Latent heat storage material and process for manufacture of the latent heat storage material

• US 7,923,112 B2
• Filed: 03/22/2007
• Issued: 04/12/2011
• Est. Priority Date: 05/12/2005
• Status: Expired due to Fees

• Current Assignee: Sgl Carbon Se
• Original Assignee: Sgl Carbon Se
• Inventors: Ottinger, Oswin H., Bacher, Jurgen J., Christ, Martin U.
• Primary Examiner(s): Ortiz; Angela
• Assistant Examiner(s): MILLER, DANIEL H
• Application Number:
  US11/689,993
• Publication Number:
  US 20080230203A1
• Time in Patent Office: 1,482 Days
• Field of Search: 428/408, 165/185
• US Class Current: 428/408
• CPC Class Codes: C09K 5/063 Materials absorbing or liberating heat during crystallisation; Heat storage materials
• CPC Class Codes: F25D 2303/085 Compositions of cold storage materials
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

The invention relates to a latent heat storage material comprising a first phase change material, at least one second phase change material different from the first phase change material, and an expanded graphite material wherein the first phase change material and the at least one second phase change material are intermixed and the latent heat storage material exhibits a phase transition over a range of temperatures. The invention also relates to a process for the preparation of a latent heat storage material comprising combining a mixture of an expanded graphite material and a first phase change material with at least one different second phase change material.

Claims

1. A latent heat storage material comprising:

a first phase change material;

at least one second phase change material different from the first phase change material; and

an expanded graphite material comprising particles prepared by cutting a planar foil-like web obtained by compression of expanded graphite particles into fragments having an average diameter of between about 5 microns (μ

m) and about 20 millimeters (mm),

wherein the first phase change material and the at least one second phase change material are immiscible materials that do not form a single phase after mixing.

2. The latent heat storage material of claim 1, wherein the first phase change material comprises a first phase change temperature and the at least one second phase change material comprises at least one second phase change temperature and a difference of the first phase change temperature and the at least one second phase change temperature is in a range up to 50 K.

3. The latent heat storage material of claim 1, wherein the expanded graphite material comprises expanded graphite particles with a bulk density of between about 2 grams per liter and about 200 grams per liter.

4. The latent heat storage material of claim 1, wherein the first phase change material and the at least one second phase change material are selected from the group consisting of paraffins, sugar alcohols, polymers, water, organic acids and mixtures thereof, aqueous solutions of salts, salt hydrates, mixtures of salt hydrates, inorganic and organic salts, mixtures of salts and eutectic blends of salts, clathrate hydrates and alkali metal hydroxides.

5. The latent heat storage material of claim 1, wherein the first phase change material is a salt hydrate and the at least one second phase change material is a paraffin.

6. The latent heat storage material of claim 1, wherein the first phase change material is sodium acetate trihydrate and the at least one second phase change material is a paraffin with a melting point in the range of between about 25°

C. and about 85°

C.

7. The latent heat storage material of claim 1, wherein a volume fraction of expanded graphite material in the latent heat storage material is at least two percent by volume.

8. A process for the preparation of a latent heat storage material comprising:

combining a mixture of an expanded graphite material and a first phase change material with at least one different second phase change material wherein the first phase change material and at least one second phase change material are immiscible materials that do not form a single phase after mixing,

wherein the expanded graphite material comprises particles prepared by cutting a planar foil-like web obtained by compression of expanded graphite particles into fragments having an average diameter of between about 5 microns (μ

m) and about 20 millimeters (mm).

9. The process of claim 8, further comprising:

forming a mixture of particles of the phase change materials and expanded graphite material in granular form;

filling a mold with the granules; and

filling gaps remaining within the mold with the at least one second phase change material in a molten state.

10. The process of claim 8, wherein the first phase change material comprises a greater temperature than the at least one second phase change material, the method further comprising:

forming a porous body of expanded graphite with a density of from about 5 grams per liter to about 500 grams per liter;

infiltrating the porous body with the first phase change material,

tempering the infiltrated body at a temperature below a melting point of the first phase change material and above the melting point of the second phase change material; and

infiltrating the porous body at least a second time with the at least one second phase change material.

11. The process of claim 8, further comprising:

forming a porous body of expanded graphite with a density of from about 5 grams per liter to about 500 grams per liter;

infiltrating the porous body with a first phase change material comprising a better wetting property than a wetting property of the porous body, wherein the volume amount or the first phase change material is lower than the porous volume of the porous body; and

infiltrating the porous body at least a second time with the at least one second phase change material.

12. The process of claim 8, wherein the first phase change material is a paraffin and the at least one second phase change material is a salt hydrate.

13. The process of claim 8, wherein the first phase change material is a paraffin with a melting point in a range of between about 65°

C. and about 85°

C. and the at least one second phase change material comprises sodium acetate trihydrate.

14. The process of claim 8, wherein the first phase change material and the at least one second phase change material have different phase change temperatures.

15. The process of claim 8, wherein the expanded graphite material comprises expanded graphite particles with a bulk density between about 2 grams per liter and 200 grams per liter.

16. The process of claim 8, wherein the expanded graphite material comprises particles prepared by cutting a planar foil-like web obtained by compression of expanded graphite particles into fragments having an average diameter between about 5 microns (μ

m) and about 20 millimeters (mm).

17. The process of claim 8, wherein the expanded graphite material comprises expanded graphite particles with a hulk density between about 2 grams per liter and about 200 grams per liter and particles prepared by cutting a planar foil-like web obtained by compression of expanded graphite particles into fragments having an average diameter between about 5 microns (μ

m) and about 20 millimeters (mm).

18. The process of claim 8, wherein the first phase change material and the at least one second phase change material are selected from the group consisting of paraffins, sugar alcohols, polymers, water, organic acids and mixtures thereof, aqueous solutions of salts, salt hydrates, mixtures of salt hydrates, inorganic and organic salts, mixtures of salts and eutectic blends of salts, clathrate hydrates and alkali metal hydroxides.

19. The process of claim 8, wherein a volume fraction of expanded graphite material in the mixture of particles of the phase change material and expanded graphite material is at least two percent by volume.

20. A latent heat storage material comprising:

a porous body of expanded graphite having a density of from about 5 grams per liter to about 500 grams per liter infiltrated with a first phase change material and at least one second phase change material, wherein the first phase change material and the at least one second phase change material are immiscible materials that do not form a single phase after mixing.

21. The latent heat storage material of claim 20, wherein the first phase change material comprises a first phase change temperature and the at least one second phase change material comprises at least one second phase change temperature and a difference of the first phase change temperature and the at least one second phase change temperature is in a range up to 50 K.

22. The latent heat storage material of claim 20, wherein the first phase change material and the at least one second phase change material are selected from the group consisting of paraffins, sugar alcohols, polymers, water, organic acids and mixtures thereof, aqueous solutions of salts, salt hydrates, mixtures of salt hydrates, inorganic and organic salts, mixtures of salts and eutectic blends of salts, clathrate hydrates and alkali metal hydroxides.