gas diffuser comprises a porous material through which the at least one of the first, the second, and the third gaseous material passes.

39. A delivery device for thin-film material deposition onto a substrate comprising:

(a) a plurality of inlet ports comprising at least a first inlet port, a second inlet port, and a third inlet port capable of receiving a common supply for a first gaseous material, a second gaseous material, and a third gaseous material, respectively;

(b) at least one exhaust port capable of receiving exhaust gas from thin-film material deposition and at least two elongated exhaust channels, each of the elongated exhaust channels capable of gaseous fluid communication with the at least one exhaust port;

(c) at least three groups of elongated emissive channels, (i) a first group comprising one or more first elongated emissive channels, (ii) a second group comprising one or more second elongated emissive channels, and (iii) a third group comprising at least two third elongated emissive channels, each of the first, second, and third elongated emissive channels capable of gaseous fluid communication, respectively unmixed, with one of the corresponding first inlet port, second inlet port, and third inlet port;

wherein each of the first, second, and third elongated emissive channels and each of the elongated exhaust channels extend in a length direction substantially in parallel;

wherein each first elongated emissive channel is separated on at least one elongated side thereof from a nearest second elongated emissive channel by a relatively nearer elongated exhaust channel and a relatively less near third elongated emissive channel;

wherein each first elongated emissive channel and each second elongated emissive channel is situated between relatively nearer elongated exhaust channels and between relatively less nearer elongated emissive channels;

(d) a gas diffuser associated with at least one group of the three groups of elongated emissive channels such that at least one of the first, second, and third gaseous material, respectively, is capable of passing through the gas diffuser prior to delivery from the delivery device to the substrate, during thin-film material deposition onto the substrate, and wherein the gas diffuser maintains flow isolation of the at least one of first, second, and third gaseous material downstream from each of the elongated emissive channels in the at least one group of elongated emissive channels;

wherein the gas diffuser comprises a mechanically formed assembly comprising a series of at least two elements, each element comprising a substantially parallel surface area facing each other;

wherein at least one element comprises a plurality of perforations extending in an elongated direction, wherein each plurality of perforations is associated with the flow from one of the each elongated emissive channels in the at least one group of elongated emissive channels; and

wherein the gas diffuser deflects gaseous material passing from each of the plurality of perforations into a thin space between the parallel surface areas in the two elements.