Hybrid nanoparticles

• US 7,919,184 B2
• Filed: 08/21/2007
• Issued: 04/05/2011
• Est. Priority Date: 08/21/2006
• Status: Expired due to Fees

• Current Assignee: Andrew Klein, Edward David Sudol, Eric Scott Daniels, Kejian Bian, Li Zhang, Satish C. Mohapatra, Victoria Laurentia Dimonie
• Original Assignee: Andrew Klein, Edward David Sudol, Eric Scott Daniels, Kejian Bian, Li Zhang, Satish C. Mohapatra, Victoria Laurentia Dimonie
• Inventors: Zhang, Li, Klein, Andrew, Sudol, Edward David, Bian, Kejian, Daniels, Eric Scott, Dimonie, Victoria Laurentia, Mohapatra, Satish C.
• Primary Examiner(s): XU, LING X
• Application Number:
  US11/894,883
• Publication Number:
  US 20080272331A1
• Time in Patent Office: 1,323 Days
• Field of Search: None
• US Class Current: 428/402.24
• CPC Class Codes: B01J 13/04 by physical processes, e.g. drying, spraying
• CPC Class Codes: C09K 5/10 Liquid materials
• CPC Class Codes: Y10T 428/2989 Microcapsule with solid core [includes liposome]
• CPC Class Codes: Y10T 428/2991 Coated
• CPC Class Codes: Y10T 428/2998 including synthetic resin or polymer
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31692 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31801 Of wax or waxy material
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers

Abstract

A method and composition for making hybrid nanoparticles and use of such nanoparticles are disclosed herein. In one embodiment of the invention, the hybrid nanoparticles comprise a phase change material (PCM) and a metal layer encapsulating the phase change material. In another embodiment of the invention, the hybrid nanoparticles comprise a phase change material, a polymer layer encapsulating the phase change material, and an outer metal layer encapsulating the polymer layer. In another embodiment of the invention, the hybrid nanoparticles comprise an inner core of a PCM encapsulated by a polymer shell containing embedded nanoparticles that have a high thermal conductivity.

Claims

1. A hybrid nanoparticle comprising:

a phase change material constituting an inner core of said hybrid nanoparticle, wherein the phase change material comprises one of hydrocarbons, wax, paraffins, salt hydrates, silicones, and polymers; and

an impermeable metal shell, the impermeable metal shell encapsulating the phase change material and containing said phase change material in different phases of said phase change material.

2. The nanoparticle of claim 1 wherein the average diameter of the nanoparticle is from about 10 nanometers to about 1000 nanometers.

3. The nanoparticle of claim 1 wherein the metal shell comprises a metal or a metal alloy with a thermal conductivity of 100 watts/m. K. or higher.

4. The nanoparticle of claim 3 wherein the metal comprises one of copper, gold, silver, aluminum, iron, and nickel.

5. The hybrid nanoparticle of claim 1, wherein a melting point of said phase change material differs substantially from a melting point of the impermeable metal shell.

6. A hybrid nanoparticle comprising:

a phase change material constituting an inner core of said hybrid nanoparticle, wherein the phase change material comprises one of hydrocarbons, wax, paraffins, salt hydrates, silicones, and polymers;

a polymer layer, the polymer layer encapsulating the phase change material, and

an impermeable metal shell encapsulating the polymer layer, said polymer layer and said impermeable metal shell containing said phase change material in different phase change states.

7. The nanoparticle of claim 6 wherein the average diameter of the nanoparticle is from about 10 nanometers to about 1000 nanometers.

8. The nanoparticle of claim 6 wherein the polymer comprises polyvinyl pyrrolidone.

9. The nanop article of claim 6 wherein the metal shell comprises a metal or a metal alloy with a thermal conductivity of 100 W/m.K or higher.

10. The nanop article of claim 9 wherein the metal comprises one of copper, gold, silver, aluminum, iron and nickel.

11. A heat transfer fluid containing suspended nanoparticles, said nanoparticles comprising:

a phase change material, a polymer layer, the polymer layer encapsulating the phase change material, and a metal shell, the metal shell encapsulating the polymer layer.

12. A hybrid nanoparticle comprising:

a phase change material constituting an inner core of said hybrid nanoparticle, and

a polymer shell embedded with nanoparticles, said polymer shell encapsulating the phase change material, wherein the average diameter of the hybrid nanoparticle is from about 10 nanometers to about 1000 nanometers, and wherein the average diameter of the embedded nanoparticles is from about 1 nanometer to about 20 nanometers.

13. The nanoparticle of claim 12 wherein the phase change material comprises one of hydrocarbons, wax, paraffins, salt hydrates, polymers and silicones.

14. The nanoparticle of claim 12 wherein the polymer shell comprises one of polymethyl methacrylate, polystyrene, and polyvinyl pyrrolidone.

15. The nanoparticle of claim 12 wherein the embedded nanoparticles in the polymer layer comprise materials with a thermal conductivity greater than 100 W/m.K.

16. The nanoparticle of claim 15 wherein the nanoparticles embedded in the polymer layer comprises one of copper, diamond, carbon nanotube, silver, gold, aluminum, nickel, silicon and iron.

17. A heat transfer fluid containing suspended hybrid nanoparticles, said hybrid nanoparticles comprising:

a phase change material,

a polymer shell embedded with nanoparticles, said polymer shell encapsulating the phase change material, wherein the average diameter of the hybrid nanoparticle is from about 10 nanometers to about 100 nanometers, and wherein the average diameter of the embedded nanoparticles is from about 1 nanometer to about 20 nanometers.

18. A hybrid nanoparticle comprising:

a phase change material constituting an inner core of said hybrid nanoparticle,

a polymer layer, the polymer layer encapsulating the phase change material, wherein the phase change material comprises one of hydrocarbons, wax, paraffins, salt hydrates, polymers and silicones, and wherein the polymer comprises one of polyvinyl pyrrolidone, polymethyl methacrylate, polyvinyl imidazole, and a polymerized mixture of styrene and vinyl imidazole comonomers; and

a metal shell, the metal shell encapsulating the polymer layer.