Method and an apparatus for removing carbon dioxide from sulphur dioxide containing flue gases

• US 7,910,079 B2
• Filed: 06/13/2006
• Issued: 03/22/2011
• Est. Priority Date: 06/15/2005
• Status: Expired due to Fees

• Current Assignee: Metso Paper Oy (Metso Corporation)
• Original Assignee: Metso Paper Oy (Metso Corporation)
• Inventors: Hämäläinen, Risto, Anttila, Mikko, Tuominiemi, Seppo
• Primary Examiner(s): Mayes; Melvin C
• Assistant Examiner(s): DAVIS, SHENG HAN
• Application Number:
  US11/451,502
• Publication Number:
  US 20060286011A1
• Time in Patent Office: 1,743 Days
• Field of Search: None
• US Class Current: 423/232
• CPC Class Codes: B01D 2251/304 of sodium
• CPC Class Codes: B01D 2251/606 Carbonates
• CPC Class Codes: B01D 53/502 characterised by a specific solution or suspension
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: F23J 15/04 using washing fluids scrubbers for removing solids only F23J15/022
• CPC Class Codes: F23J 2215/50 Carbon dioxide
• CPC Class Codes: F23J 2219/40 Sorption with wet devices, e.g. scrubbers
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y02E 20/32 Direct CO2 mitigation

Abstract

A method and an apparatus for removing carbon dioxide (CO₂) from sulphur dioxide containing (SO₂) flue gases, wherein the flue gases are washed with washing solution in a scrubber, which comprises at least two washing stages. In the first washing stage the flue gases are washed for removing the sulphur dioxide in the flue gases and after that in the second washing stage for removing carbon dioxide (CO₂). Sodium carbonate solution (Na₂CO₃) is used as washing solution in both the first and the second washing stages.

Claims

1. A method for removing carbon dioxide from sulphur dioxide containing flue gases, the method comprising:

washing the flue gases with washing solution in a scrubber, the washing comprising subjecting the flue gases to two sequential washing stages, the two sequential washing stages comprising a first washing stage and subsequent a second washing stage, wherein the first washing stage comprises washing sulphur dioxide from the flue gases with sodium carbonate solution, wherein in the first washing stage the sodium carbonate solution reacts with the sulphur dioxide in the flue gases and forms a sodium sulphite and sodium bisulphite containing solution that is removed from the scrubber, and wherein the second washing stage comprises washing carbon dioxide from the flue gases, from which sulphur dioxide has been removed in the first washing stage, with sodium carbonate solution, thereby forming sodium bicarbonate solution which is treated separately from the sodium sulphite and sodium bisulphite containing solution and is fed from the scrubber to a stripper where the sodium bicarbonate solution is processed to form a solution containing sodium carbonate and carbon dioxide gas.

2. The method according to claim 1, wherein the sodium carbonate solution formed in the stripper is led to the first washing stage and the second washing stage of the scrubber.

3. The method according to claim 1, wherein the sodium bicarbonate solution is processed in the stripper with steam.

4. The method according to claim 1, wherein sodium hydroxide solution is led to the second washing stage in order to form sodium carbonate solution.

5. The method according to claim 1, wherein the sodium bicarbonate solution is heated with at least one heat exchanger before the sodium bicarbonate solution is led to the stripper.

6. The method according to claim 1, wherein the sodium bicarbonate solution is cooled with at least one heat exchanger before the sodium bicarbonate solution is led to the second washing stage.

7. The method according to claim 5, wherein an external heat exchange medium circulation is used for heating the sodium bicarbonate solution.

8. The method according to claim 6, wherein an external heat exchange medium circulation is used for cooling the sodium carbonate solution.

9. The method according to claim 5, wherein a heat exchange medium is used in heating the sodium carbonate solution, which medium has absorbed heat in at least one heat exchanger that is a part of the heat exchange medium circulation.

10. The method according to claim 1, wherein the carbon dioxide gas from the stripper is compressed.

11. The method according to claim 1, wherein sodium sulphite and sodium bisulphite in the sodium sulphite and sodium bisulphite containing solution removed from the scrubber are oxidized into sodium sulphate, which is removed from the process.