Cleaning compositions containing water soluble magnesium compounds and methods of using them

• US 7,922,827 B2
• Filed: 05/24/2010
• Issued: 04/12/2011
• Est. Priority Date: 05/04/2007
• Status: Active Grant

• Current Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Original Assignee: Ecolab USA Incorporated (Ecolab, Inc.)
• Inventors: Sanders, Lisa M., Smith, Kim R., Olson, Keith E., Besse, Michael E., Tjelta, Brenda L.
• Primary Examiner(s): CARRILLO, BIBI SHARIDAN
• Application Number:
  US12/785,867
• Publication Number:
  US 20100234262A1
• Time in Patent Office: 323 Days
• Field of Search: 134/18, 134/25.1, 134/25.2, 134/25.3, 134/36, 134/42, 510/108, 510/220, 510/225
• US Class Current: 134/18
• CPC Class Codes: C02F 2303/14 Maintenance of water treatment installations
• CPC Class Codes: C02F 2303/22 Eliminating or preventing deposits, scale removal, scale prevention C02F1/042, C02F1/4602, C02F5/00 take precedence
• CPC Class Codes: C02F 5/02 Softening water by precipitation of the hardness
• CPC Class Codes: C02F 5/06 using calcium compounds
• CPC Class Codes: C11D 2111/14 Hard surfaces
• CPC Class Codes: C11D 3/044 Hydroxides or bases
• CPC Class Codes: C11D 3/046 Salts
• CPC Class Codes: C11D 3/10 Carbonates ; Bicarbonates
• CPC Class Codes: C11D 7/10 Salts
• CPC Class Codes: C23F 11/08 in other liquids
• CPC Class Codes: C23F 11/124 Carboxylic acids
• CPC Class Codes: C23F 11/18 using inorganic inhibitors
• CPC Class Codes: C23G 1/20 Other heavy metals
• CPC Class Codes: C23G 1/22 Light metals

Abstract

The present invention relates to cleaning compositions and methods employing a water soluble magnesium compound. Such compositions can be used for reducing scale, rinsing, hard surface cleaning, ware washing, and corrosion inhibition.

Claims

1. A method of cleaning a hard surface comprising:

contacting the hard surface with an aqueous composition comprising water comprising a calcium ion, a water soluble magnesium salt, at least about 5 wt % to less than about 60 wt % of a source of alkalinity, and about 0 wt % to about 20 wt % surfactant, wherein the aqueous composition during contacting comprises magnesium ion in a molar amount equal to or in excess over a molar amount of said calcium ion, and wherein the composition is substantially free of a builder and a phosphate or phosphate containing compound; and

achieving said hard surface with an acceptable amount of hard water spotting, wherein the acceptable amount of hard water spotting comprises up to about one quarter of the surface containing spots.

2. The method of claim 1, wherein the hard surface is selected from the group consisting of ceramic tile, a window, a kitchen surface, ware, medical instrument, vehicle, and bathroom surface.

3. The method of claim 1, wherein the water soluble magnesium salt comprises an anion that forms a soluble calcium salt.

4. The method of claim 1, wherein:

the water soluble magnesium salt comprises an anion that forms a sparingly soluble calcium salt; and

the aqueous composition during contacting comprises said magnesium ion in a molar amount equal to or greater than two-times the molar amount of said calcium ion.

5. The method of claim 1, wherein the aqueous composition during contacting comprises said magnesium ion at a molar ratio of magnesium to calcium greater than or equal to one.

6. The method of claim 1, wherein the hard surface is selected from the group consisting of floors, counters, glass, and walls.

7. The method of claim 1, wherein the source of alkalinity is selected from the group consisting of an alkali metal carbonate, an alkali metal hydroxide, and combinations thereof.

8. The method of claim 1, wherein the surfactant is selected from the group consisting of nonionic surfactants, cationic surfactants, anionic surfactants, amphoteric surfactants, and combinations thereof.

9. The method of claim 3, wherein the water soluble magnesium salt is selected from the group consisting of magnesium acetate, magnesium benzoate, magnesium bromide, magnesium bromate, magnesium chlorate, magnesium chloride, magnesium chromate, magnesium citrate, magnesium formate, magnesium hexafluorosilicate, magnesium iodate, magnesium iodide, magnesium lactate, magnesium molybdate, magnesium nitrate, magnesium perchlorate, magnesium phosphinate, magnesium salicylate, magnesium sulfate, magnesium sulfite, magnesium thiosulfate, and hydrates and mixtures thereof.

10. The method of claim 7, wherein the alkali metal carbonate is selected from the group consisting of sodium carbonate, potassium carbonate, lithium carbonate, sodium bicarbonate, potassium bicarbonate, lithium bicarbonate, sodium sesquicarbonate, potassium sesquicarbonate, lithium sesquicarbonate, and combinations thereof.

11. The method of claim 7, wherein the alkali metal hydroxide is selected from the group consisting of sodium hydroxide, lithium hydroxide, potassium hydroxide, and combinations thereof.