Anti-reflection film, production of anti-reflection film, and multi-layer film producing apparatus

• US 7,824,740 B2
• Filed: 03/21/2005
• Issued: 11/02/2010
• Est. Priority Date: 03/26/2004
• Status: Expired due to Fees

• Current Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Original Assignee: Fujifilm Corporation (Fujifilm Holdings Corporation)
• Inventors: Kawanishi, Naoyuki
• Primary Examiner(s): Cleveland; Michael
• Assistant Examiner(s): ROLLAND, ALEX A
• Application Number:
  US11/084,120
• Publication Number:
  US 20050214453A1
• Time in Patent Office: 2,052 Days
• Field of Search: 427/553, 427/595, 427/487, 427/508
• US Class Current: 427/508
• CPC Class Codes: B05D 2252/02 of indefinite length
• CPC Class Codes: B05D 3/0209 Multistage baking
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 7/04 to surfaces of films or sheets producing layered products by applying coatings of pasty or pulverulent plastics B29C41/00
• CPC Class Codes: C08J 2301/12 Cellulose acetate
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: C09D 133/14 of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
• CPC Class Codes: G02B 1/11 Anti-reflection coatings
• CPC Class Codes: G02B 1/12 by surface treatment, e.g. by irradiation

Abstract

A coater overlays actinic radiation curable composition on a long support in a liquid phase to constitute a coating layer. The actinic radiation curable composition includes polymerizable compound, and a first polymerization initiator for reacting upon ultraviolet radiation of a first wavelength range, and for rendering the coating layer semi-cured in first-stage curing. A second polymerization initiator reacts upon ultraviolet radiation of a broad wavelength range covering the first wavelength range, and completely cures the coating layer in second-stage curing after the first-stage curing, to obtain an anti-reflection layer. For the first-stage curing, optical filters are combined with an ultraviolet radiation source for the broad wavelength range, and cause transmission of radiation of the first wavelength range for reaction only upon the first polymerization initiator. In one embodiment, the optical filters are arranged in a web width direction of the long support.

Claims

1. An anti-reflection film producing method comprising:

a coating applying step of applying coating solution to a long support, said coating solution containing a polymerizable compound, and at least first and second polymerization initiators which absorb actinic radiation of wavelength ranges different from one another and generate a radical in response thereto;

an ultraviolet radiation curing step of, after drying a coating layer formed by said coating applying step to a reference dry state, applying ultraviolet radiation to said coating layer, to obtain an anti-reflection layer by ultraviolet curing of said polymerizable compound;

wherein said ultraviolet radiation curing step includes first processing and second processing subsequent to said first processing;

in said first processing, two or more optical filters having wavelength selectivity are arranged in a web width direction of said long support, for adjusting a deviation of an amount of ultraviolet radiation to said coating layer in said web width direction into a range equal to or more than 1% and equal to or less than 10% of an average amount, and in said first processing, said radical is generated from said first polymerization initiator, wherein in said second processing, said radical is generated from said second polymerization initiator.

2. An anti-reflection film producing method as defined in claim 1, wherein said optical filters are constructed to transmit ultraviolet radiation with a wavelength equal to or more than 200 nm and equal to or less than 350 nm at as low a transmittance as equal to or more than 0.5% and equal to or less than 10%.

3. An anti-reflection film producing method as defined in claim 1, wherein said optical filters prevent transmission of ultraviolet radiation with a wavelength equal to or more than 200 nm and equal to or less than 380 nm.

4. An anti-reflection film producing method as defined in claim 1, wherein said optical filters include any one of optical edge filter and a bandpass filter;

said optical edge filter includes a transparent support, and a thin film of inorganic material overlaid thereon by at least one of vacuum depositing, electron beam depositing, ion beam depositing, plasma depositing, and sputtering.

5. An anti-reflection film producing method as defined in claim 1, wherein said coating layer after said first processing and before said second processing has pencil hardness equal to or harder than B and equal to or less hard than HB, and said anti-reflection layer after said second processing has pencil hardness equal to or harder than 3H and equal to or less hard than 5H.

