Recycling of electrochemical-mechanical planarization (ECMP) slurries/electrolytes

• US 7,820,051 B2
• Filed: 02/23/2007
• Issued: 10/26/2010
• Est. Priority Date: 02/23/2007
• Status: Expired due to Fees

• Current Assignee: GlobalFoundries, Inc.
• Original Assignee: International Business Machines Corporation
• Inventors: Fang, Rui, Kulkarni, Deepak, Watts, David K.
• Primary Examiner(s): Drodge; Joseph W
• Application Number:
  US11/678,089
• Publication Number:
  US 20080233724A1
• Time in Patent Office: 1,341 Days
• Field of Search: 210/660, 210/663, 210/669, 210/670, 210/673, 210/677, 210/767, 210/787, 210/805, 210/806, 210/167.01, 210/167.31, 210/259, 210/263, 210/266, 210/335, 210/512.1, 210/683, 210/684, 210/688, 210/634, 210/638, 210/639, 438690-693, 438/584, 451/36, 451/41, 451/60, 451/65, 451/87, 451/88, 451/446, 204/224, 204/224.M, 204/554, 204/571, 204/600, 204/660, 204/665, 204/666, 205/640, 205/656, 205/674, 205/80, 205/86, 205/98
• US Class Current: 210/639
• CPC Class Codes: C22B 3/42 by ion-exchange extraction
• CPC Class Codes: C22B 7/006 Wet processes
• CPC Class Codes: Y02P 10/20 Recycling

Abstract

A method, process and system for the recycling of electrochemical-mechanical planarization slurries/electrolytes as they are used in the back end of line of the semiconductor wafer manufacturing process is disclosed. The method, process and system includes with the removal of metal ions from slurries using ion exchange media and/or electrochemical deposition.

Claims

1. A method of reclaiming a slurry comprising contacting an electrochemical-mechanical planarization slurry with an immiscible, non-aqueous phase acidic solvent and extracting metal ions from the slurry into said immiscible solvent to form a treated slurry for further use in an electrochemical mechanical planarization (ECMP) process.

2. The method according to claim 1, wherein the extracting the metal ions further comprises using an ionic exchange resin.

3. The method according to claim 2, further comprising replenishing the treated slurry with fresh slurry to maintain at least one of metal ions, additives and abrasive levels at specified levels.

4. The method according to claim 2, further comprising replenishing the treated slurry with a component of fresh slurry to maintain at least one of metal ions, additives and abrasive levels at specified levels.

5. The method according to claim 1, further comprising centrifuging used slurry to remove particles from the used slurry.

6. The method according to claim 1, wherein the extracting metal ions comprises:

mixing used slurry with the immiscible solvent for metal ions to form two phases; and

separating the two phases to extract the metal ions.

7. The method according to claim 6, wherein the extracting the metal ions further comprises electrochemically depositing the metal ions on a conductive cathode.

8. The method according to claim 6, further comprising replenishing the treated slurry with a component of fresh slurry to maintain at least one of the metal ions, additives and abrasive levels at specified levels.

9. The method according to claim 1, wherein the immiscible solvent comprises metal chelators.

10. The method according to claim 1, wherein the immiscible solvent comprises a diluent.

11. The method according to claim 1, further comprising treating the separated immiscible solvent with an aqueous acidic phase to remove the metal ions from the immiscible solvent phase into the aqueous acidic phase.

12. The method according to claim 1, wherein the extracting metal ions further comprises electrochemically depositing the metal ions on a conductive cathode.

13. The method according to claim 1, wherein the metal ions are separated from the slurry by an electrochemical reduction process.

14. The method according to claim 1, further comprising agitating or mixing the solvent and the immiscible solvent to accelerate the extraction of the metal ions.

15. The method according to claim 1, wherein used slurry and the immiscible solvent are a heterogeneous two phase system.

16. The method according to claim 15, wherein the two phases are mixed until the metal ion concentration in said slurry is below 50 ppm.

17. The method according to claim 15, wherein the two phases are mixed until the metal ion concentration in said slurry is less than 15 ppm.

18. The method according to claim 1, wherein the immiscible solvent is one of di-2-ethylhexyl phosphoric acid, benzyl alcohol and tri-butyl phosphate.