System and method for purifying an aqueous stream

• US 7,837,768 B2
• Filed: 08/27/2008
• Issued: 11/23/2010
• Est. Priority Date: 08/27/2007
• Status: Active Grant

• Current Assignee: 212 Holdings, LLC
• Original Assignee: General Electric Capital Corporation (General Electric Company)
• Inventors: Rohwer, Bradford M., Sanderson, Larry D., Schleiffarth, James W., Merrill, Leslie D.
• Primary Examiner(s): Drodge; Joseph W
• Application Number:
  US12/199,777
• Publication Number:
  US 20090078652A1
• Time in Patent Office: 818 Days
• Field of Search: 202/82, 202/152, 202/161, 202/182, 202/185.1, 202/197, 203 1- 3, 203/10, 203/31, 203/39, 203/42, 203/88, 203/89, 203/98, 210/669, 210/739, 210/742, 210/743, 210/744, 210/758, 210/763, 210/767, 210/774, 210/806, 210 85- 87, 210/90, 210/103, 210/104, 210/134, 210/137, 210/143, 210/149, 210/167.32, 210180-182, 210/188, 210/194, 210/195.1, 210/192, 210/258, 210/259, 210/741, 210/748, 210/805, 166/266, 166/267, 175/66, 175/206, 175/207, 95 14- 19, 95/23, 95/24, 951/49, 95156-159, 951/65, 951/66, 95178-180, 951/87, 951/88, 952/04, 95223-228, 95241-245, 952/51, 95254-259, 952/63, 951/86, 961/56, 961/57, 961/73, 961/74, 96182-185, 961/93, 962/01, 962/18, 962/34, 962/35, 96242-245, 96251-253, 96417-421, 961/81, 208/187, 165/108
• US Class Current: 95/158
• CPC Class Codes: B01D 1/16 by spraying B01D1/22 takes precedence
• CPC Class Codes: B01D 19/0005 with one or more auxiliary substances
• CPC Class Codes: C02F 1/048 Purification of waste water by evaporation
• CPC Class Codes: C02F 2103/365 from petrochemical industry (e.g. refineries)
• CPC Class Codes: C02F 2209/02 Temperature
• CPC Class Codes: C02F 2209/03 Pressure
• CPC Class Codes: C02F 2209/40 Liquid flow rate
• CPC Class Codes: C02F 2209/42 Liquid level
• CPC Class Codes: Y02P 70/10 Greenhouse gas [GHG] capture, material saving, heat recovery or other energy efficient measures, e.g. motor control, characterised by manufacturing processes, e.g. for rolling metal or metal working

Abstract

A system and method are disclosed for purifying a waste fluid stream. The system includes a recirculation pump having an inlet for a recirculation stream and an outlet to expel a pressurized stream. The system includes a compressor having an inlet for an evaporation stream and an outlet for a pressurized evaporation stream. A primary heat exchanger has inlets for the pressurized stream and the pressurized evaporation stream, an internal surface area for heat transfer from the evaporation stream to the pressurized stream, and outlets for a cooled product stream and a heated pressurized stream. The heated pressurized stream is formed by heating the pressurized stream and the cooled product stream is formed by cooling the evaporation stream. The system includes an evaporation unit having an inlet for the heated pressurized stream and outlets for an evaporation stream and the recycled liquid bottoms stream.

Claims

1. A system to purify a waste fluid stream, the system comprising:

a recirculation pump having an inlet for a recirculation stream and an outlet to expel a pressurized stream, the recirculation stream comprising a waste fluid stream and a recycled liquid bottoms stream;

a compressor having an inlet for an evaporation stream and an outlet for a pressurized evaporation stream;

a primary heat exchanger having inlets for the pressurized stream and the pressurized evaporation stream, having an internal surface area for heat transfer from the evaporation stream to the pressurized stream, and having outlets for a cooled evaporation stream and a heated pressurized stream, wherein

the heated pressurized stream is formed by heating the pressurized stream, and

the cooled evaporation stream is formed by cooling the evaporation stream; and

an evaporation unit having an inlet for the heated pressurized stream and outlets for the evaporation stream and the recycled liquid bottoms stream, wherein

the evaporation stream is formed when volatile compounds in the heated pressurized stream evaporate in the evaporation unit, and

the liquid bottoms stream is formed from a portion of the heated pressurized stream that does not evaporate.

