Method of preparing ceramic powders using chelate precursors

• US 7,914,755 B2
• Filed: 03/07/2006
• Issued: 03/29/2011
• Est. Priority Date: 04/12/2001
• Status: Active Grant

• Current Assignee: Eestor Inc. (FuelPositive Corp.)
• Original Assignee: Eestor Inc. (FuelPositive Corp.)
• Inventors: Nelson, Carl W., Weir, Richard D.
• Primary Examiner(s): Mayes; Melvin C
• Assistant Examiner(s): Li; Jun
• Application Number:
  US11/369,255
• Publication Number:
  US 20070148065A1
• Time in Patent Office: 1,848 Days
• Field of Search: 423/352, 423/592.1, 423/598, 423/599, 423/594.16, 423/608, 423/356, 423/263, 423/1, 423/71, 501/134, 501/135, 501/136, 501/137, 501/102, 501/105
• US Class Current: 423/1
• CPC Class Codes: C01B 13/363 Mixtures of oxides or hydroxides by precipitation
• CPC Class Codes: C01G 1/02 Oxides
• CPC Class Codes: C04B 2235/3208 Calcium oxide or oxide-forming salts thereof, e.g. lime
• CPC Class Codes: C04B 2235/3215 Barium oxides or oxide-forming salts thereof
• CPC Class Codes: C04B 2235/3224 Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
• CPC Class Codes: C04B 2235/3225 Yttrium oxide or oxide-forming salts thereof
• CPC Class Codes: C04B 2235/3244 Zirconium oxides, zirconates, hafnium oxides, hafnates, or oxide-forming salts thereof
• CPC Class Codes: C04B 2235/3262 Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
• CPC Class Codes: C04B 2235/441 Alkoxides, e.g. methoxide, tert-butoxide
• CPC Class Codes: C04B 2235/442 Carbonates
• CPC Class Codes: C04B 2235/443 Nitrates or nitrites
• CPC Class Codes: C04B 2235/449 Organic acids, e.g. EDTA, citrate, acetate, oxalate
• CPC Class Codes: C04B 35/4682 based on BaTiO3 perovskite phase
• CPC Class Codes: C04B 35/49 containing also titanium oxides or titanates
• CPC Class Codes: H01G 4/1227 based on alkaline earth titanates
• CPC Class Codes: H01G 4/30 Stacked capacitors H01G4/33 takes precedence

Abstract

Wet-chemical methods involving the use of water-soluble hydrolytically stable metal-ion chelate precursors and the use of a nonmetal-ion-containing strong base can be used in a coprecipitation procedure for the preparation of ceramic powders. Examples of the precipitants used include tetraalkylammonium hydroxides. A composition-modified barium titanate is one of the ceramic powders that can be produced. Certain metal-ion chelates can be prepared from 2-hydroxypropanoic acid and ammonium hydroxide.

Claims

1. A method of forming a composition-modified barium titanate ceramic powder, with a formula of (Ba_1-α

-μ

-ν

A_μ

D_ν

Ca_α

)[Ti<sub>1-x-δ

-μ

′

-ν

′</sub>

Mn_δ

A′

<sub>μ

′</sub>

D′

<sub>ν

′</sub>

Zr_x]_zO₃, where A=Ag or La, A′

=Dy, Er, Ho, Y, Yb, or Ga;

D=Nd, Pr, Sm, or Gd;

D′

=Nb or Mo, 0.10≦

x≦

0.25;

0≦

μ

≦

0.01, 0≦

μ

′

≦

0.01, 0≦

ν

≦

0.01, 0≦

ν

′

≦

0.01, 0≦

δ

≦

0.01, 0.995≦

z≦

1, and 0≦

α

≦

0.005 the method comprising;

