High-viscosity elastomeric adhesive composition

• US 7,923,505 B2
• Filed: 11/13/2007
• Issued: 04/12/2011
• Est. Priority Date: 07/02/2002
• Status: Expired due to Fees

• Current Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Original Assignee: Kimberly-Clark Worldwide Incorporated (Kimberly-Clark Corporation)
• Inventors: Hall, Gregory K., Zhou, Peiguang
• Primary Examiner(s): Zimmer; Marc S
• Application Number:
  US11/938,928
• Publication Number:
  US 20080064808A1
• Time in Patent Office: 1,246 Days
• Field of Search: None
• US Class Current: 524/571
• CPC Class Codes: A61L 15/585 Mixtures of macromolecular compounds
• CPC Class Codes: C08L 53/02 of vinyl-aromatic monomers and conjugated dienes
• CPC Class Codes: C09J 153/00 Adhesives based on block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
• CPC Class Codes: Y10T 428/28 Web or sheet containing structurally defined element or component and having an adhesive outermost layer
• CPC Class Codes: Y10T 428/2852 Adhesive compositions
• CPC Class Codes: Y10T 428/2878 including addition polymer from unsaturated monomer
• CPC Class Codes: Y10T 442/2738 Coating or impregnation intended to function as an adhesive to solid surfaces subsequently associated therewith

Abstract

High-viscosity elastomeric adhesive compositions including a high softening point tackifier resin in combination with a base polymer can be used to create elastomeric composite laminates having effective adhesion and elastic properties. The elastomeric adhesive compositions suitably have a viscosity between about 100,000 and about 500,000 cps at between about 300 degrees Fahrenheit (149 degrees Celsius) and about 350 degrees Fahrenheit (177 degrees Celsius). Facing layers, such as nonwoven webs, films, elastic strands, fastening material, absorbent material, and the like, can be laminated to one or both surfaces of the elastomeric compositions to form elastomeric composite laminates. A method of making such compositions and laminates involves forming the compositions into elastomeric adhesive films and/or strands.

Claims

1. An elastomeric adhesive composition, comprising:

a base polymer; and

a high softening point tackifier resin having a softening point of about 80 degrees Celsius or greater, and a viscosity of about 1500 cps or greater at 182 degrees Celsius;

wherein the elastomeric adhesive composition has a viscosity between about 100,000 and about 500,000 cps at between about 149 and about 177 degrees Celsius; and

wherein the elastomeric adhesive composition further comprises an absorbent material

wherein the absorbent material comprises hydrophilic fibers, combinations of hydrophilic and hydrophobic fibers, or a super-absorbent material selected from the group consisting of natural polymers, synthetic polymer, modified natural polymers, and combinations thereof.

2. The composition of claim 1, wherein the base polymer is present in the composition in an amount between about 50% and about 75% by weight.

3. The composition of claim 1, wherein the base polymer comprises a styrene content of between about 10% and about 45% by weight.

4. The composition of claim 1, wherein the base polymer comprises at least one of the group consisting of polystyrene-polyethylene-polypropylene-polystyrene (SEPS) block copolymer, styrene-isoprene-styrene (SIS) block copolymer, styrene-butadiene-styrene (SBS) block copolymer, styrene-ethylene-butylene-styrene (SEBS) block copolymer, ethylene-propylene-diene (EPDM) copolymers, thermoplastic polyurethane, and combinations thereof.

5. The composition of claim 1, wherein the high softening point tackifier is present in the composition in an amount between about 20% and about 40% by weight.

6. The composition of claim 1, wherein the high softening point tackifier comprises at least one type of hydrocarbon selected from the group consisting of petroleum distillates, rosin, rosin esters, polyterpenes derived from wood, polyterpenes derived from synthetic chemicals, and combinations thereof.

7. The composition of claim 1, further comprising a low softening point additive having a softening point of about 60 degrees Celsius or less and a viscosity of about 1000 cps or less at 182 degrees Celsius, present in an amount between about 0% and about 20% by weight.

8. The composition of claim 1, wherein the composition is formed as at least one of the group consisting of:

a plurality of extruded strands, an extruded film, a foam, a plurality of beads, and combinations thereof.

9. The composition of claim 1, wherein the composition is formed as a combination of a plurality of extruded strands and an extruded film.

10. The composition of claim 1, wherein the adhesive composition has an elongation-to-break of about 500% to about 1300%.

11. The composition of claim 1, wherein the base polymer has a styrene content of between about 10% and about 45% by weight.

12. The composition of claim 1, wherein the base polymer has a Shore A hardness of about 20 to about 90.

13. The composition of claim 1, wherein the base polymer is selected from the group consisting of elastomeric polymer compositions, tackified polymers, olefinic copolymers, ethylene-propylene-diene monomer, styrene-isoprene-styrene, styrene-butadiene-styrene, styrene-ethylene/butylene-styrene, styrene-ethylene/propylene-styrene, polyurethane, polyisoprene, cross-linked polybutadiene, and combinations thereof.

14. The composition of claim 13, wherein the high softening point tackifier resin is selected from the group consisting of petroleum distillates, rosin, rosin esters, polyterpenes derived from wood, polyterpenes derived from synthetic chemicals, and combinations thereof.

18. The composition of claim 1, wherein the absorbent material comprises hydrophilic fibers or combinations of hydrophilic and hydrophobic fibers.

19. The composition of claim 1, wherein the absorbent material comprises superabsorbent material from the group consisting of natural polymers, synthetic polymers, modified natural polymers and combinations thereof.

15. An elastomeric adhesive composition, comprising:

a base polymer, present in an amount between about 40% and about 80% by weight;

a high softening point tackifier resin having a softening point of about 80 degrees Celsius or greater, and a viscosity of about 1500 cps or greater at 182 degrees Celsius, present in an amount between about 20% and about 40% by weight; and

a low softening point additive having a softening point of about 60 degrees Celsius or less and a viscosity of about 1000 cps or less at 182 degrees Celsius, present in an amount between about 0% and about 20% by weight;

wherein the elastomeric adhesive composition has a viscosity between about 100,000 and about 500,000 cps at between about 149 and about 177 degrees Celsius; and

wherein the elastomeric adhesive composition further comprises an absorbent material.

16. The composition of claim 15, wherein:

the base polymer is selected from the group consisting of elastomeric polymer compositions, tackified polymers, olefinic copolymers, ethylene-propylene-diene monomer, styrene-isoprene-styrene, styrene-butadiene-styrene, styrene-ethylene/butylene-styrene, styrene-ethylene/propylene-styrene, polyurethane, polyisoprene, cross-linked polybutadiene, and combinations thereof and

the high softening point tackifier resin is selected from the group consisting of petroleum distillates, rosin, rosin esters, polyterpenes derived from wood, polyterpenes derived from synthetic chemicals, and combinations thereof.

17. A method of making an elastomeric adhesive composition, comprising the steps of:

forming a solid phase composition of a base polymer and a high softening point tackifier resin having a softening point of about 80 degrees Celsius or greater and a viscosity of about 1500 cps or greater at 182 degrees Celsius;

forming a liquid phase composition by heating the solid phase composition to a temperature of about 191 degrees Celsius or lower;

achieving a viscosity of the liquid phase composition between about 100,000 and about 500,000 cps at between about 149 and about 177 degrees Celsius; and

forming an elastomeric adhesive composition by extruding the liquid phase composition through hot-melt equipment; and

incorporating an absorbent material into the elastomeric adhesive composition.