2. The system of claim 1, further comprising a stripping unit that receives the cooled evaporation stream from the primary heat exchanger, the stripping unit comprising a stripping vessel, a stripper recycle pump, a reboiler, a condensing unit, and at least one valve, wherein:

the stripping vessel comprises inlets for the cooled evaporation stream, a recycled bottoms stream, and a stripper reflux stream and outlets for a stripper vapor outlet stream and a stripper bottoms stream;

the stripper recycle pump comprises an inlet for the stripper bottoms stream and an outlet for the recycled bottoms stream;

the reboiler comprises inlets for the recycled bottoms stream and a heat transfer fluid, the reboiler having an internal surface area for heat transfer from the heat transfer fluid to the recycled bottoms stream;

the condensing unit comprises an inlet for the stripper vapor outlet stream and outlets for a volatile fractions stream, a non-condensable stream, and the stripper reflux stream, wherein the stripper reflux stream returns to the stripping vessel; and

the at least one valve comprises an inlet for the recycled bottoms stream and at least two outlets, wherein one outlet comprises a final product stream port.

3. The system of claim 2, wherein the condensing unit comprises:

a primary condenser having inlets for the stripper vapor outlet stream and a first coolant stream, having an internal surface area for heat transfer from the stripper vapor outlet stream to the coolant stream, and having outlets for a cooled stripper vapor stream and a spent coolant stream;

a collection vessel having inlets for the cooled stripper vapor stream and a liquid return stream and having outlets for a collection vapor stream and a condensed stream;

a secondary condenser having inlets for the collection vapor stream and a second coolant stream, having an internal surface area for heat transfer from the collection vapor stream to the second coolant stream, and having outlets for a non-condensable stream, the liquid return stream, and a spent coolant stream, wherein

the liquid return stream comprises a fraction of the collection vapor stream that condenses in the secondary condenser, and

the non-condensable stream comprises a fraction of the collection vapor stream that does not condense in the secondary condenser; and

a splitter valve having an inlet for the condensed stream and outlets for the stripper reflux stream and the volatile fractions stream.

4. The system of claim 2, wherein the ratio of the flow rate of the stripper reflux stream to the sum of the flow rates of the volatile fraction stream and the non-condensable stream is between 1 and 200.

5. The system of claim 2, wherein the ratio of the flow rate of the stripper reflux stream to the sum of the flow rates of the volatile fraction stream and the non-condensable stream is between 10 and 50.

6. The system of claim 2, wherein the ratio of the flow rate of the stripper reflux stream to the sum of the flow rates of the volatile fraction stream and the non-condensable stream is approximately 20.

7. The system of claim 2 further comprising a steam control unit that provides backpressure to keep the cooled evaporation stream in a liquid phase, the steam control unit comprising:

a separator having an inlet for the cooled evaporation stream from the primary heat exchanger and a outlets for a liquid stream and a vapor vent stream;

a pump having an inlet for the liquid stream and an outlet to the stripping unit; and

a vent having an inlet for the vapor vent stream and an outlet to the stripping unit.

8. The system of claim 7 wherein the steam control unit provides the liquid stream to the stripping vessel and wherein the vapor vent stream is introduced to the stripping vessel below a distribution tray.

