Electro-chemical sensor

• US 7,901,555 B2
• Filed: 12/22/2004
• Issued: 03/08/2011
• Est. Priority Date: 01/08/2004
• Status: Active Grant

• Current Assignee: Schlumberger Technology Corporation (SLB)
• Original Assignee: Schlumberger Technology Corporation (SLB)
• Inventors: Wildgoose, Gregory George, Jiang, Li, Mullins, Oliver Clinton, Pandurangappa, Malingappagari, Meredith, Andrew, Lawrence, Nathan, Jones, Timothy Gareth John, Compton, Richard
• Primary Examiner(s): Neckel; Alexa D
• Assistant Examiner(s): DIETERLE, JENNIFER M
• Application Number:
  US10/585,263
• Publication Number:
  US 20070272552A1
• Time in Patent Office: 2,267 Days
• Field of Search: 205775-791, 205/792, 204400-434
• US Class Current: 204/416
• CPC Class Codes: G01N 27/302 pH sensitive, e.g. quinhydron, antimony or hydrogen electrodes ion selective electrodes G01N27/333, glass electrodes G01N27/36
• CPC Class Codes: G01N 27/308 at least partially made of carbon
• CPC Class Codes: G01N 27/3335 the membrane containing at least one organic component G01N27/3271 takes precedence; aspects concerning the enzyme reagent in enzyme electrodes C12Q1/001

Abstract

An electro-chemical sensor is described having two molecular redox systems sensitive to the same species and having an detector to detect relative shifts in the voltammograms of the two redox systems.

Claims

1. An electro-chemical sensor comprising:

at least a first and a second redox system, wherein the first and the second redox systems comprise different redox systems that are sensitive to the same species, and wherein the first and the second redox systems are coupled with a conductive substrate and configured to function in use as a working electrode;

a counter electrode;

a reference electrode

means to apply a varying potential to the working electrode; and

means to detect peaks in a current flowing between the working and counter electrode as the applied voltage is varied, wherein the peaks in the current flowing between the working and counter electrodes are produced by oxidation or reduction of the first and the second redox systems and wherein the first and the second redox systems produce peak current flows at different applied potentials.

2. The sensor of claim 1 wherein the first and the second redox systems are bonded with or immobilized on the conductive substrate.

3. The sensor of claim 1 wherein the conductive substrate comprises a carbon-based substrate.

4. The sensor of claim 1 wherein the conductive substrate comprises a carbon powder substrate.

5. The sensor of claim 1 wherein the conductive substrate comprises a diamond-based substrate.

6. The sensor of claim 1 wherein the conductive substrate comprises a multi-walled nanotube-based substrate.

7. The sensor of claim 1 further comprising:

a detector adapted to measure a redox potential of said first and said second redox system in the presence of the species and to convert measurements into an signal indicative of the concentration of said species.

8. The sensor of claim 1 wherein one of the first and second redox systems comprises one of an anthraquinone, a phenanthrenequinone and N,N′

-diphenyl-p-phenylenediamine.

9. The sensor of claim 1 wherein the first and second redox systems are sensitive to H+.

10. A downhole tool for measuring characteristic parameters of wellbore effluents comprising an electro-chemical sensor in accordance with claim 1.

11. A downhole formation sampling tool for measuring characteristic parameters of wellbore effluents comprising an electro-chemical sensor in accordance with claim 1.

12. A downhole tool for measuring characteristic parameters of wellbore effluents comprising an electro-chemical sensor in accordance with claim 1 mounted onto a permanently installed part of the wellbore.