X-ray detection system for wavelength dispersive and energy dispersive spectroscopy and electron beam applications

• US 7,928,400 B1
• Filed: 08/04/2008
• Issued: 04/19/2011
• Est. Priority Date: 08/04/2008
• Status: Active Grant

• Current Assignee: Bruker AXS Incorporated (Bruker Corporation)
• Original Assignee: Bruker AXS Incorporated (Bruker Corporation)
• Inventors: Durst, Roger D., Diawara, Yacouba, Sedov, Vladislav N., Lesher, Donald P., Medved, Sergei A.
• Primary Examiner(s): Souw; Bernard E
• Application Number:
  US12/185,565
• Time in Patent Office: 988 Days
• Field of Search: 250/361.R, 250/362, 250/363.01, 250/370.01, 250/370.09, 378/5, 378/6, 378/140, 378/161
• US Class Current: 250/370.09
• CPC Class Codes: G01T 1/366 with semi-conductor detectors see provisionally also G01T1/36
• CPC Class Codes: H01J 2237/2442 Energy-dispersive (Si-Li type) spectrometer
• CPC Class Codes: H01J 2237/24425 Wavelength-dispersive spectrometer
• CPC Class Codes: H01J 37/244 Detectors; Associated components or circuits therefor
• CPC Class Codes: H01J 37/252 Tubes for spot-analysing by electron or ion beams; Microanalysers
• CPC Class Codes: H01L 31/107 the potential barrier working in avalanche mode, e.g. avalanche photodiodes

Abstract

A detection system for wavelength-dispersive and energy-dispersive spectrometry comprises an X-ray detector formed from a solid-state avalanche photodiode with a thin entrance window electrode that permits the efficient detection of X-rays scattered from “light” elements. The detector can be tilted relative to the incident X-rays in order to increase the detection efficiency for X-rays scattered from “heavy” elements. The entrance window may be continuous conductive layer with a thickness in the range of 5 to 10 nanometers or may be a pattern of conductive lines with “windowless” areas between the lines. A signal processing circuit for the avalanche photodiode detector includes an ultra-low noise amplifier, a dual channel discriminator, a scaler and a digital counter. A linear array of avalanche photodiode detectors is used to increase the count rate of the detection system.

Claims

1. Apparatus for detecting X-rays incident thereon, comprising:

an avalanche photodiode detector having a slab of semiconductor material with a first face on which incident X-rays impinge and a second face on the opposite side of the slab from the first face, a conductive entrance window electrode with a thickness less than ten nanometers covering the first face and a conductive collection electrode covering the second face; and

a voltage source that applies a reverse bias voltage across the entrance window electrode and the collection electrode.

2. The apparatus of claim 1 wherein the conductive entrance window electrode has a thickness in the range of five to ten nanometers.

3. The apparatus of claim 1 wherein the conductive entrance window electrode is continuous.

4. The apparatus of claim 1 wherein the conductive entrance window comprises a pattern of conductive lines wherein the semiconductor material is exposed between the lines.

5. The apparatus of claim 1 further comprising a mechanism that tilts the detector so that the entrance window electrode is at an angle relative to the incident X-rays in order to increase a detection efficiency for X-rays scattered from “

heavy”

elements.

6. The apparatus of claim 1 further comprising a signal processing circuit connected to the avalanche photodiode detector including an ultra-low noise amplifier, a dual channel discriminator, a scaler and a digital counter.

7. The apparatus of claim 1 further comprising a signal processing circuit connected to the avalanche photodiode detector including an ultra-low noise amplifier, a digital signal processing circuit and a digital counter.

8. The apparatus of claim 1 further comprising a linear array of avalanche photodiode detectors.

9. The apparatus of claim 1 wherein the semiconductor material is selected from the group consisting of silicon, germanium, gallium arsenide, gallium nitride and HgCdTe.

10. Apparatus for detecting X-rays incident thereon, comprising:

an avalanche photodiode detector having a slab of semiconductor material with a first face on which incident X-rays impinge and a second face on the opposite side of the slab from the first face, a conductive entrance window electrode with a thickness less than ten nanometers covering the first face and a conductive collection electrode covering the second face;

a voltage source that applies a reverse bias voltage across the entrance window electrode and the collection electrode;

a mechanism that tilts the detector so that the entrance window electrode is at an angle relative to the incident X-rays in order to increase a detection efficiency for X-rays scattered from “

heavy”

elements; and

a signal processing circuit connected to the avalanche photodiode detector including an ultra-low noise amplifier, a dual channel discriminator, a scaler and a digital counter.

11. The apparatus of claim 10 wherein the conductive entrance window electrode has a thickness in the range of five to ten nanometers.

12. The apparatus of claim 10 wherein the conductive entrance window electrode is continuous.

13. The apparatus of claim 10 wherein the conductive entrance window comprises a pattern of conductive lines wherein the semiconductor material is exposed between the lines.

14. The apparatus of claim 10 further comprising a linear array of avalanche photodiode detectors.

15. A wavelength-dispersive spectrometer for measuring X-rays generated when an electron beam strikes a sample, the spectrometer comprising:

an X-ray detector;

a crystal; and

a spectrometer mechanism that positions the crystal relative to the generated X-rays so that X-rays with a selected wavelength are incident on the X-ray detector, wherein the X-ray detector is an avalanche photodiode detector having a slab of semiconductor material with a first face on which incident X-rays impinge and a second face on the opposite side of the slab from the first face, a conductive entrance window electrode with a thickness less than ten nanometers covering the first face and a conductive collection electrode covering the second face.

16. The spectrometer of claim 15 wherein the conductive entrance window electrode has a thickness in the range of five to ten nanometers.

17. The spectrometer of claim 15 wherein the conductive entrance window electrode is continuous.

18. The spectrometer of claim 15 wherein the conductive entrance window comprises a pattern of conductive lines wherein the semiconductor material is exposed between the lines.

19. The spectrometer of claim 15 further comprising a mechanism that tilts the detector so that the entrance window electrode is at an angle relative to the incident X-rays in order to increase a detection efficiency for X-rays scattered from “

heavy”

elements.

20. An energy-dispersive spectrometer for measuring X-rays generated when an electron beam strikes a sample, the spectrometer comprising:

an avalanche photodiode detector having a slab of semiconductor material with a first face on which incident X-rays impinge and a second face on the opposite side of the slab from the first face, a conductive entrance window electrode with a thickness less than ten nanometers covering the first face and a conductive collection electrode covering the second face; and

a counter circuit for processing a signal generated by the detector to generate an X-ray spectrum.

21. The spectrometer of claim 20 wherein the conductive entrance window electrode has a thickness in the range of five to ten nanometers.

22. The spectrometer of claim 20 wherein the conductive entrance window electrode is continuous.

23. The spectrometer of claim 20 wherein the conductive entrance window comprises a pattern of conductive lines wherein the semiconductor material is exposed between the lines.

24. The spectrometer of claim 20 wherein the counter circuit comprises a signal processing circuit connected to the avalanche photodiode detector including an ultra-low noise amplifier, a dual channel discriminator, a scaler and a digital counter.

25. The spectrometer of claim 20 wherein the counter circuit comprises a signal processing circuit connected to the avalanche photodiode detector including an ultra-low noise amplifier, a digital signal processing circuit and a digital counter.