Polymeric compositions having low glass transition temperatures

• US 7,893,157 B2
• Filed: 05/05/2003
• Issued: 02/22/2011
• Est. Priority Date: 08/26/2002
• Status: Active Grant

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Weier, Jane Elizabeth, Troy, Edward Joseph, McDonald, David John
• Primary Examiner(s): Mullis; Jeffrey C
• Application Number:
  US10/430,195
• Publication Number:
  US 20040039123A1
• Time in Patent Office: 2,850 Days
• Field of Search: 525/227, 525/228, 525/239, 525/85
• US Class Current: 525/85
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 27/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08L 33/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C08L 33/12 Homopolymers or copolymers of methyl methacrylate

Abstract

The present invention provides polymeric compositions having a high polymer size and a low Tg. These novel compositions are useful as plastic additives. Also provided is a method of improving the processing of a matrix resin by adding one or more of the novel polymeric compositions.

Claims

1. A method for improving the processability of a matrix resin, comprising adding to said matrix resin a plastic additive consisting essentially of

(I) a polymeric composition having a Polymer Size Index of 3 or higher and a glass transition temperature (Tg) of less than 10°

C., wherein said polymeric composition comprises a first polymeric stage, wherein at least 50 weight percent of said first polymeric stage comprises a first polymeric component, wherein said first polymeric component consists of units derived from

(A) at least one monomer selected from the group consisting of methyl acrylate, ethyl acrylate, and butyl acrylate, and

(B) optionally, one or more additional monomer selected from the group consisting of butadiene;

dienes other than butadiene;

isoprene;

(meth)acrylic acid;

substituted C1 to C18 alkyl (meth)acrylates;

styrene;

substituted styrenes;

vinyl alcohols;

vinyl ethers;

vinyl esters;

vinyl halides;

vinyl nitriles, and C₁-C₁₈ alkyl (meth)acrylates other than methyl acrylate, ethyl acrylate, and butyl acrylate,

wherein said polymeric composition (I) reduces the time required for solid polyvinyl chloride resin to form a homogeneous melt upon exposure to heat and mechanical work, and

wherein said polymeric composition (I) lubricates polyvinyl chloride resin,

(II) optionally, at least one processing aid that is hard particles which have Tg of at least 30°

C.;

(III) optionally, at least one lubricant other than said polymeric composition (I);

(IV) optionally, at least one impact modifier that has a core that is a homopolymer or copolymer of butadiene, acrylate monomers, or a combination thereof, wherein said core has Tg less than −

20°

C., wherein said core is spherical or nearly spherical, and wherein said shell has Tg greater than 30°

C.;

(V) optionally, at least one stabilizer; and

(VI) optionally, at least one inorganic oxide, at least one inorganic carbonate, or a mixture thereof,

wherein said matrix resin is poly(vinyl chloride),

wherein, after adding said plastic additive to said matrix resin, the predominant matrix resin in the resulting blend of plastic additive and matrix resin is poly(vinyl chloride), and

wherein said improving the processability of said matrix resin comprises improving fusion in said resin and comprises providing lubricant properties.

2. The method as recited in claim 1, wherein said polymeric composition has a Polymer Size Index of 4 and a Tg of less than 0°

C.

3. The method of claim 1, wherein said first polymeric component consists essentially of units derived from monomers selected from the group consisting of methyl acrylate, ethyl acrylate, and butyl acrylate.

4. The method of claim 1, wherein said first polymeric component consists essentially of units derived from ethyl acrylate.

5. The method of claim 1, wherein the amount of said plastic additive is 0.05 solid weight percent or more, based on the solid weight of said matrix resin.

6. The method of claim 1, wherein the amount of said plastic additive is 0.1 solid weight percent or more, based on the solid weight of said matrix resin.

7. The method of claim 1, wherein the amount of said plastic additive is 0.25 solid weight percent or more, based on the solid weight of said matrix resin.

8. The method of claim 1, wherein said first polymeric component consists of units derived from monomers selected from the group consisting of methyl acrylate, ethyl acrylate, and butyl acrylate, and wherein the amount of said plastic additive is 0.05 solid weight percent or more, based on the solid weight of said matrix resin.

9. The method of claim 1, wherein said plastic additive consists of said (I), said (II), said (III), said (IV), said (V) and said (VI).

10. The method of claim 1, wherein said polymeric composition has Tg of less than −

10°

C.

11. The method of claim 1, wherein said polymeric composition has weight average molecular weight of 4,000,000 or higher.

12. The method of claim 1, wherein said first polymeric component consists of units derived from butyl acrylate and ethyl acrylate.

13. The method of claim 1, wherein said first polymeric component consists of units derived from ethyl acrylate.

17. The method of claim 1, wherein said first polymeric component consists of units derived from ethyl acrylate.

14. A method for improving the processability of a matrix resin, comprising adding to said matrix resin a plastic additive consisting essentially of

(I) a polymeric composition having a Polymer Size Index of 3 or higher and a glass transition temperature (Tg) of less than 10°

C., wherein said polymeric composition comprises a first polymeric stage, wherein at least 50 weight percent of said first polymeric stage comprises a first polymeric component, wherein said first polymeric component consists of units derived from

(A) at least one monomer selected from the group consisting of methyl acrylate, ethyl acrylate, and butyl acrylate, and

(B) optionally, one or more additional monomer selected from the group consisting of butadiene;

dienes other than butadiene;

isoprene;

(meth)acrylic acid;

substituted C1 to C18 alkyl (meth)acrylates;

styrene;

substituted styrenes;

vinyl alcohols;

vinyl ethers;

vinyl esters;

vinyl halides;

vinyl nitriles, and C₁-C₁₈ alkyl (meth)acrylates other than methyl acrylate, ethyl acrylate, and butyl acrylate,

wherein said polymeric composition (I) reduces the time required for solid polyvinyl chloride resin to form a homogeneous melt upon exposure to heat and mechanical work, and

wherein said polymeric composition (I) lubricates polyvinyl chloride resin,

(II) optionally, at least one processing aid that is hard particles which have Tg of at least 30°

C.;

(III) optionally, at least one lubricant other than said polymeric composition (I);

(IV) optionally, at least one impact modifier that has a core that is a homopolymer or copolymer of butadiene, acrylate monomers, or a combination thereof, wherein said core has Tg less than −

20°

C., wherein said core is spherical or nearly spherical, and wherein said shell has Tg greater than 30°

C.;

(V) optionally, at least one stabilizer; and

(VI) optionally, at least one inorganic oxide, at least one inorganic carbonate, or a mixture thereof,

wherein said matrix resin is a matrix resin in which the sum of all poly(vinyl chloride) resin constitutes 75% to 99.9% by weight of said matrix resin, based on the weight of said matrix resin,

wherein, after adding said plastic additive to said matrix resin, the predominant matrix resin in the resulting blend of plastic additive and matrix resin is a matrix resin in which the sum of all poly(vinyl chloride) resin constitutes 75% to 99.9% by weight of said matrix resin, and

wherein said improving the processability of said matrix resin comprises improving fusion in said resin and comprises providing lubricant properties.

15. The method of claim 14, wherein said polymeric composition has weight average molecular weight of 4,000,000 or higher.

16. The method of claim 14, wherein said first polymeric component consists of units derived from butyl acrylate and ethyl acrylate.