Multipass optical device and process for gas and analyte determination

• US 7,876,443 B2
• Filed: 09/29/2008
• Issued: 01/25/2011
• Est. Priority Date: 09/29/2008
• Status: Active Grant

• Current Assignee: Battelle Memorial Institute
• Original Assignee: Battelle Memorial Institute
• Inventors: Bernacki, Bruce E.
• Primary Examiner(s): Toatley; Gregory J
• Assistant Examiner(s): Ton; Tri T
• Application Number:
  US12/239,978
• Publication Number:
  US 20100079760A1
• Time in Patent Office: 848 Days
• Field of Search: 356432-440, 359/838, 250/336.1, 25033901-33902, 25033905-33906, 25033912-33913
• US Class Current: 356/437
• CPC Class Codes: G01N 21/031 Multipass arrangements
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G02B 17/004 Systems comprising a plurality of reflections between two or more surfaces, e.g. cells, resonators multipass arrangements for optical cuvettes G01N21/031; laser resonators H01S3/05

Abstract

A torus multipass optical device and method are described that provide for trace level determination of gases and gas-phase analytes. The torus device includes an optical cavity defined by at least one ring mirror. The mirror delivers optical power in at least a radial and axial direction and propagates light in a multipass optical path of a predefined path length.

Claims

1. A multipass optical device, characterized by:

a torus structure that defines an optical cavity that includes at least one seamless ring mirror with a surface of revolution along the circumference that is rotationally symmetric with no defined optical axis, said at least one ring mirror provides optical power that propagates light introduced to said cavity in at least a radial direction and an axial direction such that it is optically continuous at all locations on the face thereof, defining a multipass optical path of a predefined path length.

2. The optical device of claim 1, wherein said optical cavity includes a single ring mirror.

3. The optical device of claim 2, said single ring mirror has an optical surface selected from the group consisting of:

spherical surfaces, concave spherical surfaces, convex spherical surfaces, equi-concave spherical surfaces, aspherical surfaces, astigmatic surfaces, and combinations thereof.

4. The optical device of claim 1, wherein said optical cavity includes two concentric ring mirrors each of which has an optical surface that faces, and is disposed apart from, the other in said cavity.

5. The optical device of claim 4, said device further includes a hub disposed at the center of said device external to said optical cavity.

6. The optical device of claim 4, said concentric ring mirrors each have an optical surface selected from the group consisting of:

spherical surfaces, concave spherical surfaces, convex spherical surfaces, equi-concave spherical surfaces, aspherical surfaces, astigmatic surfaces, and combinations thereof.

7. The optical device of claim 6, wherein one of said concentric ring mirrors is a convex ring mirror and one of said ring mirrors is a concave ring mirror.

8. The optical device of claim 6, wherein at least one of said concentric ring mirrors is an astigmatic mirror or includes an astigmatic portion.

9. The optical device of claim 1, wherein said at least one ring mirror has a radius of curvature equal to the radius of revolution of said optical cavity.

10. The optical device of claim 1, wherein said at least one ring mirror has a radius of curvature different from the radius of revolution of said optical cavity.

11. The optical device of claim 1, wherein said optical cavity is an open-air cavity.

12. The optical device of claim 1, wherein said optical cavity is a sealed cavity.

13. The optical device of claim 12, wherein said sealed cavity is an evacuated sealed cavity.

14. The optical device of claim 12, wherein said sealed cavity is a partially evacuated sealed cavity with a reduced pressure atmosphere.

15. The optical device of claim 1, said device includes at least one surface opening that allows light to enter into, and exit from, said optical cavity.

16. The optical device of claim 15, wherein said at least one opening is an off-center axis opening.

17. The optical device of claim 15, wherein said at least one opening is an on-center axis opening.

18. The optical device of claim 15, wherein said at least one opening is an opening through an external surface within said central hub.

19. The optical device of claim 1, wherein said multipass optical path includes a path length predefined in the range from about 10 meters to greater than or equal to 1000 meters.

