Multilayer coating system

• US 7,923,113 B2
• Filed: 12/12/2006
• Issued: 04/12/2011
• Est. Priority Date: 12/15/2005
• Status: Active Grant

• Current Assignee: AKZO Nobel Coatings International BV (Nouryon BV)
• Original Assignee: AKZO Nobel Coatings International BV (Nouryon BV)
• Inventors: Jonker, Josef Pancratius Maria, Wijnands, Peter, Dogan, Nazire, Van Der Krogt, Robertus Petrus Cornelis
• Primary Examiner(s): Tran; Thao T.
• Application Number:
  US12/097,431
• Publication Number:
  US 20090142600A1
• Time in Patent Office: 1,582 Days
• Field of Search: 428/422.8, 428/423.1, 428/425.9, 427/333, 427/340, 427/517
• US Class Current: 428/423.1
• CPC Class Codes: B05D 1/36 Successively applying liquids or other fluent materials, e.g. without intermediate treatment
• CPC Class Codes: B05D 3/067 Curing or cross-linking the coating
• CPC Class Codes: B05D 7/532 the two layers being cured or baked together, i.e. wet on wet
• CPC Class Codes: C08G 18/3876 containing mercapto groups
• CPC Class Codes: C08G 18/4676 containing sulfur
• CPC Class Codes: C08G 18/792 formed by oligomerisation of aliphatic and/or cycloaliphatic isocyanates or isothiocyanates
• CPC Class Codes: C09D 175/06 from polyesters
• CPC Class Codes: Y10T 428/31547 Of polyisocyanurate
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]
• CPC Class Codes: Y10T 428/31609 Particulate metal or metal compound-containing

Abstract

The invention relates to a multi-layer coating system comprising at least one layer a) comprising a coating composition a) comprising at—least one isocyanate-functional compound and at least one thiol-functional compound, and—at least one layer b) comprising an aqueous coating composition b), wherein at least one layer a) and at least one layer b) have at least one common layer boundary, and wherein coating composition b) comprises at least 17 mmol/kg, calculated on the weight of coating composition b), of a catalyst for the addition reaction of the at least one thiol-functional compound and the at least one isocyanate-functional compound.

Claims

1. A multilayer coating system comprising

at least one layer a) comprising a coating composition a) comprising at least one isocyanate-functional compound and at least one thiol-functional compound, and a photolatent base, and

at least one layer b) comprising an aqueous coating composition b), wherein the at least one layer a) and the at least one layer b) have at least one common layer boundary, and wherein the coating composition b) comprises at least 17 mmol/kg, calculated on the weight of coating composition b), of a catalyst for the addition reaction of the at least one thiol-functional compound and the at least one isocyanate-functional compound, wherein said catalyst is a tertiary amine.

2. The multilayer coating system according to claim 1, wherein the coating composition a) comprises pentaerythritol tetrakis(3-mercapto propionate).

3. The multilayer coating system according to claim 1, wherein the coating composition a) comprises a thiol-functional polyester.

4. The multilayer coating system according to claim 3, wherein the thiol-functional polyester comprises hydroxyl groups.

5. The multilayer coating system according to claim 1, wherein the coating composition a) comprises pentaerythritol tetrakis(3-mercapto propionate) and a thiol-functional polyester.

6. The multilayer coating system according to claim 1, wherein the photolatent base is an α

-amino acetophenone.

7. The multilayer coating system according to claim 1, wherein the at least one layer a) is a clear coat layer.

8. The multilayer coating system according to claim 1, wherein the tertiary amine is N,N-dimethyl ethanolamine.

9. The multilayer coating system according to claim 1, wherein the at least one layer b) is a colour- and/or effect-imparting base coat layer.

10. The multilayer coating system according to claim 1, wherein the coating composition b) comprises a curing agent capable of chemical reaction with functional groups present in coating composition b).

11. A multilayer coating system comprising

at least one layer a) comprising a coating composition a) comprising at least one isocyanate-functional compound and at least one thiol-functional compound, and a photolatent base, and

at least one layer b) comprising an aqueous coating composition b), wherein the at least one layer a) and the at least one layer b) have at least one common layer boundary, and wherein the coating composition b) comprises an effective amount of at least one component of a co-catalyst comprising a phosphine component and a Michael acceptor component, and the other of the phosphine component and the Michael acceptor component is present in coating composition a).

12. The multilayer coating system according to claim 11, wherein the at least one layer b) is a colour- and/or effect-imparting base coat layer.

13. The multilayer coating system according to claim 11, wherein the coating composition b) comprises a curing agent capable of chemical reaction with functional groups present in coating composition b).

14. A process of preparing a multilayer coating system comprising the steps of

i. applying a layer b) of an aqueous coating composition b) comprising at least 17 mmol/kg, calculated on the weight of coating composition b), of a catalyst for the addition reaction of a thiol-functional compound and an isocyanate-functional compound to a substrate, wherein said catalyst is a tertiary amine,

ii. prior to or subsequent to the application of layer b), applying a layer a) of a coating composition a) comprising at least one isocyanate-functional compound, at least a photolatent base, and at least one thiol-functional compound so that layer a) and layer b) have at least one common layer boundary, and

iii. curing layer a) at room temperature or an elevated temperature, supported by irradiation with UV and/or visible light.

15. The process according to claim 14, wherein the process is implemented for finishing or refinishing of automobiles, large transportation vehicles, or parts thereof.

16. A method of increasing the drying speed in a multilayer coating system comprising applying a clear coat composition a) comprising at least one isocyanate-functional compound, at least a photolatent base, and at least one thiol-functional compound on top of a base coat layer b) prepared from an aqueous base coat composition b) comprising at least 17 mmol/kg, calculated on the weight of coating composition b), of a catalyst for the addition reaction of the at least one thiol-functional compound and the at least one isocyanate-functional compound, wherein said catalyst is a tertiary amine.