individually forming each of a plurality of water-stable constituent ion chelates, wherein each of the water-stable constituent ion chelates is formed from a constituent ionic species of the ceramic powder, ammonium hydroxide, and a chelate agent, a plurality of water-stable constituent ion chelates including ionic species zirconium, manganese, yttrium, lanthanum, and neodymium, the chelate agent comprising 2-hydroxypropanoic acid or an alpha-hydroxycarboxylic acid selected from the group consisting of 2-hydroxyethanoic acid, 2-hydroxybutanedioic acid, 2,3-dihydroxybutanedioic acid, 2-hydroxy-1,2,3-propanetricarboxylic acid, 2-hydroxybutanoic acid, 2-hydroxypentanoic acid, and 2-hydroxyhexanoic acid;

providing a plurality of precursor materials in an aqueous solution, a first precursor material of the plurality of precursor materials comprising Ba(NO₃)₂ and calcium nitrate, a second precursor comprising a stable titanium alpha-carboxylic acid chelate, a third precursor material of the plurality of precursor materials comprising the plurality of water-stable constituent ion chelates;

combining the plurality of precursor materials in the aqueous solution with a precipitant solution to cause coprecipitation of primary particles of the ceramic powder in a combined solution, the precipitant solution comprising tetraalkylammonium hydroxide, the primary particles comprising the first, second, and third precursors;

refluxing the coprecipitated primary particles of the ceramic powder;

separating the ceramic powder from the combined solution; and

calcining the ceramic powder, the primary particles of the ceramic powder comprising composition-modified barium titanate having a perovskite structure.

2. The method of claim 1 wherein the constituent ionic species of the plurality of water-stable constituent ion chelates further include an ionic specie selected from the group consisting of Pr, Sm, Gd, Dy, Er, Ho, Yb, Ga, Ag, Dy, Er, Ho, Nb, and Mo.

3. The method of claim 1 wherein the plurality of water-stable constituent ion chelates include zirconium(IV) bis(ammonium 2-hydroxypropanato)dihydroxide;

bis(ammonium 2-hydroxypropanato) manganese(II);

tris(ammonium 2-hydroxypropanato) yttrium(III);

tris(ammonium 2-hydroxypropanato)-lanthanum(III); and

tris(ammonium 2-hydroxypropanato) neodymium(III).

4. The method of claim 1 wherein the tetraalkylammonium hydroxide is tetramethylammonium hydroxide.

5. The method of claim 1 wherein the combining further comprises:

mixing the plurality of precursor materials in the aqueous solution and the precipitant solution in a fluid jet column.

6. The method of claim 5 further comprising:

introducing the plurality of precursor materials in solution in a first stream; and

introducing the precipitant solution in a second stream.

7. The method of claim 1 wherein the combining further comprises at least one of:

mechanically mixing the plurality of precursor materials in solution and the precipitant solution; and

ultrasonically mixing the plurality of precursor materials in solution and the precipitant solution.

8. The method of claim 1 wherein the separating the ceramic powder from the combined solution further comprises at least one of:

filtering the ceramic powder from the combined solution;

centrifuging the combined solution;

sedimenting the combined solution;

spray drying the combined solution; and

freeze drying the combined solution.

9. The method of claim 1 further comprising at least one of:

washing the separated ceramic powder;

drying the separated ceramic powder; and

sintering the separated ceramic powder.

10. The method of claim 1 wherein at least one constituent ionic species is derived from a metal alkyl oxide.

11. The method of claim 1 wherein at least one constituent ionic species is derived from a metal ion carbonate.

12. The method of claim 1 wherein the composition-modified barium titanate is doped barium-calcium-zirconium-titanate.

13. A method of forming a ceramic powder with a formula of (Ba_1-α

-μ

-ν

A_μ

D_ν

Ca_α

)[Ti<sub>1-x-δ

-μ

′

-ν

′</sub>

Mn_δ

A′

<sub>μ

′</sub>

D′

<sub>ν

′</sub>

Zr_x]_zO₃, where A=Ag or La, A′

=Dy, Er, Ho, Y, Yb, or Ga;

D=Nd, Pr, Sm, or Gd;

D′

=Nb or Mo, 0.10≦

x≦

0.25;