9. The system of claim 2, further comprising a steam control unit that provides backpressure to keep the cooled evaporation stream in a liquid phase, the steam control unit comprising:

a steam trap having an inlet for the cooled evaporation stream from the primary heat exchanger and an outlet for a condensed distillate stream;

a storage vessel having an inlet for the condensed distillate stream and outlets for a vapor vent stream and a liquid stream;

a pump having an inlet for the liquid stream and an outlet to the stripping unit; and

a vent having an inlet for the vapor vent stream and an outlet to the stripping unit.

10. The system of claim 9 wherein the steam control unit provides condensed steam to the stripping vessel and wherein the vapor vent stream from the storage vessel is introduced to the stripping vessel below a distribution tray.

11. The system of claim 1 further comprising an oxidizer unit, wherein the oxidizer unit comprises:

inlets for a product stream and an oxidizer;

an outlet for an oxidized stream; and

an ultrasonic vibration source.

12. The system of claim 1 further comprising an oxidizer unit, wherein the oxidizer unit comprises:

an inlet for a product stream;

an outlet for an oxidized stream; and

an ultraviolet radiation source.

13. The system of claim 1 further comprising a secondary recovery heat exchanger having inlets for the waste fluid stream and a final product stream, having an internal surface area for heat transfer from the final product stream to the waste fluid stream, and having outlets for a cooled final product stream and a heated waste fluid stream.

14. The system of claim 1 further comprising an additives unit, the additives unit comprising a pump having an inlet for additives and an outlet to the recirculation stream.

15. The system of claim 1 wherein the primary heat exchanger is further configured with an inlet and an outlet for a heat transfer fluid and with an internal surface area for heat transfer from the heat transfer fluid to the pressurized stream.

16. The system of claim 1, wherein the primary heat exchanger transfers heat from the evaporation stream to the recirculation stream such that the cooled evaporation stream is a liquid.

17. The system of claim 1 further comprising a secondary recovery heat exchanger having inlets for the waste fluid stream and a purge stream, having an internal surface area for heat transfer from the purge stream to the waste fluid stream, and having outlets for a cooled purge stream and a heated waste fluid stream.

18. The system of claim 1 further comprising an orifice through which the heated pressurized stream flows prior to entering the evaporation unit, the orifice being configured to enhance a flash effect of the heated pressurized stream within the evaporation unit.

19. The system of claim 1 wherein a ratio of the mass flow rate of the recirculation stream to the mass flow rate of the evaporation stream is greater than about 200.

20. The system of claim 1, further comprising a separator that removes solid material and hydrocarbons immiscible in water from the waste fluid stream before the waste fluid stream joins the recirculation stream.

21. The system of claim 20, further comprising a feed pump to deliver the waste fluid stream to the separator.

22. The system of claim 1, further comprising a final processing unit configured to remove remaining contaminants from the final product stream.

23. The system of claim 22, wherein the final processing unit comprises a carbon adsorber.

24. The system of claim 1, further comprising a controller that receives one or more signals from sensors and sends one or more signals to actuators.

25. The system of claim 24, wherein the sensors measure parameters selected from the group consisting of pressure, temperature, level, flow, density, and chemical composition.

26. The system of claim 24, wherein the actuators are selected from the group consisting of electronic, hydraulic, and pneumatic manipulation of controlled physical components of the apparatus.

27. The system of claim 24, wherein the controlled physical components of the apparatus are selected from the group consisting of valves, pumps, and blowers.

28. The system of claim 24, wherein the controller comprises an operator interface.

29. The system of claim 1, wherein the waste fluid stream is contaminated oilfield process water.

30. The system of claim 1, wherein the ratio of the flow rate of the recirculation stream to the flow rate of the waste fluid stream is between 50 and 500.

31. The system of claim 1, wherein the ratio of the flow rate of the recirculation stream to the flow rate of the waste fluid stream is between 150 and 250.

32. The system of claim 1, wherein the ratio of the flow rate of the recirculation stream to the flow rate of the waste fluid stream is approximately 200.

