Process for the manufacture of 1,3,3,3-tetrafluoropropene

• US 7,829,748 B1
• Filed: 09/21/2009
• Issued: 11/09/2010
• Est. Priority Date: 09/21/2009
• Status: Active Grant

• Current Assignee: Honeywell International Inc.
• Original Assignee: Honeywell International Inc.
• Inventors: Johnson, Robert C., Merkel, Daniel C., Wang, Haiyou, Tung, Hsuehsung
• Primary Examiner(s): Witherspoon; Sikarl A
• Application Number:
  US12/563,458
• Time in Patent Office: 414 Days
• Field of Search: 570/164, 570/170
• US Class Current: 570/164
• CPC Class Codes: B01J 21/18 Carbon
• CPC Class Codes: B01J 27/10 Chlorides
• CPC Class Codes: B01J 27/138 with alkaline earth metals, magnesium, beryllium, zinc, cadmium or mercury
• CPC Class Codes: C07C 17/087 to unsaturated halogenated hydrocarbons
• CPC Class Codes: C07C 17/21 with simultaneous increase of the number of halogen atoms
• CPC Class Codes: C07C 17/25 by splitting-off hydrogen halides from halogenated hydrocarbons
• CPC Class Codes: C07C 19/08 containing fluorine
• CPC Class Codes: C07C 19/10 and chlorine
• CPC Class Codes: C07C 21/18 containing fluorine

Abstract

The invention provides an economic process for the manufacture of 1,3,3,3-tetrafluoropropene (HFO-1234ze) by a two stage process. A vapor phase hydrofluorination of 1-chloro-3,3,3-trifluoropropene (HCFC-1233zd) into 1-chloro-1,3,3,3-tetrafluoropropane (HCFC-244fa) and/or 1,1,1,3,3-pentafluoropropane (HFC-245fa) is conducted, followed by the thermal dehydrochlorination of HCFC-244fa and dehydro fluorination of HFC-245fa into HFO-1234ze in the presence of a catalyst which comprises one or more of alkali metal halides, alkaline earth metal halides, halogenated metal oxides, zero oxidation state metals, zinc halides, palladium halides, and activated carbon.

Claims

1. A process for the manufacture of 1,3,3,3-tetrafluoropropene comprising:

a) reacting 1-chloro-3,3,3-trifluoropropene with hydrogen fluoride in a reactor in the vapor phase and in the presence of a fluorination catalyst and under conditions sufficient to form an intermediate product which comprises 1-chloro-1,3,3,3-tetrafluoropropane and/or 1,1,1,3,3-pentafluoropropane; and

b) thermally decomposing the intermediate product in the presence of a catalyst which comprises one or more of alkali metal halides, alkaline earth metal halides, halogenated metal oxides, zero oxidation state metals, zinc halides, palladium halides, cerium halides, yttrium halides, aluminum halides, and activated carbon, under conditions sufficient to dehydrochlorinate 1-chloro-1,3,3,3-tetrafluoropropane and/or to dehydrofluorinate 1,1,1,3,3-pentafluoropropane, forming 1,3,3,3-tetrafluoropropene.

2. The process of claim 1 wherein the intermediate product comprises 1-chloro-1,3,3,3-tetrafluoropropane.

3. The process of claim 1 wherein the intermediate product comprises 1,1,1,3,3-pentafluoropropane.

4. The process of claim 1 wherein the intermediate product comprises both 1-chloro-1,3,3,3-tetrafluoropropane and 1,1,1,3,3-pentafluoropropane.

5. The process of claim 1 which comprises reacting the trans isomer form of 1-chloro-3,3,3-trifluoropropene.

6. The process of claim 1 which comprises reacting the cis isomer form of 1-chloro-3,3,3-trifluoropropene.

7. The process of claim 1 which comprises reacting both the trans and cis isomer forms of 1-chloro-3,3,3-trifluoropropene.

8. The process of claim 1 wherein the dehydrochlorination of 1-chloro-1,3,3,3-tetrafluoropropane and the dehydro fluorination of 1,1,1,3,3-pentafluoro-propane are conducted simultaneously in the same reactor.

9. The process of claim 1 wherein step (a) is conducted at a temperature of from about 50°

C. to about and 200°

C.

10. The process of claim 1 wherein step (a) is conducted at a pressure of from about 15 psia to about 215 psia.

11. The process of claim 1 wherein in step (a) 1-chloro-3,3,3-trifluoropropene vapor and hydrogen fluoride vapor contact the fluorination catalyst for from about 0.01 to about 240 seconds.

12. The process of claim 1 wherein step (b) is conducted by first separating 1-chloro-1,3,3,3-tetrafluoropropane and 1,1,1,3,3-pentafluoropropane, and then separately dehydrochlorinating 1-chloro-1,3,3,3-tetrafluoropropane and separately dehydrofluorinating 1,1,1,3,3-pentafluoropropane.

13. The process of claim 1 wherein the fluorination catalyst is selected from the group consisting of transition metal halides, Group IVb metal halides, Group Vb metal halides and combinations thereof on activated carbon or fluorinated alumina.

14. The process of claim 1 wherein the catalyst in step (b) comprises one or more of supported or bulk metals, magnesium halides, calcium halides, lithium halides, sodium halides, potassium halides, cesium halides, cerium halides, yttrium halides, aluminum halides, halogenated magnesium oxides, halogenated calcium oxides, halogenated barium oxides, halogenated zinc oxides, halogenated cesium oxides halogenated aluminum oxides, and combinations thereof.

15. The process of claim 1 wherein the catalyst in step (b) comprises one or more of supported or bulk LiF, NaF, KF, CsF, MgF₂, CaF₂, LiCl, NaCl, KCl, CeF₄, FeF₃, YF₃, A1F₃, CsCl, MgO, CaO, BaO, ZnO, CsO, Al₂O₃, Pd, Pt, Rh, Fe, Co, Ni, Cu, Mo, Cr, and Mn.

16. The process of claim 1 wherein the catalyst in step (b) comprises a combination of CsCl and MgO, or a combination of CsCl and MgF₂.

17. The process of claim 16 wherein the catalyst in step (b) comprises from 5 to 25 wt % CsCl.

18. The process of claim 1 wherein the temperature for the thermal decomposition ranges from about 30°

C. to about 550°

C.

19. The process of claim 1 wherein the temperature for the thermal decomposition ranges from about 300°

C. to about 550°

C.

20. The process of claim 1 wherein the pressure for the thermal decomposition ranges from about 5 ton to about 760 torr.