0≦

μ

≦

0.01, 0≦

μ

′

≦

0.01, 0≦

ν

≦

0.01, 0≦

ν

′

≦

0.01, 0≦

δ

≦

0.01, 0.995≦

z≦

1, and 0≦

α

≦

005 for use in a dielectric material, the method comprising;

for each of the constituent metal species zirconium, manganese, yttrium, lanthanum, and neodymium;

mixing a first solution with a second solution to form a third solution comprising a metal ion or oxometal ion chelate, the first solution comprising a metal ion or oxometal ion and the second solution comprising an alpha-hydroxycarboxylic acid;

stabilizing the metal ion or oxometal ion chelate by adding ammonium hydroxide, the stabilized metal ion or oxometal ion chelate remaining in solution;

forming a fourth solution comprising the stabilized metal ion or oxometal ion chelate and comprising barium nitrate, calcium nitrate, and a stabilized titanium ion chelate, the fourth solution being an aqueous solution comprising each of the stabilized metal ion or oxometal ion chelate that together include the constituent metal species zirconium, manganese, yttrium, lanthanum, and neodymium;

precipitating primary particles of the ceramic powder by adding a fifth solution comprising tetraalkylammonium hydroxide, the primary particles comprising barium, calcium, titanium, and the constituent metal species;

refluxing the primary particles of the ceramic powder; and

calcining the primary particles, the calcined primary particles comprising composition-modified barium titanate having a perovskite structure.

14. The method of claim 13 wherein the tetraalkylammonium hydroxide comprises tetramethylammonium hydroxide.

15. The method of claim 13 further comprising separating the primary particles of the ceramic powder from solution.

16. The method of claim 13 wherein refluxing the precipitated primary particles includes refluxing at 90°

C. to 95°

C.

17. The method of claim 13 wherein the metal ion or oxometal ion chelate is selected from the group consisting of zirconium(IV) bis(ammonium 2-hydroxypropanato)dihydroxide;

bis(ammonium 2-hydroxypropanato) manganese(II);

tris(ammonium 2-hydroxypropanato) yttrium(III);

tris(ammonium 2-hydroxypropanato) lanthanum(III); and

tris(ammonium 2-hydroxypropanato) neodymium(III).

18. The method of claim 13 wherein the alpha-hydroxycarboxylic acid is selected from the group consisting of 2-hydroxyethanoic acid, 2-hydroxybutanedioic acid, 2,3-dihydroxybutanedioic acid, 2-hydroxy-1,2,3-propanetricarboxylic acid, 2-hydroxybutanoic acid, 2-hydroxypentanoic acid, and 2-hydroxyhexanoic acid.

19. The method of claim 13 wherein the alpha-hydroxycarboxylic acid is 2-hydroxy-1,2,3-propanetricarboxylic acid.

20. The method of claim 13 wherein the alpha-hydroxycarboxylic acid is 2-hydroxypropanoic acid.

21. The method of claim 13 wherein the composition-modified barium titanate is doped barium-calcium-zirconium-titanate.

22. A method of forming a ceramic powder with a formula of (Ba_1-α

-μ

-ν

A_μ

D_ν

Ca_α

)[Ti<sub>1-x-δ

-μ

′

-ν

′</sub>

Mn_δ

A′

<sub>μ

′</sub>

D′

<sub>ν

′</sub>

Zr_x]_zO₃, where A=Ag or La, A′

=A′

=Dy, Er, Ho, Y, Yb, or Ga;

D=Nd, Pr, Sm, or Gd;

D′

=Nb or Mo, 0.10≦

x≦

0.25;