33. A system to purify a waste fluid stream, the system comprising:

a recirculation pump having an inlet for a recirculation stream and an outlet to expel a pressurized stream, the recirculation stream comprising a waste fluid stream and a recycled liquid bottoms stream;

a compressor having an inlet for an evaporation stream and an outlet for a pressurized evaporation stream;

a primary heat exchanger having inlets for the pressurized stream, the pressurized evaporation stream, and a heat transfer fluid, the heat exchanger transferring heat from the heat transfer fluid and from the evaporation stream to the pressurized stream;

an evaporation unit having an inlet for the pressurized stream and outlets for the evaporation stream and the recycled liquid bottoms stream;

a stripping vessel having inlets for the evaporation stream, a recycled bottoms stream, and a stripper reflux stream and outlets for a stripper vapor outlet stream and a stripper bottoms stream;

a stripper recycle pump having an inlet for the stripper bottoms stream and an outlet for the recycled bottoms stream;

a reboiler having inlets for the recycled bottoms stream and a heat transfer fluid, the reboiler having an internal surface area for heat transfer from the heat transfer fluid to the recycled bottoms stream;

a condensing unit having an inlet for the stripper vapor outlet stream and outlets for a volatile fractions stream, a non-condensable stream, and the stripper reflux stream, wherein the stripper reflux stream returns to the stripping vessel;

a secondary recovery heat exchanger having inlets for the waste fluid stream and the final product stream, the heat exchanger transferring heat from the final product stream to the waste fluid stream.

34. A method to purify a waste fluid stream, the method comprising:

joining a waste fluid stream with a concentrated bottoms stream from an evaporation unit to form a pressurized stream;

recirculating the pressurized stream through a primary heat exchanger and the evaporation unit;

transferring heat from a compressed evaporation stream to the pressurized stream to form a heated pressurized stream; and

evaporating volatile compounds from the heated pressurized stream in the evaporation unit and passing the volatile compounds through a compressor to become the compressed evaporation stream, the volatile compounds forming the evaporation stream;

wherein the concentrated bottoms stream comprises a portion of the heated pressurized stream that does not evaporate.

35. The method of claim 34, further comprising:

introducing the evaporation stream into a stripping vessel, wherein the evaporation stream separates into a vapor outlet stream and a liquid bottoms stream;

pumping the stripper bottoms stream from the stripping vessel through a reboiler and back to the stripping vessel;

extracting a portion of the stripper bottoms stream as a product stream;

heating the stripper bottoms stream in the reboiler;

condensing a portion of the vapor outlet stream to form a stripper reflux stream; and

returning the stripper reflux stream to the stripping vessel.

36. The method of claim 35 further comprising mixing a chemical oxidizer with the product stream.

37. The method of claim 36 further comprising vibrating a mixture of the chemical oxidizer and the product stream with ultrasonic vibration.

38. The method of claim 35 further comprising irradiating the product stream with ultraviolet radiation.

39. The method of claim 35 further comprising removing contaminants from the product stream by passing the product stream through a filter.

40. The method of claim 35, further comprising transferring heat from the product stream to the waste fluid stream.

41. The method of claim 34, further comprising adding chemical additives to the pressurized stream.

42. The method of claim 34, further comprising transferring heat from a heat transfer fluid to the pressurized stream.

43. The method of claim 34, further comprising separating solid material and hydrocarbons immiscible in water from the waste fluid stream before the waste fluid stream joins the pressurized stream.

44. The method of claim 34, further comprising:

receiving one or more signals from sensors; and

controlling one or more actuators.

45. The method of claim 44, wherein the sensors measure parameters selected from the group consisting of pressure, temperature, level, flow, density, and chemical composition.

46. The method of claim 44, wherein the actuators are selected from the group consisting of electronic, hydraulic, and pneumatic manipulation of controlled physical components of the apparatus.

47. The method of claim 46, wherein the controlled physical components of the apparatus are selected from the group consisting of valves, pumps, and blowers.