Formation fluid sampling tools and methods utilizing chemical heating

• US 7,886,825 B2
• Filed: 11/22/2006
• Issued: 02/15/2011
• Est. Priority Date: 09/18/2006
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (SLB)
• Original Assignee: Schlumberger Technology Corporation (SLB)
• Inventors: Goodwin, Anthony, Del Campo, Christopher Scott, Betancourt, Soraya S., Van Hal, Ronald E. G., Dubost, Francois Xavier, Raghuraman, Bhavani, Mullins, Oliver C., Hegeman, Peter S., Vasques, Ricardo, Ayan, Cosan
• Primary Examiner(s): Stephenson; Daniel P
• Application Number:
  US11/562,908
• Publication Number:
  US 20080066904A1
• Time in Patent Office: 1,546 Days
• Field of Search: 166/250.1, 166/300, 166/302, 166/162, 73/644.5
• US Class Current: 166/302
• CPC Class Codes: E21B 36/008 using chemical heat generating means
• CPC Class Codes: E21B 49/10 using side-wall fluid samplers or testers

Abstract

A formation fluid sampling tool is provided with reactants which are carried downhole and which are combined in order to generate heat energy which is applied to the formation adjacent the borehole. By applying heat energy to the formation, the formation fluids are heated, thereby increasing mobility, and fluid sampling is expedited.

Claims

1. A tool for expediting the downhole sampling of hydrocarbons of a formation traversed by a borehole, the tool comprising:

a first chamber carrying a first reactant;

a second chamber separate from said first chamber and carrying a second reactant, said first reactant and second reactant chosen to generate an exothermic chemical reaction when in contact with each other;

a first port coupled to said first chamber and said second chamber; and

an injector coupled to said first port, said injector injecting heated injection fluid generated by causing said first reactant and said second reactant to react in an exothermic chemical reaction while in said tool through said first port and into one of the borehole or the formation.

2. The tool according to claim 1, further comprising a mixer coupled to said first chamber and said second chamber which mixes said first reactant and said second reactant.

3. The tool according to claim 2, wherein said mixer is located in one of said first chamber and said second chamber.

4. The tool according to claim 2, further comprising a third chamber coupled to said first chamber and said second chamber and said mixer is located in said third chamber.

5. The tool according to claim 2, wherein said mixer is located at said first port.

6. The tool according to claim 1, wherein said first reactant comprises water and said second reactant comprises a chemical which reacts with water in an exothermic dissolving reaction.

7. The tool according to claim 6, wherein said chemical is a salt.

8. The tool according to claim 7, wherein said salt is chosen from a group consisting of a magnesium salt, a potassium salt, an aluminum salt, and a sodium salt.

9. The tool according to claim 7, wherein said salt is at least one magnesium chloride, magnesium sulfate, aluminum bromide, aluminum chloride, potassium hydroxide and sodium hydroxide.

10. The tool according to claim 6, wherein said chemical is a chemical which when reacted with said water will generate an acid solution.

11. The tool according to claim 10, wherein said chemical which when reacted with water will generate at least one acid is chosen from phosphorous trichloride, phosphorous pentoxide, phosphorous pentachloride, and sulfur trioxide.

12. The tool according to claim 1, wherein said first reactant comprises an acid and said second reactant comprises a base.

13. The tool according to claim 12, wherein said acid is chosen from HCl and HNO₃, and said base is NAOH.

14. The tool according to claim 1, wherein said first reactants comprises water, and said second reactant comprises an acid.

15. The tool according to claim 14, wherein said acid is chosen from hydrochloric acid, sulfuric acid and pyro-phosphorous acid.

16. The tool according to claim 1, further comprising a third chamber coupled to said first chamber and said second chamber and containing a third reactant, wherein said first reactants comprises water, said second reactant comprises a chemical which when reacted with water will generate an acid solution, and said third reactant comprises a base.

17. The tool according to claim 1, wherein said first reactant and said second reactant are chemicals which will undergo an exothermic reduction-oxidation reaction when brought into contact with each other.

18. The tool according to claim 1, further comprising means for withdrawing into the tool at least some of the injection fluid and some formation hydrocarbon fluid from the formation.

19. The tool according to claim 18, wherein said means for withdrawing comprises a pump.

20. The tool according to claim 19, further comprising a third chamber for storing substantially pure formation hydrocarbon fluid.

21. The tool according to claim 20, further comprising a first flow line coupled to said first chamber, said second chamber and said first port;

and a second flow line coupled to said third chamber.

22. The tool according to claim 21, further comprising a plurality of valves coupling said first flow line to said first chamber, said second chamber, and said first port, and coupling said second line to said third chamber.

23. The tool according to claim 21, further comprising a second port coupled to said means for withdrawing and to said third chamber.

24. The tool according to claim 23, wherein said first port is one of a packer assembly and a probe assembly, and said second port is one of a packer assembly and a probe assembly.

25. The tool according to claim 21, further comprising monitoring means for monitoring fluid flowing through said second flow line.

26. The tool according to claim 25, wherein said monitoring means comprises at least one of an optical fluid analyzer, a pressure sensor, a temperature sensor, and a viscosity sensor.

27. The tool according to claim 1, wherein said first port is a packer assembly.

28. The tool according to claim 1, wherein said first port is a probe assembly.

29. The tool according to claim 1, further comprising a drilling assembly, wherein said first port is incorporated in said drilling assembly.

30. The tool according to claim 1, further comprising means for withdrawing into the tool at least some heated fluid generated by an exothermic chemical reaction of said first fluid reactant and said second fluid reactant and some formation hydrocarbon fluid from the formation.

31. The tool according to claim 1, further comprising a fluid analysis device that analyzes at least some heated fluid generated by an exothermic chemical reaction of said first fluid reactant and said second fluid reactant and some formation hydrocarbon fluid from the formation.

32. A tool for expediting the downhole sampling of hydrocarbons of a formation traversed by a borehole, the tool comprising:

a first chamber carrying a first fluid reactant;

a second chamber separate from said first chamber and carrying a second fluid reactant, said first fluid reactant and second fluid reactant chosen to generate an exothermic chemical reaction when in contact with each other;

a mixer coupled to said first chamber and said second chamber which mixes said first reactant and said second reactant, wherein said mixer is located in one of said first chamber or said second chamber; and

a first port coupled to said first chamber and said second chamber; and

an injector coupled to said first chamber, said second chamber and said first port, said injector injecting said first fluid reactant and said second fluid reactant into one of the borehole or the formation.

33. The tool according to claim 32, further comprising means for withdrawing into the tool at least some heated fluid generated by an exothermic chemical reaction of said first fluid reactant and said second fluid reactant and some formation hydrocarbon fluid from the formation.

34. A downhole device for expediting the downhole sampling of hydrocarbons of a formation traversed by a borehole, the downhole device comprising:

a first chamber carrying a first fluid reactant;

a second chamber separate from said first chamber and carrying a second fluid reactant, said first fluid reactant and second fluid reactant chosen to generate an exothermic chemical reaction when in contact with each other;

a third chamber coupled to said first chamber and said second chamber and containing a third reactant, wherein said first reactants comprises water, said second reactant comprises a chemical which when reacted with water will generate an acid solution, and said third reactant comprises a base; and

a first port coupled to said first chamber and said second chamber; and

an injector coupled to said first chamber, said second chamber and said first port, said injector injecting said first fluid reactant and said second fluid reactant into one of the borehole or the formation.