Electrode for use with double electric layer electrochemical capacitors having high specific parameters

• US 7,919,014 B2
• Filed: 11/27/2007
• Issued: 04/05/2011
• Est. Priority Date: 11/27/2006
• Status: Expired due to Fees

• Current Assignee: Universal Supercapacitors, LLC
• Original Assignee: Universal Supercapacitors, LLC
• Inventors: Shumovsky, Vyacheslav I., Litvinenko, Sergey Vitalievich, Kharisov, Gamir Galievich, Razumov, Sergey Nikolaevich, Kazaryan, Samvel Avakovich
• Primary Examiner(s): Kopec; Mark
• Assistant Examiner(s): Nguyen; Khanh Tuan
• Application Number:
  US11/946,035
• Publication Number:
  US 20080266754A1
• Time in Patent Office: 1,225 Days
• Field of Search: 252/506, 252/500, 252/518.1, 252/521.3, 252/521.4, 361/263, 361/311, 361/502, 361/508, 361/529, 423/447.1, 429/12, 429/223, 429/235, 502/416, 208/216
• US Class Current: 252/506
• CPC Class Codes: H01G 11/24 characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
• CPC Class Codes: H01G 11/34 characterised by carbonisation or activation of carbon
• CPC Class Codes: H01G 11/38 Carbon pastes or blends; Binders or additives therein
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

The present invention relates to the production of electrochemical capacitors with a DEL. The proposed electrodes with DEL are based on non-metal conducting materials, including porous carbon materials, and are capable of providing for high specific energy, capacity and power parameters of electrochemical capacitors. P-type conductivity and high concentration of holes in electrode materials may be provided by thermal, ionic or electrochemical doping by acceptor impurities; irradiating by high-energy fast particles or quantums; or chemical, electrochemical and/or thermal treatment. The present invention allows for an increase in specific energy, capacity and power parameters, as well as a reduction in the cost of various electrochemical capacitors with DEL. The proposed electrodes with DEL can be used as positive and/or negative electrodes of symmetric and asymmetric electrochemical capacitors with aqueous and non-aqueous electrolytes.

Claims

1. An electrode for use in a double electric layer electrochemical capacitor, the electrode based on porous non-metal conducting materials with p-type conductivity, comprising:

an electrode material having a concentration of holes in its pore walls of not less than 1·

10¹⁹ per cm<sup>−

3</sup>;

an active electrode material containing impurity atoms that are acceptors and impurity atoms that are donors; and

a polymer binding material;

wherein the active material also includes intrinsic lattice defects that are acceptors.

2. The electrode of claim 1, wherein the concentration of holes in the pore walls of the electrode material is in the range of about 5·

10¹⁹ to about 2·

10²⁰ per cm<sup>−

3</sup>.

3. The electrode of claim 1, wherein the electrode material surface has a specific area in the range of about 600 to about 2,500 m²/g.

4. The electrode of claim 1, wherein the electrode material contains boron in an amount of about 0.08 to about 2.5%.

5. The electrode of claim 1, wherein the electrode material contains nitrogen in an amount of about 0.1 to about 5.0%.

6. The electrode of claim 1, wherein the electrode material contains silicon in an amount of about 0.001 to about 0.2%.

7. The electrode of claim 1, wherein the electrode material is doped using a thermal, ionic, or electrochemical method.

8. The electrode of claim 1, wherein the electrode material is subjected to chemical, electrochemical and/or thermal treatment.

9. The electrode of claim 1, wherein doping of the electrode material is performed by adding doping impurities to an initial electrode substance to synthesize active material until its carbonization and activation processes take place.

10. The electrode of claim 1, wherein the electrode material is subjected to irradiation by high-energy particles or quantums.

11. The electrode of claim 1, wherein the active material is fabricated of porous non-metal conducting materials selected from the group consisting of SiC, Si, titanium oxides, TiC, TiCN, TiN, MoN, RuO₂, SnO₂, carbin, fullerenes, carbon nanoparticles, carbon nanotubes, and diamond, in various mixtures or combinations and in various proportions.

12. The electrode of claim 11, further comprising a polymer binding material.

13. The electrode of claim 11, wherein the concentration of holes in the pore walls of the electrode material is in the range of about 1·

10¹⁹ to about 5·

10¹⁹ per cm<sup>−

3</sup>.

14. An electrode for use in a double electric layer electrochemical capacitor, the electrode based on porous non-metal conducting materials with p-type conductivity, comprising:

an electrode material having a concentration of holes in its pore walls of not less than 1·

10¹⁹ per cm<sup>−

3</sup> and a specific area of between about 600 to about 2,500 m²/g;

a polymer binder; and

an active electrode material doped at least with Boron;

wherein the active material also includes intrinsic lattice defects that are acceptors.

15. The electrode of claim 14, wherein the concentration of holes in the pore walls of the electrode material is in the range of about 5·

10¹⁹ to about 2·

10 per cm<sup>−

3</sup>.

16. The electrode of claim 14, wherein the electrode material contains boron in an amount of about 0.08 to about 2.5%.

17. The electrode of claim 14, wherein the electrode material further comprises nitrogen in an amount of about 0.1 to about 5.0%.

18. The electrode of claim 14, wherein the electrode material further comprises silicon in an amount of about 0.001 to about 0.2%.

19. The electrode of claim 14, wherein the electrode material is doped using a thermal, ionic, or electrochemical method.

20. An electrode for use in a double electric layer electrochemical capacitor, the electrode based on porous non-metal conducting materials with p-type conductivity, comprising:

an electrode material having a concentration of holes in its pore walls of not less than 1·

10¹⁹ per cm<sup>−

3</sup> and a specific area of between about 600 to about 2,500 m²/g;

a polymer binder; and

an active electrode material doped with a dopant selected from the group consisting of Boron, Nitrogen, Phosphorus, Silicon, and various combinations thereof;

wherein the active material also includes intrinsic lattice defects that are acceptors.

21. The electrode of claim 20, wherein the electrode material is doped using a thermal, ionic, or electrochemical method.

22. An electrode for use in a double electric layer electrochemical capacitor, the electrode based on porous non-metal conducting materials with p-type conductivity, comprising:

an electrode material having a concentration of holes in its pore walls of not less than 1·

10¹⁹ per cm<sup>−

3</sup> and a specific surface area in the range of about 600 to about 2,500 m²/g; and

an active electrode material containing impurity atoms that are acceptors and impurity atoms that are donors;

wherein the active material also includes intrinsic lattice defects that are acceptors.

23. An electrode for use in a double electric layer electrochemical capacitor, the electrode based on porous non-metal conducting materials with p-type conductivity, comprising:

an electrode material having a concentration of holes in its pore walls of not less than 1·

10¹⁹ per cm<sup>−

3</sup>, said electrode material containing a dopant selected from the group consisting of boron in an amount of about 0.08 to about 2.5%, nitrogen in an amount of about 0.1 to about 5.0%, and silicon in an amount of about 0.001 to about 0.2%; and

an active electrode material containing impurity atoms that are acceptors and impurity atoms that are donors;

wherein the active material also includes intrinsic lattice defects that are acceptors.