0≦

μ

≦

0.01, 0≦

μ

′

≦

0.01, 0≦

ν

≦

0.01, 0≦

ν

′

≦

0.01, 0≦

δ

≦

0.01, 0.995≦

z≦

1, and 0≦

α

≦

005 for use in a dielectric material, the method comprising;

individually forming each of a plurality of stabilized metal ion or oxometal ion chelates, wherein each of the stabilized metal ion or oxometal ion chelates is formed from a constituent ionic species of the ceramic powder, ammonium hydroxide, and a chelate agent, a plurality of water-stable constituent ion chelates including the ionic species zirconium, manganese, yttrium, lanthanum, and neodymium, the chelate agent comprising 2-hydroxypropanoic acid or an alpha-hydroxycarboxylic acid selected from the group consisting of 2-hydroxyethanoic acid, 2-hydroxybutanedioic acid, 2,3-dihydroxybutanedioic acid, 2-hydroxy-1,2,3-propanetricarboxylic acid, 2-hydroxybutanoic acid, 2-hydroxypentanoic acid, and 2-hydroxyhexanoic acid;

forming a first solution from barium nitrate, calcium nitrate, a stabilized titanium ion chelate, and the plurality of stabilized metal ion or oxometal ion chelates;

precipitating primary particles of the ceramic powder including barium, titanium and the metal or oxometal ions of the plurality of metal ion or oxometal ion chelates by adding a second solution comprising tetraalkylammonium hydroxide;

refluxing the primary particles in solution;

separating the primary particles from solution; and

calcining the primary particles, the calcined primary particles comprising composition-modified barium titanate having a perovskite structure.

23. The method of claim 22 wherein the tetraalkylammonium hydroxide comprises tetramethylammonium hydroxide.

24. The method of claim 22 wherein refluxing the precipitated primary particles includes refluxing at 90°

C. to 95°

C.

25. The method of claim 22, wherein the plurality of metal ion or oxometal ion chelates include zirconium(IV) bis(ammonium 2-hydroxypropanato)dihydroxide;

bis(ammonium 2-hydroxypropanato) manganese(II);

tris(ammonium 2-hydroxypropanato) yttrium(III);

tris(ammonium 2-hydroxypropanato) lanthanum(III); and

tris(ammonium 2-hydroxypropanato) neodymium(III).

26. The method of claim 22 wherein the composition-modified barium titanate is doped barium-calcium-zirconium-titanate.

27. A method of forming a ceramic powder with a formula of (Ba_1-α

-μ

-ν

A_μ

D_ν

Ca_α

)[Ti<sub>1-x-δ

-μ

′

-ν

′</sub>

Mn_δ

A′

<sub>μ

′</sub>

D′

<sub>ν

′</sub>

Zr_x]_zO₃, where A=Ag or La, A′

=A′

=Dy, Er, Ho, Y, Yb, or Ga;

D=Nd, Pr, Sm, or Gd;

D′

=Nb or Mo, 0.10≦

x≦

0.25;

0≦

μ

≦

0.01, 0≦

μ

′

≦

0.01, 0≦

ν

≦

0.01, 0≦

ν

′

≦

0.01, 0≦

δ

≦

0.01, 0.995≦

z≦

1, and 0≦

α

≦

005 for use in a dielectric material, the method comprising;

forming a first solution from barium nitrate, calcium nitrate, a stabilized titanium ion chelate, and a plurality of stabilized metal ion or oxometal ion chelates, each of the stabilized metal ion or oxometal ion chelates is formed from a constituent ionic species of the ceramic powder, a hydroxide, and a chelate agent, a plurality of water-stable constituent ion chelates including the ionic species zirconium, manganese, yttrium, lanthanum, and neodymium, the chelate agent comprising 2-hydroxypropanoic acid or an alpha-hydroxycarboxylic acid selected from the group consisting of 2-hydroxyethanoic acid, 2-hydroxybutanedioic acid, 2,3-dihydroxybutanedioic acid, 2-hydroxy-1,2,3-propanetricarboxylic acid, 2-hydroxybutanoic acid, 2-hydroxypentanoic acid, and 2-hydroxyhexanoic acid;

precipitating primary particles of the ceramic powder, the particles including barium, titanium and the metal or oxometal ions of the plurality of metal ion or oxometal ion chelates by adding a second solution comprising tetraalkylammonium hydroxide;

refluxing the primary particles in solution;

separating the primary particles from solution; and

calcining the primary particles, the calcined primary particles being composition-modified barium titanate having a perovskite structure.

28. The method of claim 27 wherein the composition-modified barium titanate is doped barium-calcium-zirconium-titanate.