Microemulsions to convert OBM filter cakes to WBM filter cakes having filtration control

• US 7,838,467 B2
• Filed: 05/04/2010
• Issued: 11/23/2010
• Est. Priority Date: 09/03/2004
• Status: Active Grant

• Current Assignee: Baker Hughes Holdings LLC (Baker Hughes Company)
• Original Assignee: Baker Hughes Incorporated (Baker Hughes Company)
• Inventors: Clark, David E., Jones, Thomas A., Quintero, Lirio
• Primary Examiner(s): Kugel; Timothy J.
• Application Number:
  US12/773,533
• Publication Number:
  US 20100216671A1
• Time in Patent Office: 203 Days
• Field of Search: 507/103, 507/203, 516/20, 516/21, 516/198
• US Class Current: 507/103
• CPC Class Codes: C09K 2208/18 Bridging agents, i.e. particles for temporarily filling the pores of a formation; Graded salts
• CPC Class Codes: C09K 8/32 Non-aqueous well-drilling compositions, e.g. oil-based
• CPC Class Codes: C09K 8/36 Water-in-oil emulsions
• CPC Class Codes: C09K 8/52 Compositions for preventing, limiting or eliminating depositions, e.g. for cleaning

Abstract

Single phase microemulsions improve the removal of filter cakes formed during drilling with oil-based muds (OBMs). The single phase microemulsion removes oil and solids from the deposited filter cake. Optionally, an acid capable of solubilizing the filter cake bridging particles may also be used with the microemulsion. In one non-limiting embodiment the acid may be a polyamino carboxylic acid. Skin damage removal from internal and external filter cake deposition can be reduced. In another optional embodiment, the single phase microemulsion may contain a filtration control additive for delaying the filter cake removal, destruction or conversion.

Claims

1. A thermodynamically stable, macroscopically homogeneous, single phase microemulsion (SPME) comprising:

a polar phase;

a nonpolar phase;

a surfactant; and

a water-soluble filtration control additive selected from the group consisting of solid particulates, polymers and mixtures thereof.

2. The SPME of claim 1 where the surfactant is selected from the group consisting of non-ionic surfactants, anionic surfactant, cationic surfactants and amphoteric surfactants.

3. The SPME of claim 1 further comprising an acid selected from the group of inorganic acids consisting of hydrochloric acid, sulfuric acid, and mixtures thereof, and organic acids consisting of acetic acid, formic acid and salts of these organic acids, and mixtures of one or more of these acids.

4. The SPME of claim 1 further comprising at least one polyamino carboxylic acid or salt thereof, where the concentration of polyamino carboxylic acid or a salt thereof in the microemulsion ranges from 1 to 30 volume %.

5. The SPME of claim 1 where in the filtration control additive, the solid particulates are selected from the group consisting of sized salts, hematite, ilmenite, manganese tetroxide, and mixtures thereof, and where the water-soluble polymers are selected from the group consisting of natural and synthetic polymers and copolymers and mixtures thereof.

6. The SPME of claim 1 where the proportion of filtration control additive in the SPME ranges from about 0.1 to about 10 lb/bbl.

7. The SPME of claim 1 where the nonpolar phase is selected from the group consisting of synthetic base and mineral oils, ester fluids, paraffins, and isomerized olefins.

8. A thermodynamically stable, macroscopically homogeneous, single phase microemulsion (SPME) comprising:

a polar phase;

a nonpolar phase;

a surfactant selected from the group consisting of non-ionic surfactants, anionic surfactant, cationic surfactants and amphoteric surfactants; and

from about 0.1 to about 10 lb/bbl, based on the SPME, of a water-soluble filtration control additive selected from the group consisting of solid particulates, polymers and mixtures thereof.

9. The SPME of claim 8 further comprising an acid selected from the group of inorganic acids consisting of hydrochloric acid, sulfuric acid, and mixtures thereof, and organic acids consisting of acetic acid, formic acid and salts of these organic acids, and mixtures of one or more of these acids.

10. The SPME of claim 8 further comprising at least one polyamino carboxylic acid or salt thereof, where the concentration of polyamino carboxylic acid or a salt thereof in the microemulsion ranges from 1 to 30 volume %.

11. The SPME of claim 8 where in the filtration control additive, the solid particulates are selected from the group consisting of sized salts, hematite, ilmenite, manganese tetroxide, and mixtures thereof, and where the water-soluble polymers are selected from the group consisting of natural and synthetic polymers and copolymers and mixtures thereof.

12. The SPME of claim 8 where the nonpolar phase is selected from the group consisting of synthetic base and mineral oils, ester fluids, paraffins, and isomerized olefins.

13. A thermodynamically stable, macroscopically homogeneous, single phase microemulsion (SPME) comprising:

a polar phase;

a nonpolar phase;

a surfactant; and

from about 0.1 to about 10 lb/bbl, based on the SPME, of a water-soluble filtration control additive selected from the group consisting of sized salts, hematite, ilmenite, manganese tetroxide, and mixtures thereof, and where the water-soluble polymers are selected from the group consisting of natural and synthetic polymers and copolymers and mixtures thereof.

14. The SPME of claim 13 where the surfactant is selected from the group consisting of non-ionic surfactants, anionic surfactant, cationic surfactants and amphoteric surfactants.

15. The SPME of claim 13 further comprising an acid selected from the group of inorganic acids consisting of hydrochloric acid, sulfuric acid, and mixtures thereof, and organic acids consisting of acetic acid, formic acid and salts of these organic acids, and mixtures of one or more of these acids.

16. The SPME of claim 13 further comprising at least one polyamino carboxylic acid or salt thereof, where the concentration of polyamino carboxylic acid or a salt thereof in the microemulsion ranges from 1 to 30 volume %.

17. The SPME of claim 13 where the nonpolar phase is selected from the group consisting of synthetic base and mineral oils, ester fluids, paraffins, and isomerized olefins.