Aqueous dispersion of fine resin particles, method for producing aqueous dispersion of fine resin particles, and method for producing toner particles

• US 7,833,687 B2
• Filed: 10/06/2009
• Issued: 11/16/2010
• Est. Priority Date: 06/02/2008
• Status: Active Grant

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Natori, Ryo, Chimoto, Yuya, Shibata, Takaho, Miyazaki, Takeshi, Higashi, Ryuji, Toyoda, Takayuki, Kato, Masayoshi
• Primary Examiner(s): LE, HOA VAN
• Application Number:
  US12/574,217
• Publication Number:
  US 20100028794A1
• Time in Patent Office: 406 Days
• Field of Search: 524/458, 524/460, 524/461, 526/201, 526/203, 521/29, 430/137.1, 430/137.19
• US Class Current: 430/137.19
• CPC Class Codes: C08J 3/03 in aqueous media
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/0819 characterised by the dimensions of the particles
• CPC Class Codes: G03G 9/0827 characterised by their shape, e.g. degree of sphericity
• CPC Class Codes: G03G 9/08755 Polyesters
• CPC Class Codes: G03G 9/08791 characterised by the presence of specified groups or side chains
• CPC Class Codes: G03G 9/08797 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature

Abstract

The present invention provides an aqueous dispersion of nonspherical fine resin particles having excellent storage stability and processability such as aggregation and adherence to other substances, a method for producing the aqueous dispersion of fine resin particles, and a method for producing toner particles using the aqueous dispersion of fine resin particles. The present invention relates to an aqueous dispersion of fine resin particles characterized in that the fine resin particles are nonspherical particles with an average minor axis being 0.02 μm or more and 1.00 μm or less and an average ratio of a major axis to a minor axis being 2.0 or more and 5.0 or less, a method for producing the aqueous dispersion of fine resin particles, and a method for producing toner particles using the aqueous dispersion of fine resin particles.

Claims

1. An aqueous dispersion of fine resin particles comprising fine resin particles containing an acid group-containing resin and an aqueous medium, wherein the fine resin particles are nonspherical particles with an average minor axis being 0.02 μ

m or more and 1.00 μ

m or less and an average ratio of a major axis to a minor axis being 2.0 or more and 5.0 or less.

wherein a 50%-particle diameter based on volume distribution of the fine resin particles is 0.02 μ

m or more and 1.00 μ

m or less, and

wherein the acid group-containing resin is a polyester resin.

2. The aqueous dispersion of fine resin particles according to claim 1, wherein the 50%-particle diameter based on volume distribution of the fine resin particles is 0.02 μ

m or more and 0.40 μ

m or less.

3. The aqueous dispersion of fine resin particles according to claim 1, wherein a softening temperature (Tm) of the acid group-containing resin is 90°

C. or higher and 150°

C. or lower.

4. A method for producing an aqueous dispersion of fine resin particles comprising at least (1) mixing an aqueous medium, an acid group-containing resin, a basic substance, and a surfactant to obtain a mixture, (2) emulsifying the mixture by applying a shear force with heating the mixture at a temperature of 10°

C. or higher relative to a softening temperature (Tm) of the acid group-containing resin to form an emulsified mixture, and (3) cooling the emulsified mixture, wherein the cooling is done, with applying a shear force, at a cooling rate of 0.5°

C./minute or faster and 10°

C./minute or slower till a glass transition temperature (Tg) of the acid group-containing resin or lower, and the obtained aqueous dispersion of fine resin particles is the aqueous dispersion of fine resin particles according to claim 1.

5. The method for producing an aqueous dispersion of fine resin particles according to claim 4, wherein a mass ratio of the fine resin particles to the total mass of the aqueous medium and the fine resin particles (mass of the fine resin particles/total mass of the aqueous medium and the fine resin particles) is 0.20 or more and less than 0.60.

6. The method for producing an aqueous dispersion of fine resin particles according to claim 4, wherein the emulsification is done under conditions of 100°

C. or higher and 0.11 MPa or higher.

7. A method for producing toner particles comprising at least aggregating to form aggregates by mixing at least an aqueous dispersion of fine resin particles and a colorant thereby aggregating the fine resin particles and the colorant in an aqueous medium and fusing the aggregates by heating to obtain toner particles, characterized in that the aqueous dispersion of fine resin particles is the aqueous dispersion of fine resin particles according to claim 1.