20. A method for determination of a gas or a gas-phase analyte, comprising:

introducing a gas or a gas-phase analyte into an optical device comprising a torus structure that defines an optical cavity that includes at least one seamless ring mirror with a surface of revolution along the circumference that is rotationally symmetric with no defined optical axis, said at least one ring mirror provides optical power that propagates light introduced to said cavity in at least a radial direction and an axial direction such that it is optically continuous at all locations on the face thereof, defining a multipass optical path of a predefined path length;

introducing light into said optical cavity at a preselected launch angle and preselected wavelength, said gas or said gas-phase analyte absorbs light at a wavelength characteristic for said gas or said gas-phase analyte;

measuring an absorption signal for said gas or said gas-phase analyte; and

determining said gas or said gas-phase analyte.

21. The method of claim 20, wherein the step of introducing said gas or said gas-phase analyte includes an optical cavity with two concentric ring mirrors, each of said mirrors has an optical surface selected from the group consisting of:

spherical surfaces, concave spherical surfaces, convex spherical surfaces, equi-concave spherical surfaces, aspherical surfaces, astigmatic surfaces, and combinations thereof.

22. The method of claim 21, wherein the step of introducing a gas or a gas-phase analyte includes an optical cavity with at least one convex ring mirror or at least one concave ring mirror.

23. The method of claim 21, wherein the step of introducing a gas or a gas-phase analyte includes use of an optical cavity with an astigmatic mirror or an astigmatic mirror portion.

24. The method of claim 20, wherein the step of introducing a gas or a gas-phase analyte includes use of an optical cavity with at least one ring mirror that has a radius of curvature equal to the radius of revolution of said optical cavity.

25. The method of claim 20, wherein the step of introducing a gas or a gas-phase analyte includes use of an optical cavity with at least one ring mirror that has a radius of curvature different from the radius of revolution of said optical cavity.

26. The method of claim 20, wherein the step of introducing a gas or a gas-phase analyte includes partially evacuating said optical cavity prior to introducing said gas or said gas-phase analyte.

27. The method of claim 20, wherein the step of introducing a gas or a gas-phase analyte includes evacuating said optical cavity prior to introducing said gas or said gas-phase analyte.

28. The method of claim 20, wherein the step of introducing light into said optical cavity includes light of a preselected wavelength.

29. The method of claim 20, wherein the step of introducing light into said optical cavity includes a launch angle with respect to X- or Y-axes selected in the range from about 1 degree to about 50 degrees, respectively.

30. The method of claim 20, wherein the step of introducing light includes use of an optical cavity that is open to air.

31. The method of claim 20, wherein said optical device is used as a component of a gas detection system or instrument.

32. The method of claim 20, wherein said optical device is used as an absorption device for spectroscopy of a gas or a gas-phase analyte.

33. The method of claim 20, wherein said optical device is used as an emission stack monitor for real-time measurement of effluent gases.

34. The method of claim 20, wherein said optical device is used as a modular element or component in a multi-wavelength absorption spectroscopy system or process.

35. The method of claim 20, wherein said optical device is used as a gas sensor in an airborne gas measurement device or process.

36. The method of claim 20, wherein said optical device is used to determine a gas or a mixture of gases.

37. The method of claim 20, wherein said optical device is used as a component of a gas-phase analyte detection system or process.

38. The method of claim 20, wherein said device is used in a stack comprising two or more of same for determination of two or more preselected gases or gas-phase analytes.

39. In a system, a torus multipass optical device, comprising:

a torus structure that defines an optical cavity that includes at least one seamless ring mirror with a surface of revolution along the circumference that is rotationally symmetric with no defined optical axis, said at least one ring mirror provides optical power that propagates light introduced to said cavity in at least a radial direction and an axial direction such that it is optically continuous at all locations on the face thereof, defining a multipass optical path of a predefined path length.

40. The system of claim 39, further including a laser light source.

41. The system of claim 39, further including beam steering, focusing, and mode-matching optics.

42. The system of claim 39, further including an optical detector.

43. The system of claim 39, further including a lock-in detector.