Vapor grown carbon fiber reinforced composite materials and methods of making and using same

• US 7,927,701 B2
• Filed: 01/18/2008
• Issued: 04/19/2011
• Est. Priority Date: 02/12/2004
• Status: Expired due to Fees

• Current Assignee: Performance Polymer Solutions, Inc. (Proof Research, Inc.)
• Original Assignee: Performance Polymer Solutions, Inc. (Proof Research, Inc.)
• Inventors: Lincoln, Jason E., Curliss, David B.
• Primary Examiner(s): Ortiz; Angela
• Assistant Examiner(s): MILLER, DANIEL H
• Application Number:
  US12/016,571
• Publication Number:
  US 20080182108A1
• Time in Patent Office: 1,187 Days
• Field of Search: 428/408, 423/447.1, 423/445.R
• US Class Current: 428/408
• CPC Class Codes: B82Y 30/00 Nanotechnology for materials or surface science, e.g. nanocomposites
• CPC Class Codes: C04B 2235/3272 Iron oxides or oxide forming salts thereof, e.g. hematite, magnetite
• CPC Class Codes: C04B 2235/405 Iron group metals
• CPC Class Codes: C04B 2235/614 Gas infiltration of green bodies or pre-forms
• CPC Class Codes: C04B 35/83 Carbon fibres in a carbon matrix
• CPC Class Codes: D01F 9/127 by thermal decomposition of hydrocarbon gases or vapours or other carbon-containing compounds in the form of gas or vapour, e.g. carbon monoxide, alcohols
• CPC Class Codes: D01F 9/1272 Methane
• CPC Class Codes: D01F 9/1275 Acetylene
• CPC Class Codes: Y10S 977/843 Gas phase catalytic growth, i.e. chemical vapor deposition
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

This invention provides vapor grown carbon fiber (VGCF) reinforced continuous fiber performs for the manufacture of articles with useful mechanical, electrical, and thermal characteristics. Continuous fiber preforms are treated with a catalyst or catalyst precursor and processed to yield VGCF produced in situ resulting in a highly entangled mass of VGCF infused with the continuous fiber preform. The resulting continuous fiber preforms are high in volume fraction of VGCF and exhibit high surface area useful for many applications. Furthermore, this invention provides for a continuous fiber preform infused with VGCF so that the carbon nanofibers are always contained within the fiber preform. This eliminates the processing steps for isolated carbon nanofibers reported in other carbon nanofiber composite approaches and therefore greatly reduces risk of environmental release and exposure to carbon nanofibers.

Claims

1. A carbon reinforced continuous fiber preform produced by the process of:

(a) dispersing a catalyst precursor throughout a continuous fiber preform;

(b) converting said catalyst precursor into catalytic particles, said catalytic particles dispersed on the continuous fiber preform; and

(c) contacting the continuous fiber preform containing the catalytic particles with a hydrocarbon gas;

(d) growing vapor grown carbon fibers in situ from the catalytic particles dispersed on said continuous fiber surface, the VGCF fused to the continuous fiber surface to yield a carbon reinforced continuous fiber surface.

2. A carbon reinforced continuous fiber preform useful in the manufacture of carbon reinforced composite articles, comprising:

(a) a continuous fiber preform; and

(b) vapor grown carbon fibers (VGCF) dispersed throughout said continuous fiber preform, the VGCF grown in situ and fused to the continuous fiber surface.

3. The carbon reinforced continuous fiber preform according to claim 2, wherein said vapor grown carbon fibers are less than about 1 micrometer in diameter.

4. The carbon reinforced continuous fiber preform according to claim 2, wherein said carbon reinforced continuous fiber preform is an electrical conductor.

5. A carbon reinforced composite article produced by a process of:

(a) dispersing a catalyst precursor throughout a continuous fiber preform;

(b) converting said catalyst precursor into catalytic particles, said catalytic particles dispersed on the continuous fiber preform;

(c) contacting the continuous fiber preform containing the catalytic particles with a hydrocarbon gas;

(d) growing vapor grown carbon fibers in situ from the catalytic particles dispersed on said continuous fiber surface, the VGCF fused to the surface; and

(e) infusing said carbon reinforced continuous fiber preform with a thermoplastic or thermoset polymer, thermoplastic or thermoset polymer resin, metal, ceramic, ceramic precursor, or amorphous glass to provide a carbon reinforced composite article.