6. An anti-reflection film producing method as defined in claim 1, further comprising an embossing step of embossing by use of a surface processing device including an embosser, for imparting an antiglare property;

wherein said embossing step is between said first processing and said second processing.

7. An anti-reflection film producing method as defined in claim 1, wherein said coating layer comprises at least first and second coating layers;

overlaying said first coating layer on said long support is constituted by said coating applying step and said first processing in combination; and

overlaying said second coating layer on said first coating layer is constituted by said coating applying step and said first processing in combination, and is after said overlaying of said first coating layer.

8. An anti-reflection film producing method as defined in claim 1, wherein said optical filters have a shape obtained by chamfering away a small portion of one vertex of a triangle that is an approximately regular triangle, and constitute an array extending over a web width of said long support;

a first one of said optical filters has said chamfered portion directed upstream in a transporting direction of said long support, and a second one of said optical filters adjacent to said first has said chamfered portion directed downstream in said transporting direction.

9. An anti-reflection film producing method as defined in claim 1, wherein said first polymerization initiator is at least one selected from phosphine oxides, thioxantones, N-methyl acridones, ketones, and oximes;

said second polymerization initiator is at least one selected from aceto phenones, benzoins, benzophenones, ketals, and anthraquinones.

10. An anti-reflection film producing method as defined in claim 1, wherein in said first processing, an ultraviolet radiation source is used to generate said ultraviolet radiation;

content adjusting gas is supplied into an ultraviolet curing region of said coating layer of said long support opposed to said ultraviolet radiation source, for adjusting proportion of oxygen in said ultraviolet curing region.

11. An anti-reflection film producing method as defined in claim 10, wherein in said first processing, said ultraviolet radiation source is contained in a casing having an opening, and said optical filters are secured to said opening;

said content adjusting gas is blocked by a labyrinth structure in a peripheral region of said optical filters, and kept from escaping from said ultraviolet curing region.

12. An anti-reflection film producing method as defined in claim 11, wherein in said first processing, heat dissipating gas is circulated in said casing, to eliminate heat from said ultraviolet radiation source;

temperature of a back surface of said long support reverse to said coating layer is controlled by temperature control gas.

13. An anti-reflection film producing method as in claim 1, wherein the method is carried out on a multi-layer film producing apparatus comprising:

a coater for applying coating solution to a long support, said coating solution containing a polymerizable compound, and at least first and second polymerization initiators which absorb actinic radiation of wavelength ranges different from one another and generate a radical in response thereto;

a drier for drying a coating layer formed by said coater to a reference dry state;

an ultraviolet processor for applying ultraviolet radiation to said coating layer, to obtain an anti-reflection layer by ultraviolet curing of said polymerizable compound;

wherein said ultraviolet processor includes;

a first ultraviolet radiation source;

a second ultraviolet radiation source for applying ultraviolet radiation to said coating layer after processing with said first ultraviolet radiation source;

two or more optical filters, associated with said first ultraviolet radiation source, having wavelength selectivity for generating said radical from said first polymerization initiator, wherein said radical is generated from said second polymerization initiator by use of said second ultraviolet radiation source;

wherein said optical filters are arranged in a web width direction of said long support, for adjusting a deviation of an amount of ultraviolet radiation to said coating layer in said web width direction into a range equal to or more than 1% and equal to or less than 10% of an average amount,

said apparatus comprising a plurality of units, each of which is constituted by said coater, said drier and said first ultraviolet radiation source, and which form a plurality of said coating layer on said long support successively.

14. An anti-reflection film producing method as defined in claim 1, wherein said support has an optical transmittance of 80% or higher.

15. An anti-reflection film producing method as defined in claim 1, wherein said support has an optical transmittance of 86% or higher.

16. An anti-reflection film producing method as defined in claim 1, wherein said support comprises triacetyl cellulose.