Compositions including hardness ions and gluconate and methods employing them to reduce corrosion and etch

• US 7,919,448 B2
• Filed: 03/17/2010
• Issued: 04/05/2011
• Est. Priority Date: 05/04/2007
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Lawrence, Michel M., Smith, Kim R., Besse, Michael E., Bartelme, Michael
• Primary Examiner(s): Boyer; Charles I
• Application Number:
  US12/726,179
• Publication Number:
  US 20100173820A1
• Time in Patent Office: 384 Days
• Field of Search: 510/220, 510/227, 510/235, 510/255, 510/287, 510/401, 510/514
• US Class Current: 510/227
• CPC Class Codes: C02F 2303/14 Maintenance of water treatment installations
• CPC Class Codes: C02F 2303/22 Eliminating or preventing deposits, scale removal, scale prevention C02F1/042, C02F1/4602, C02F5/00 take precedence
• CPC Class Codes: C02F 5/02 Softening water by precipitation of the hardness
• CPC Class Codes: C02F 5/06 using calcium compounds
• CPC Class Codes: C11D 2111/14 Hard surfaces
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 7/10 Salts
• CPC Class Codes: C23F 11/08 in other liquids
• CPC Class Codes: C23F 11/124 Carboxylic acids
• CPC Class Codes: C23F 11/18 using inorganic inhibitors
• CPC Class Codes: C23G 1/20 Other heavy metals
• CPC Class Codes: C23G 1/22 Light metals

Abstract

The present invention relates to compositions including a water soluble magnesium salt, water soluble calcium salt, and gluconate, which have a beneficial effect on corrosion during cleaning. The present compositions can reduce corrosion of glass, aluminum, or steel. The present invention also relates to methods employing these compositions.

Claims

1. A hard surface cleaner comprising surfactant and about 0.01 to about 20 wt-% corrosion inhibitor;

the corrosion inhibitor consisting essentially of;

about 2 to about 85 wt-% water soluble calcium salt;

about 10 to about 95 wt % water soluble magnesium salt; and

about 2 to about 50 wt-% gluconate;

wherein the weight ratio of water soluble magnesium salt to water soluble calcium salt is about 1-2;

1-2;

the weight ratio of water soluble magnesium salt to gluconate is greater than 1;

1;

the weight ratio of water soluble calcium salt to gluconate is about 1-19;

1-13, and the detergent comprises less than about 0.5 wt-% phosphorous-containing compounds.

2. The cleaner of claim 1, comprising about 0.1 to about 10 wt-% corrosion inhibitor.

3. The cleaner of claim 1, further comprising an alkalinity source.

4. The cleaner of claim 1, wherein the weight ratio of water soluble magnesium salt to water soluble calcium salt is about 1-1.5:

1-1.5;

the weight ratio of water soluble magnesium salt to gluconate is greater than 1.25;

1; and

the weight ratio of water soluble calcium salt to gluconate is about 1-15;

1-8.

5. The cleaner of claim 1, wherein the weight ratio of water soluble magnesium salt to water soluble calcium salt is about 1-1.25:

1-1.25;

the weight ratio of water soluble magnesium salt to gluconate is greater than 1.5;

1; and

the weight ratio of water soluble calcium salt to gluconate is about 3-10;

1-5.

6. The cleaner of claim 1, wherein the weight ratio of water soluble magnesium salt to water soluble calcium salt is about 1:

1;

the weight ratio of water soluble magnesium salt to gluconate is greater than 2;

1; and

the weight ratio of water soluble calcium salt to gluconate is about 3-8;

2-4.

7. The cleaner of claim 1, wherein the gluconate is selected from the group consisting of sodium gluconate, lithium gluconate, potassium gluconate or a mixture thereof.

8. The cleaner of claim 1, wherein the water soluble magnesium salt is selected from the group consisting of magnesium acetate, magnesium benzoate, magnesium bromide, magnesium bromate, magnesium chlorate, magnesium chloride, magnesium chromate, magnesium citrate, magnesium formate, magnesium hexafluorosilicate, magnesium iodate, magnesium iodide, magnesium lactate, magnesium molybdate, magnesium nitrate, magnesium perchlorate, magnesium phosphinate, magnesium salicylate, magnesium sulfate, magnesium sulfite, magnesium thiosulfate, a hydrate thereof, and a mixture thereof.

9. The cleaner of claim 1, wherein the water soluble calcium salt is selected from the group consisting of calcium acetate, calcium benzoate, calcium bromate, calcium bromide, calcium chlorate, calcium chloride, calcium chromate, calcium dihydrogen phosphate, calcium dithionate, calcium formate, calcium gluconate, calcium glycerophosphate, calcium hydrogen sulfide, calcium iodide, calcium lactate, calcium metasilicate, calcium nitrate, calcium nitrite, calcium pantothenate, calcium perchlorate, calcium permanganate, calcium phosphate, calcium phosphinate, calcium salicylate, calcium succinate, a hydrate thereof, and a mixture thereof.

10. The cleaner of claim 1, comprising less than about 0.5 wt-% zinc-containing compounds.

11. The cleaner of claim 1, comprising less than about 0.5 wt-% aluminum-containing compounds.