SOFC system producing reduced atmospheric carbon dioxide using a molten carbonated carbon dioxide pump

• US 7,883,803 B2
• Filed: 03/30/2007
• Issued: 02/08/2011
• Est. Priority Date: 03/30/2007
• Status: Active Grant

• Current Assignee: Bloom Energy Corporation
• Original Assignee: Bloom Energy Corporation
• Inventors: Ballantine, Arne Watson, McElroy, James F.
• Primary Examiner(s): Ridley; Basia
• Assistant Examiner(s): Buchanan; Jacob
• Application Number:
  US11/730,256
• Publication Number:
  US 20080241638A1
• Time in Patent Office: 1,411 Days
• Field of Search: 429 12- 46, 429/400, 429410-411, 429/415, 429/472, 429/479, 429/490
• US Class Current: 429/410
• CPC Class Codes: H01M 2008/1293 Fuel cells with solid oxide electrolytes
• CPC Class Codes: H01M 2008/147 Fuel cells with molten carbonates
• CPC Class Codes: H01M 8/04156 with product water removal
• CPC Class Codes: H01M 8/0618 Reforming processes, e.g. autothermal, partial oxidation or steam reforming
• CPC Class Codes: H01M 8/0637 Direct internal reforming at the anode of the fuel cell
• CPC Class Codes: H01M 8/0668 Removal of carbon monoxide or carbon dioxide
• CPC Class Codes: H01M 8/2495 of fuel cells of different types
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A solid oxide fuel cell power generation system'"'"'s entire output is made up of three streams: water, sequestered carbon dioxide provided into a storage tank, and carbon dioxide depleted air. Thus, the system generates electricity from a hydrocarbon fuel, while outputting substantially no pollutants into the atmosphere and cleaning the air by removing carbon dioxide from the air exhaust stream. Thus, the system outputs cleaner air than it takes in without releasing pollutants into the atmosphere, while generating electricity from a readily available hydrocarbon fuel, such as natural gas.

Claims

1. A method of operating a fuel cell system, comprising:

providing a hydrocarbon fuel inlet stream and a carbon dioxide containing air inlet stream into the fuel cell system, wherein the fuel cell system comprises a fuel cell stack and a carbon dioxide pump;

operating the system to generate electricity and a plurality of output streams consisting essentially of oxygen and carbon dioxide depleted air, water, and carbon dioxide available for sequestration,

providing the carbon dioxide containing air inlet stream into the carbon dioxide pump;

removing at least 90 percent of the carbon dioxide contained in the air inlet stream using the carbon dioxide pump;

providing the air inlet stream from which the at least 90 percent carbon dioxide has been removed from the carbon dioxide pump into the fuel cell stack;

operating the fuel cell stack to generate the electricity, a fuel exhaust stream and an oxygen and carbon dioxide depleted air exhaust stream;

providing at least a portion of the fuel exhaust stream into the carbon dioxide pump; and

removing at least a portion of the carbon dioxide contained in the air inlet stream using the fuel exhaust stream in the carbon dioxide pump.

2. The method of claim 1, further comprising:

providing the hydrocarbon fuel inlet stream toward the fuel cell stack.

3. The method of claim 2, wherein:

the fuel cell stack comprises a SOFC stack; and

the carbon dioxide pump comprises a molten carbonate fuel cell stack.

4. The method of claim 3, further comprising separating at least 95% of hydrogen contained in the fuel exhaust stream using a cascaded electrochemical hydrogen pump, and providing the hydrogen separated from the fuel exhaust stream into the hydrocarbon fuel inlet stream.

5. The method of claim 4, further comprising providing a remaining fuel exhaust stream consisting essentially of water and carbon dioxide from the cascaded electrochemical hydrogen pump to a dryer, separating the water from the carbon dioxide in the dryer and sequestering the separated carbon dioxide.

6. The method of claim 5, wherein all output streams of the system consist essentially of a first output stream consisting essentially of oxygen and carbon dioxide depleted air, a second output stream consisting essentially of water, and a third output stream consisting essentially of carbon dioxide provided for sequestration.

7. The method of claim 3, wherein the air inlet stream comprises at least 0.02% carbon dioxide by volume.

8. A fuel cell system, comprising:

a solid oxide fuel cell stack;

a carbon dioxide pump;

a first conduit which operatively connects a fuel exhaust outlet of the fuel cell stack to a first inlet of the carbon dioxide pump; and

a second conduit which operatively connects an air exhaust outlet of the carbon dioxide pump to an air inlet of the fuel cell stack.

9. The system of claim 8, wherein:

the carbon dioxide pump further comprises a second inlet exposed to an air atmosphere comprising carbon dioxide; and

the carbon dioxide pump is adapted to remove at least a portion of the carbon dioxide in the atmosphere.

10. The system of claim 9, wherein the carbon dioxide pump is adapted to remove at least 90% of the carbon dioxide in the atmosphere comprising at least 0.02% carbon dioxide by volume.

11. The system of claim 8, further comprising a third conduit which operatively connects a fuel exhaust outlet of the carbon dioxide pump to an inlet of a cascaded electrochemical hydrogen pump, a fourth conduit which operatively connects a first outlet of the cascaded electrochemical hydrogen pump to a fuel inlet of the fuel cell stack and a fifth conduit which operatively connects a second outlet of the cascaded electrochemical hydrogen pump to a dryer.

12. The system of claim 11, further comprising a carbon dioxide storage tank operatively connected to one output of the dryer.

13. The system of claim 11, wherein the cascaded electrochemical hydrogen pump comprises a high temperature, low hydration ion exchange membrane cell stack.

14. The system of claim 8, wherein:

the carbon dioxide pump comprises a molten carbonate fuel cell stack.

15. A method of operating a fuel cell system, comprising:

providing a hydrocarbon fuel inlet stream towards a solid oxide fuel cell stack;

providing an air inlet stream and at least a portion of a fuel exhaust stream of the solid oxide fuel cell stack to a molten carbonate carbon dioxide pump to remove carbon dioxide from the air inlet stream; and

providing a carbon dioxide depleted air stream from the carbon dioxide pump into the solid oxide fuel cell stack.