Method for coating an ophthalmic lens within an injection molding machine

• US 7,833,442 B2
• Filed: 12/21/2005
• Issued: 11/16/2010
• Est. Priority Date: 12/21/2005
• Status: Active Grant

• Current Assignee: Essilor International SA
• Original Assignee: Essilor International SA
• Inventors: Chen, Xu, Yang, Hsinjin, Lockwood, Matthew
• Primary Examiner(s): Crispino; Richard
• Assistant Examiner(s): Bell; William P
• Application Number:
  US11/313,590
• Publication Number:
  US 20070138665A1
• Time in Patent Office: 1,791 Days
• Field of Search: 264/1.32, 264/1.7, 264/255, 264/40.5, 264/328.7, 264/328.8, 264/328.1, 264/2.2, 264/2.7, 425/135, 425/556, 425/565, 425/437, 524/430, 351/177, 351/163, 427/561, 427/162, 525/276
• US Class Current: 264/1.7
• CPC Class Codes: B29C 2045/0079 applying a coating or covering
• CPC Class Codes: B29C 45/0001 characterised by the choice of material
• CPC Class Codes: B29C 45/1679 applying surface layers onto injection-moulded substrates inside the mould cavity, e.g. in-mould coating [IMC] applying suface layers after ejection B29C45/0053
• CPC Class Codes: B29C 45/32 having several axially spaced mould cavities , i.e. for making several separated articles
• CPC Class Codes: B29D 11/00009 Production of simple or compound lenses
• CPC Class Codes: B29D 11/0048 Moulds for lenses moulds for plastic articles in general B29C33/00
• CPC Class Codes: B29D 11/00865 Applying coatings; tinting; colouring printing, marking or copying processes B41M; identification in general G09F3/00; producing decorative effects in general B44C; positioning or marking of lenses B24B13/0055
• CPC Class Codes: B29K 2995/0026 Transparent
• CPC Class Codes: B29L 2011/0016 Lenses
• CPC Class Codes: Y10S 425/808 Lens mold

Abstract

A method for in-mold coating of an injection molded thermoplastic lens that resides in an injection molding machine oriented to a horizontal parting line. An optical lens is initially formed by injecting molten thermoplastic resin into an edge-gated lens-forming cavity held closed under a primary clamp force. The mold is opened at a time when the lens is rigid enough to retain its shape. An unpressurized full metered charge of coating is applied onto the center of the lens. The coating is co-molded by ramping up the clamp force from zero to a secondary clamp force less than the primary clamp force to compress the coating into a uniformly thick, fringe-free layer.

Claims

1. A method for optically coating an injection molded thermoplastic lens that resides in an injection molding machine oriented to a horizontal parting line, comprising the steps of:

injecting molten thermoplastic resin into an edge-gated lens-forming cavity of an injection molding machine held closed under a primary clamp force;

opening the mold at a time when the lens is rigid enough to retain its shape;

depositing an unpressurized full metered charge of liquid coating onto the center of the lens; and

co-molding the coating by ramping up the clamp force from zero to a secondary clamp force not greater than the primary clamp force to compress the liquid coating into a uniformly thick, fringe-free layer within the same lens-forming cavity volume, wherein the liquid coating thermally cures from the heat of the solidifying lens and the injection mold to form an optically transparent coating.

2. The method of to claim 1, wherein the co-molding step includes reclamping the open mold to spread the coating radially-outwardly to a lens periphery within a surficial zone.

3. The method of to claim 2, wherein during said reclamping step, the coating is spread in the absence back pressure.

4. The method of to claim 1, wherein the co-molding step includes co-molding the coating to exactly replicate the part-forming surface without deforming the lens.

5. The method of claim 1, wherein said depositing step comprises applying a liquid coating in an open-air state.

6. The method according to claim 5, wherein the liquid coating includes one or more (meth)acrylate compounds, a catalyst, and a metal salt.

7. The method according to claim 6, wherein the liquid coating includes at least one hexafunctional acrylate compound, at least one difunctional acrylate compound, and at least one monofunctional acrylate compound.

8. The method according to claim 6, wherein the catalyst is selected from alkyl aralkyl peracide compounds.

9. The method according to claim 6, wherein the metal salt is Cobalt naphthenate.

10. The method according to claim 5, wherein the liquid coating has a reacted kick-off temperature near the molding temperature of the substrate lens.

11. The method of claim 1, wherein the mold opens and closes vertically.

12. The method of claim 1, wherein the primary clamp force is over 100 tons.

13. The method of claim 12, wherein the secondary clamp force is in the range from about 10% to about 90% of the primary clamp force.

14. The method of claim 1, wherein the primary clamp force is about 150 tons.

15. The method according to claim 1, wherein the full metered charge of coating is between 0.1 ml and 0.8 ml.

16. The method according to claim 1, wherein the full metered charge of coating is between 0.2 ml and 0.5 ml.

17. The method according to claim 1, wherein the thermoplastic resin is selected from the group consisting of polymethyl(meth)acrylate, polycarbonate, polycarbonate/polyester blends, polyamide, polyester, cyclic olefin copolymers, polyurethane, polysulfone and combinations thereof.

18. The method according to claim 17, wherein thermoplastic is a polycarbonate derivative.

19. The method according to claim 1, wherein said co-molding step includes curing the coating for about 2 minutes to 5 minutes.

20. The method of claim 1, wherein the edge-gated lens-forming cavity is one of an afocal lens forming cavity, a unifocal lens forming cavity, a bifocal straight-top lens forming cavity, a trifocal straight-top lens forming cavity, and a progressive lens forming cavity.

21. The method of claim 1, wherein following said co-molding step, the method further including the step of:

ejecting the lens from the mold after the coating has cured and the lens is capable of withstanding ejection forces without deforming.

22. The method of claim 1, wherein following said co-molding step, the method additionally including the step of:

further opening the mold at a time when the lens is rigid enough to retain its shape;

further depositing an unpressurized full metered charge of further coating onto the center of the lens; and

further co-molding the coating by ramping up the clamp force from zero to a secondary clamp force to compress the further coating into a further uniformly thick, fringe-free layer.

23. The method of claim 22, wherein the further deposited coating is the same as said deposited coating.

24. The method of claim 22, wherein the deposited coating is selected from the group consisting of photochromic coatings, anti-fog coatings, anti-static coatings, anti-scratch coatings, protective coatings, anti-reflective coatings, clear coatings, cosmetically tinted coatings and anti-smudge coatings.

25. The method of claim 22, wherein the further deposited coating is different from said deposited coating.

26. The method of claim 25, wherein the further deposited coating has a different optical function from said deposited coating to produce an in-mold multifunctional coated lens.

27. The method of claim 26, wherein the deposited coating and the further deposited coating are independently selected from the group consisting of photochromic coatings, anti-fog coatings, anti-static coatings, anti-scratch coatings, protective coatings, anti-reflective coatings, clear coatings, cosmetically tinted coatings and anti-smudge coatings.

28. The method of claim 22, wherein said steps of further opening, further depositing and further co-molding are repeated for the application of a third or higher layer of coatings.

29. A thermoplastic ophthalmic lens manufactured by the process of claim 1.