Method of manufacturing a birefringent film, optical film using the same, liquid crystal panel, liquid crystal display device and imaged display device

• US 7,867,414 B2
• Filed: 10/06/2005
• Issued: 01/11/2011
• Est. Priority Date: 10/07/2004
• Status: Expired due to Fees

• Current Assignee: Nitto Denko Corporation
• Original Assignee: Nitto Denko Corporation
• Inventors: Ishibashi, Kuniaki, Yoshimi, Hiroyuki
• Primary Examiner(s): HON, SOW FUN
• Application Number:
  US11/244,159
• Publication Number:
  US 20060078693A1
• Time in Patent Office: 1,923 Days
• Field of Search: 428/1.3, 428/1.31, 428/1.33, 428/1.5, 428/1.54, 264/291, 264/289.6, 264/1.34, 264/479, 264/342.R, 264/342.RE, 264/2.7, 349117-121, 524481-482, 524/553, 525/210
• US Class Current: 264/2.7
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: C09K 2323/031 Polarizer or dye
• CPC Class Codes: G02B 5/3083 Birefringent or phase retarding elements G02B5/3008, G02B5/3016 take precedence; systems for polarisation control G02B27/286; manufacturing phase modulating patterns by lithographic processes G03F7/001

Abstract

A method of manufacturing a birefringent film includes stretching a polymer film in a widthwise direction while at the same time shrinking the same in a lengthwise direction so as to satisfy the relational expression: (1/STD)^1/2≦SMD<1, in which the length in the widthwise direction and the length in the lengthwise direction, of the polymer film before being stretched are respectively designated as 1, and STD represents a change ratio of the length in the widthwise direction of the polymer film due to stretching and SMD represents a change ratio of the length in the lengthwise direction of the polymer film due to shrinking, and make the stretched polymer film have an Nz coefficient of 0.9-1.1. This method achieves manufacturing of a birefringent film with a high production efficiency, while omitting the bowing phenomenon when manufacturing a birefringent film by stretching a polymer film in the widthwise direction, thereby limiting unevenness in birefringence, retardation and orientation angle and hence producing excellent optical characteristics, as well as achieving successive lamination when laminating with a polarizing film.

Claims

1. A method of manufacturing a birefringent film comprising stretching a polymer film in a widthwise direction while at the same time shrinking the same polymer film in a lengthwise direction, wherein the widthwise direction is a direction perpendicular to the lengthwise direction, so as to satisfy the relational expression:

(1/STD)^1/2≦

SMD<

1, in which the length in the widthwise direction and the length in the lengthwise direction, of said polymer film before being stretched are respectively designated as 1, and STD represents a change ratio of the length in the widthwise direction of said polymer film due to stretching and SMD represents a change ratio of the length in the lengthwise direction of said polymer film due to shrinking, and make the stretched polymer film have an Nz coefficient of 0.9-1.1, where Nz=(nx−

nz)/(nx−

ny), in which nx=maximum in-plane refractive index of the polymer film, ny=in-plane refractive index in a direction crossing at right angles to an in-plane nx direction that gives the maximum in-plane refractive index of the polymer film, and nz=thickness-wise refractive index in a direction crossing at right angles to a refractive index angle of nx and a refractive index angle of ny of the polymer film, and the stretching treatment and the shrinking treatment which are to be made simultaneously are indirectly applied to the polymer film, by laminating the polymer film on a substrate and simultaneously applying the stretching and shrinking treatments to the substrate, where the stretching ratio of the polymer film in the widthwise direction is controlled while simultaneously controlling the shrinking length of the polymer film in the lengthwise direction by changing the distance between the opposite ends of the substrate.

2. The method of manufacturing a birefringent film according to claim 1, wherein said polymer film contains at least one selected from the group consisting of norbomene type resin, polycarbonate type resin and cellulose type resin.