Method and apparatus for increasing an intrinsic viscosity of polyester

• US 7,828,538 B2
• Filed: 10/15/2002
• Issued: 11/09/2010
• Est. Priority Date: 10/29/2001
• Status: Active Grant

• Current Assignee: Markus Fellinger
• Original Assignee: Markus Fellinger
• Inventors: Fellinger, Markus
• Primary Examiner(s): Gupta; Yogendra N
• Assistant Examiner(s): Leyson; Joseph
• Application Number:
  US10/494,012
• Publication Number:
  US 20050062186A1
• Time in Patent Office: 2,947 Days
• Field of Search: 425/67, 425/68, 425/70, 425/203, 425/310, 425/311, 425/313, 425/315, 425/316, 425/377, 425/404, 425/445
• US Class Current: 425/67
• CPC Class Codes: B29B 13/021 Heat treatment of powders
• CPC Class Codes: B29B 2009/165 Crystallizing granules
• CPC Class Codes: B29B 9/16 Auxiliary treatment of granules
• CPC Class Codes: B29K 2067/00 Use of polyesters or derivatives thereof, as moulding material
• CPC Class Codes: B29K 2105/0094 having particular viscosity
• CPC Class Codes: C08G 63/785 characterised by the apparatus used
• CPC Class Codes: C08G 63/80 Solid-state polycondensation

Abstract

A method of increasing the intrinsic viscosity of polyester by means of solid state polymerization, wherein a polyester plastics melt is granulated and after granulation is conveyed into a thermal treatment container (13) for thermal treatment therein, the granules being produced slightly below their melting temperature and being fed into the thermal treatment container (13) immediately after granulation so as to utilize the residual heat in the granules, as well as an arrangement for increasing the intrinsic viscosity of polyester by means of solid state polymerization with a granulating and a thermal treatment unit, with an unheated, thermally insulated container (13) or a container (13) having wall heating means (15) being provided as the thermal treatment unit, which is directly connected to the granulating unit via a conveying device (11, 36, 37).

Claims

1. Apparatus for increasing the intrinsic viscosity of polyester by solid state polymerization comprising

a supply of heated polyester material including an extruder for producing strands of the material,

a polyester granulator having a chamber housing a cutter for cutting the polyester material strands received from the extruder into granules while subjecting the strands to a coolant to only surface-cool the strands to a strand temperature slightly below the melting temperature of the polyester,

a screening device directly bordering the chamber for separating the granules from the coolant so as to maintain the granules at a temperature only slightly below the melting temperature of the polyester by receiving polyester granules and coolant directly from the chamber,

a solid state polymerization-thermal treatment unit including a polymerization-thermal treatment container, and

a screw conveyor receiving granules at a temperature only slightly below the melting temperature of the polyester directly from the screening device for transporting the granules from the screening device directly into an interior of the container to thereby utilize residual heat in the granules received from the conveyor during a polymerization process of the granules conducted in the interior of the container.

2. The apparatus according to claim 1, wherein said thermal treatment container is an unheated container, a thermally insulated container, or a container with a wall heating device.

3. The apparatus according to claim 1, which comprises at least one mixing element in said container.

4. The apparatus according to claim 3, wherein said mixing element is a heatable mixing element.

5. The apparatus according to claim 1, wherein said thermal treatment container is filled with an inert gas.

6. The apparatus according to claim 1, wherein said cutting chamber is filled with a liquid having a higher boiling point than water at ambient pressure.

7. The apparatus according to claim 6, wherein said liquid is a water/glycol mixture.

8. The apparatus according to claim 1, wherein said cutting chamber is a pressure chamber.

9. The apparatus according to claim 1, wherein said conveyor is a thermally insulated device.

10. The apparatus according to claim 1, wherein said conveyor is a heatable device.

11. The apparatus according to claim 1, which comprises a pre-drying unit disposed upstream of said granulator in a conveying direction.

12. The apparatus according to claim 11, wherein said pre-drying unit is a vacuum dryer or a hot air dryer.

13. The apparatus according to claim 1, wherein the extruder includes at least one degassing zone disposed upstream of said granulator in a conveying direction, and said extruder is subject to vacuum pressure.

14. The apparatus according to claim 13, wherein the vacuum in said extruder is between substantially 1 mbar and substantially 40 mbar.

15. Apparatus according to claim 1 wherein the thermal treatment container comprises an interior space subjected to a vacuum and has a container top with an intake opening receiving the granules from the conveyor and an exit opening at a bottom of the container for discharging the granules, the exit opening being arranged below the intake opening so that the granules flow gravitationally from the intake opening to the exit opening.