OLED device having improved light output

• US 7,834,541 B2
• Filed: 10/05/2006
• Issued: 11/16/2010
• Est. Priority Date: 10/05/2006
• Status: Active Grant

• Current Assignee: Global OLED Technology LLC (LG Display Co., Ltd.)
• Original Assignee: Global OLED Technology LLC (LG Display Co., Ltd.)
• Inventors: Cok, Ronald S.
• Primary Examiner(s): Guharay; Karabi
• Application Number:
  US11/538,966
• Publication Number:
  US 20080084150A1
• Time in Patent Office: 1,503 Days
• Field of Search: 313/504, 313/506, 313/110, 313/512
• US Class Current: 313/504
• CPC Class Codes: B82Y 20/00 Nanooptics, e.g. quantum optics or photonic crystals
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: H10K 2102/331 Nanoparticles used in non-emissive layers, e.g. in packaging layer
• CPC Class Codes: H10K 50/854 comprising scattering means
• CPC Class Codes: H10K 50/865 comprising light absorbing layers, e.g. light-blocking layers
• CPC Class Codes: H10K 59/38 comprising colour filters or colour changing media [CCM]
• CPC Class Codes: H10K 59/877 comprising scattering means

Abstract

An organic light-emitting diode (OLED) device, comprising: a light-emitting area of an OLED comprising a first electrode, a second transparent electrode, and one or more layers of organic light-emitting material formed between the electrodes; and a light-scattering layer, formed on a side of the transparent electrode opposite the one or more layers of organic light-emitting material, comprising transparent, light-scattering particles, wherein the ratio of the volume of light-scattering particles to the volume of the layer is greater than 0.55 over a majority of the light-emitting area.

Claims

1. An organic light-emitting diode (OLED) device, comprising:

a light-emitting area of an OLED comprising a first electrode, a second transparent electrode, and one or more layers of organic light-emitting material formed between the electrodes; and

a light-scattering layer, formed on a side of the transparent electrode opposite the one or more layers of organic light-emitting material, comprising transparent, light-scattering particles having a refractive index greater than or equal to 1.8 formed in a cavity, wherein the ratio of the volume of light-scattering particles to the volume of the light scattering layer is within the range of 0.55 to 0.75 over a majority of the light-emitting area.

2. The OLED device of claim 1, wherein the light-scattering particles have a relatively higher index of refraction than the average index of the remaining volume of the light-scattering layer.

3. The OLED device of claim 1, wherein the light-scattering particles are non-spherical and randomly oriented.

4. The OLED device of claim 1, wherein no layers having an index of more than 0.1 less than that of the light-emitting material layer and a thickness sufficient to trap light are formed between the scattering layer and the light emitting material layer.

5. The OLED device of claim 1, wherein the light-scattering layer is in direct optical contact with the transparent electrode.

6. The OLED device of claim 1, wherein the majority of the light-scattering layer volume that is not occupied by light-scattering particles is occupied by a gas or vacuum.

7. The OLED device of claim 1, wherein the light-scattering layer further comprises a binder having a refractive optical index less than the refractive index of the light-scattering particles and having a weight less than 10% of the weight of the light-scattering particles.

8. The OLED device of claim 1, wherein the ratio of the volume of light-scattering particles to the volume of the layer is between 0.55 and 0.65.

9. The OLED device of claim 1, further comprising one or more protective layers formed between the light-scattering layer and the transparent electrode and/or over the light-scattering layer on the side of the light-scattering layer opposite the transparent electrode.

10. The OLED device of claim 1, wherein the light-scattering particles have an average maximum diameter of less than 2 microns.

11. The OLED device of claim 10, wherein the light-scattering particles have an average maximum diameter of between one and two microns.

12. The OLED device of claim 1, wherein the light-scattering particles comprise phosphorescent or fluorescent particles.

13. The OLED device of claim 1, wherein the light-scattering layer further includes phosphorescent or fluorescent particles.

14. The OLED device of claim 13, wherein the phosphorescent or fluorescent particles have an average diameter less than or equal to 400 nm.

15. The OLED device of claim 1, wherein the OLED device is a display device.

16. The OLED device of claim 1, wherein the light-scattering particles comprise a metal oxide.

17. The OLED device of claim 1, wherein the light-scattering particles comprise one or more of the following:

rutile particles, SiO_x (x>

1), SiN_x (x>

1), Si₃N₄, TiO₂, MgO, ZnO, Al₂O₃, SnO₂, In₂O₃, MgF₂, hafnia (HfO₂), zirconia (ZrO₂), zircon (ZrO₂.SiO ₂), gadolinium gallium garnet (Gd₃Ga₅O₁₂), barium sulfate, yttria (Y₂O₃), yttrium aluminum garnet (Y₃Al₅O₁₂), calcite (CaCO₃), sapphire (Al₂O₃), diamond, magnesium oxide, germanium oxide, or CaF₂.

18. The OLED device of claim 1, wherein the light-scattering layer is less than one micrometer thick.

19. A method of forming an OLED device comprising the steps of:

a) providing an OLED with a light-emitting area comprising a first electrode and a second transparent electrode and one or more layers of organic light-emitting material formed between the electrodes;

b) forming a dispersion comprising an evaporable solvent and a plurality of transparent light scattering particles;

c) coating the dispersion on a side of the transparent electrode opposite the one or more layers of organic light-emitting material; and

d) drying the dispersion to form a light scattering layer on the transparent electrode, wherein the ratio of the volume of scattering particles to the volume of the light scattering layer is within the range of 0.55 to 0.75 over a majority of the light-emitting area.