High-temperature thermocouples and related methods

• US 7,871,198 B2
• Filed: 02/26/2007
• Issued: 01/18/2011
• Est. Priority Date: 02/26/2007
• Status: Active Grant

• Current Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Original Assignee: Battelle Energy Alliance LLC (Battelle Memorial Institute)
• Inventors: Knudson, Darrell L., Wilkins, S. Curt, Condie, Keith G., Rempe, Joy L.
• Primary Examiner(s): Caputo; Lisa M
• Assistant Examiner(s): Jagan; Mirellys
• Application Number:
  US11/678,901
• Publication Number:
  US 20080205483A1
• Time in Patent Office: 1,422 Days
• Field of Search: 374/179, 374/208, 136/232, 136/230
• US Class Current: 374/179
• CPC Class Codes: G01K 7/02 using thermoelectric elements, e.g. thermocouples
• CPC Class Codes: H10N 10/01 Manufacture or treatment
• CPC Class Codes: Y10T 29/49085 Thermally variable

Abstract

A high-temperature thermocouple and methods for fabricating a thermocouple capable of long-term operation in high-temperature, hostile environments without significant signal degradation or shortened thermocouple lifetime due to heat induced brittleness.

Claims

1. A method of manufacturing a thermocouple, comprising:

forming a thermocouple junction between a first thermoelement wire and a second thermoelement wire formed from thermoelectrically dissimilar materials by swaging a metallic tube onto a first end of the first thermoelement wire and a first end of the second thermoelement wire;

threading the first thermoelement wire through a first longitudinal passageway formed in a first electrical insulating material and threading the second thermoelement wire through a second longitudinal passageway formed in the first electrical insulating material;

disposing the first electrical insulating material, a second electrical insulating material, and a third electrical insulating material having a different density than the first electrical insulating material and the second electrical insulating material in a sheath, comprising;

interfacing the third electrical insulating material with the second electrical insulating material; and

positioning the thermocouple junction within a void formed in the first electrical insulating material and another void formed in the second electrical insulating material;

swaging the sheath so that the first electrical insulating material and the second electrical insulating material contact the first thermoelement wire, the second thermoelement wire, and the thermocouple junction;

determining a location of the interface between the second electrical insulating material and the third electrical insulating material;

cutting the thermocouple between the thermocouple junction and the interface between the second electrical insulating material and the third electrical insulating material to form a sheath end; and

capping the sheath end with an end plug.

2. The method of claim 1, further comprising heating the first electrical insulating material, the second electrical insulating material, and the third electrical insulating material at a sufficient temperature and time to remove moisture contained therein.

3. The method of claim 1, further comprising forming the first electrical insulating material and the second electrical insulating material from hafnia.

4. The method of claim 1, further comprising forming the third electrical insulating material from alumina.

5. The method of claim 1, wherein determining a location of the interface between the second electrical insulating material and the third electrical insulating material comprises determining the location of the interface between the second electrical insulating material and the third electrical insulating material with an x-ray imaging system.

6. The method of claim 1, wherein capping the sheath end with an end plug comprises laser welding a niobium plug onto the sheath end.

7. The method of claim 1, further comprising heating the first thermoelement wire, the second thermoelement wire, the first electrical insulating material, the second electrical insulating material, and the third electrical insulating material at a sufficient temperature and time to remove moisture contained therein.

8. The method of claim 7, further comprising heating the thermocouple to at least 100°

C. above a planned service temperature of the thermocouple for at least three hours to stabilize a grain structure of the thermocouple.

9. The method of claim 1, further comprising forming the first thermoelement wire from molybdenum doped with elements selected from the group consisting of tungsten, potassium, and silicon.

10. The method of claim 9, wherein forming the first thermoelement wire from molybdenum doped with elements selected from the group consisting of tungsten, potassium, and silicon comprises forming the molybdenum with doped elements that are present in amounts ranging from between 100 parts per million to 300 parts per million.

11. The method of claim 1, further comprising forming the second thermoelement wire from a niobium and zirconium alloy.

12. The method of claim 11, wherein forming the second thermoelement wire from a niobium and zirconium alloy comprises forming the niobium and zirconium alloy from 99% by weight niobium and 1% by weight zirconium.

13. The method of claim 1, further comprising forming the sheath from a niobium and zirconium alloy.

14. The method of claim 13, wherein forming the sheath from a niobium and zirconium alloy comprises forming the niobium and zirconium alloy from 99% by weight niobium and 1% by weight zirconium.

15. A method of fabricating a thermocouple, comprising:

forming a thermocouple junction by swaging an end of a first thermoelement wire and an end of a second thermoelement wire formed from thermoelectrically dissimilar materials with a metallic tube;

heating a first insulating material, a second insulating material, and a third insulating material at a sufficient temperature and time to remove moisture and impurities contained therein;

threading the first thermoelement wire through a first passageway formed in the first insulating material and threading the second thermoelement wire through a second passageway formed in the first insulating material;

disposing the first insulating material, the second insulating material, and the third insulating material within a metallic sheath, comprising;

forming an interface between the second insulating material and the third insulating material; and

positioning the thermocouple junction within a void formed in the first insulating material and another void formed in the second insulating material;

swaging the sheath so that the first insulating material and the second insulating material contact the first thermoelement wire, the second thermoelement wire, and the thermocouple junction;

cutting the thermocouple at a location between the thermocouple junction and the interface between the second insulating material and the third insulating material to form a sheath end; and

capping the sheath end with an end plug.

16. The method of claim 15, further comprising heating the capped thermocouple at a sufficient temperature and time to stabilize a grain structure of the thermocouple.

17. The method of claim 15, further comprising forming the first insulating material and the second insulating material from hafnia.

18. The method of claim 15, further comprising forming the third insulating material from alumina.

19. The method of claim 15, further comprising determining the location of the thermocouple junction and the interface between the second insulating material and the third insulating material by x-ray imaging.

20. The method of claim 15, wherein capping of the sheath end with an end plug comprises laser welding a niobium plug onto the sheath end.

21. The method of claim 15, further comprising forming the sheath from a niobium and zirconium alloy.

22. A thermocouple produced by the method of claim 15.

23. The method of claim 15, further comprising forming the first thermoelement wire from molybdenum doped with elements selected from the group consisting of tungsten, potassium and silicon.

24. The method of claim 23, wherein forming the first thermoelement wire from molybdenum doped with elements selected from the group consisting of tungsten, potassium and silicon comprises forming the molybdenum with doped elements that are present in amounts ranging from between 100 to 300 parts per million.

25. The method of claim 15, further comprising forming the second thermoelement from a niobium and zirconium alloy.

26. The method of claim 25, wherein forming the second thermoelement from a niobium and zirconium alloy comprises forming the niobium and zirconium alloy from 99% by weight niobium and 1% by weight zirconium.

27. A high-temperature thermocouple, comprising:

a thermocouple junction between a first thermoelement wire comprising a doped molybdenum and a second thermoelement wire comprising a niobium and zirconium alloy;

a first electrical insulating material comprising;

a first longitudinal passageway and a second longitudinal passageway formed therein, wherein the first thermoelement wire is at least partially disposed in the first longitudinal passageway and the second thermoelement wire is at least partially disposed in the second longitudinal passageway; and

a void formed in the first electrical insulating material for receiving a portion of the thermocouple junction;

a second electrical insulating material comprising a void for receiving a portion of the thermocouple junction;

a sheath comprising a niobium and zirconium alloy having the first electrical insulating material, material and the second electrical insulating material at least partially disposed therein, wherein the thermocouple junction is at least partially positioned within the void of the first electrical insulating material and the void of the second electrical insulating material, and wherein the first electrical insulating material and the second electrical insulating material is at least partially in contact with the first thermoelement wire, the second thermoelement wire, and the thermocouple junction; and

an end plug disposed on an end of the sheath proximate to the thermocouple junction.